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51.
Sorptivity data are reported for the capillary absorption of water, ethanol, propan-2-ol, and n-heptane by the calcitic limestone Lépine (Lavoux à grain). The data confirm that the water sorptivity is anomalously low, an indication of partial wetting by water. Results are expressed in terms of a wetting index. The water sorptivity increases after heat treatment and chemical oxidation by hydrogen peroxide bleaching, while the sorptivity with organic liquids is unchanged. These treatments, therefore, increase the water wetting index. The results provide strong evidence that the presence of a natural organic adlayer is responsible for the anomalously low water sorptivity of this particular limestone. This natural water repellency effect may be exploited in developing chemical treatments to modify the water transport properties of stone. 相似文献
52.
53.
Expeditious CuI-catalyzed conjugate 1,4-addition of bromo[2-(1,3-dioxolan-2-yl)ethyl]magnesium to the five-, six-, seven-, and eight-membered alpha,beta-cycloalkenones is described. The reaction times are decreased dramatically compared to CuBr-(CH(3))(2)S catalysis. The resulting ketoacetals were subsequently cyclized to bicyclic beta-hydroxy ketones and alpha,beta-enones, followed by further transformations. 相似文献
54.
Let G be a group and E an idempotent matrix with entries in the complex group algebra C
G. In this paper, we study arithmetic properties of the coefficients r
E
(g), gG, of the Hattori-Stallings rank r
E
of E. Bass proved in [2] that the r
E
(g)s are algebraic numbers. Following Zaleskii, we proceed by reduction to positive characteristic and give an alternative proof of that assertion, while obtaining at the same time an upper bound for the degree of the minimum polynomial of r
E
(g) over Q. 相似文献
55.
We establish that an ordered Banach space is order-isomorphic to c0 if and only if it is a -Dedekind complete vector lattice and its norm dual is order-isomorphic to 1. 相似文献
56.
Alexander B. Manenkov Ioannis G. Tigelis Angelos J. Amditis 《Optics Communications》2007,274(2):333-340
The diffraction phenomenon caused by metal transverse irises placed into an asymmetrical slab waveguide is examined by using the integral equation method. We concentrate on the possibility of controlling the radiation characteristics of the structure by changing the irises positions and the slab waveguide asymmetry. The aperture electric-field distribution is expressed in terms of a finite series of Chebyshev polynomials. The dominant TE guided-mode reflection and transmission coefficients, the near-field distribution and the far-field radiation pattern are calculated, while numerical results are presented for several cases of asymmetrical slab waveguides and different irises’ positions. 相似文献
57.
The Pummerer intermediate generated from 10 with TFAA was trapped intermolecularly in the presence of Lewis acid by the indoline 2 at position 5. Sequential treatment of the resulted compound 3 with Ra-Ni, LiAlH4 and active MnO2 gave compound 6 in high overall yield. 相似文献
58.
Ioannis P. Zois 《Communications in Mathematical Physics》2000,209(3):757-783
59.
60.
Christos Kokkinos Anastasios Economou Ioannis Raptis Thanasis Speliotis 《Electrochemistry communications》2009,11(2):250-253
This work describes a novel type of antimony electrode for adsorptive stripping voltammetry (AdSV). The electrode was microfabricated by coating a silicon chip with a thin antimony-film by means of sputtering and the active area of the electrode was defined by photolithography. The resulting antimony-film electrodes (SbFEs) were characterized by optical and electrochemical techniques. The sensors were tested for the detection of low concentrations of Ni(II) by AdSV in the presence of dimethylglyoxime. Well-formed stripping peaks and a linear dependence of the stripping peak current on the Ni(II) concentration were observed on the microfabricated SbFEs while comparative measurements attempted with electroplated SbFEs were unsuccessful. Utilizing thin-film technology for the formation of the antimony-film extends the scope of these devices as mercury-free sensors in AdSV. 相似文献