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Isidore P. Decostaire 《Tetrahedron letters》2006,47(39):7057-7060
An aminooxy-containing peptide, the nucleophile partner for oxime ligations, is usually grafted on a NH2-peptide resin by activating a protected aminooxyacetic acid as an active ester. Here, we have shown that its subsequent coupling to NH2-peptide resin competes with the overacylation of the -NH-O- nitrogen and that the overacylation level increases with the basicity of the reaction mixture. Moreover, we found that overacylation is prevented when the COOH of the Aoa-derivatives is engaged in an amide bond. 相似文献
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Hong Heng See Peter C. Hauser Wan Aini Wan Ibrahim Mohd Marsin Sanagi 《Electrophoresis》2010,31(3):575-582
Rapid and direct online preconcentration followed by CE with capacitively coupled contactless conductivity detection (CE‐C4D) is evaluated as a new approach for the determination of glyphosate, glufosinate (GLUF), and aminophosphonic acid (AMPA) in drinking water. Two online preconcentration techniques, namely large volume sample stacking without polarity switching and field‐enhanced sample injection, coupled with CE‐C4D were successfully developed and optimized. Under optimized conditions, LODs in the range of 0.01–0.1 μM (1.7–11.1 μg/L) and sensitivity enhancements of 48‐ to 53‐fold were achieved with the large volume sample stacking‐CE‐C4D method. By performing the field‐enhanced sample injection‐CE‐C4D procedure, excellent LODs down to 0.0005–0.02 μM (0.1–2.2 μg/L) as well as sensitivity enhancements of up to 245‐ to 1002‐fold were obtained. Both techniques showed satisfactory reproducibility with RSDs of peak height of better than 10%. The newly established approaches were successfully applied to the analysis of glyphosate, glufosinate, and aminophosphonic acid in spiked tap drinking water. 相似文献
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Hong Heng See Peter C. Hauser M. Marsin Sanagi Wan Aini Wan Ibrahim 《Journal of chromatography. A》2010,1217(37):5832-5838
A dynamic supported liquid membrane tip extraction (SLMTE) procedure for the effective extraction and preconcentration of glyphosate (GLYP) and its metabolite aminomethylphosphonic acid (AMPA) in water has been investigated. The SLMTE procedure was performed in a semi-automated dynamic mode and demonstrated a greater performance against a static extraction. Several important extraction parameters such as donor phase pH, cationic carrier concentration, type of membrane solvent, type of acceptor stripping phase, agitation and extraction time were comprehensively optimized. A solution of Aliquat-336, a cationic carrier, in dihexyl ether was selected as the supported liquid incorporated into the membrane phase. Quantification of GLYP and AMPA was carried out using capillary electrophoresis with contactless conductivity detection. An electrolyte solution consisting of 12 mM histidine (His), 8 mM 2-(N-morpholino)ethanesulfonic acid (MES), 75 μM cetyltrimethylammonium bromide (CTAB), 3% methanol, pH 6.3, was used as running buffer. Under the optimum extraction conditions, the method showed good linearity in the range of 0.01–200 μg/L (GLYP) and 0.1–400 μg/L (AMPA), acceptable reproducibility (RSD 5–7%, n = 5), low limits of detection of 0.005 μg/L for GLYP and 0.06 μg/L for AMPA, and satisfactory relative recoveries (90–94%). Due to the low cost, the SLMTE device was disposed after each run which additionally eliminated the possibility of carry-over between runs. The validated method was tested for the analysis of both analytes in spiked tap water and river water with good success. 相似文献
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Hartmann F. J. Daniel H. Maierl Chr Mühlbauer M. Schott W. Wojciechowski P. Hauser P. Petitjean C. Taqqu D. Kottmann F. Markushin V. E. 《Hyperfine Interactions》1996,101(1):623-632
Two experiments with low-energy muons are described: the determination of the stopping power of C, Si, Ti and Au for muons at energies down to 2 keV and the measurement of the diffusion times for pµ and dµ atoms in low-pressure (0.25–12 hPa) hydrogen gas. A pronounced Barkas effect was found for muons at the Bragg peak (about 10 keV): the stopping power for µ– in C, e.g., is about 30% lower than that for µ+. The mean kinetic energy of pµ atoms at the end of the cascade in 1 hPa hydrogen gas was determined to be (2.6 ± 0.6) eV (preliminary value). 相似文献
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F. Horst Müller Ernst A. Hauser Ernst A. Hauser E. Baertich 《Colloid and polymer science》1948,110(2):133-136
Ohne Zusammenfassung 相似文献
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In conventional fracture-toughness testing, the line of application of the loads remains fixed with respect to specimen geometry. In this testing machine, the load moves with the advancing crack front, and displacement is used as the controlled variable to propagate and arrest a crack. The energy-release rate at the onset of crack propagation and, hence, the plane-strain fracture toughnessK Ic can be measured directly without compliance calibration or stress-intensity evaluation. The specimen is in the form of a flat plat 25 by 50 cm which is simple to machine and provides about 30 values ofK Ic. The versatility of the machine is demonstrated by making a statistical analysis ofK Ic for 7075-T6 Al by showing the effect of plate thickness on the fracture toughnessK c using a tapered specimen, and by evaluatingK c in 7075 Al as a function of aging temperature in a thermal-gradient-treated specimen. 相似文献