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71.
G. Lindau 《Colloid and polymer science》1932,60(3):253-263
72.
The wear resistance of homogeneous and multilayer TiNx., TiCxNy- and TiCx-coatings is considerably determined by the layer composition and by the conditions at the interface. This work deals with the possibilities of different depth profile analysis methods for the study of TiNx and TiCx layers on hard metal and steel substrates prepared by plasma assisted CVD technique, and furthermore it demonstrates the performance of factor analysis for detailed investigation of a multilayer system consisting of amorphous C and TiCx single layers.The hard materials coatings were investigated by different methods of depth profile analysis, which may be an important tool in the research of thin layer deposition for wear applications. The following techniques were used: GDOES, analytical TEM, electron microdiffraction and AUGER electron spectroscopy. By means of the combined application of energy dispersive X-ray spectrometry and microdiffraction a correlation of the depth profiles of both elemental concentrations and lattice parameters in TiCx coatings could be revealed.Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthday 相似文献
73.
G. Rossi L. Caliari I. Abbati L. Braicovich I. Lindau W.E. Spicer 《Surface science》1982,116(2):L202-L206
We give the first photoemission results on the enhancement of Si reactivity to oxygen when a noble metal (Ag) is present. The tunability of synchrotron radiation (SR) has been used to get high surface sensitivity and to take advantage of cross section energy dependence. We show that when one monolayer of Ag is deposited onto Si(111), the exposure to oxygen (30 × 106L) originates the overgrowth of an oxide phase which is basically SiO2. This indicates that Ag breaks the sp3 configuration of Si atoms with a consequent dramatic increase in the Si reactivity. This behaviour rules out the model of Ag adsorbed on top of Si with an atomically abrupt interface. 相似文献
74.
C Binns C Norris I Lindau M.L Shek B Pate P.M Stefan W.E Spicer 《Solid State Communications》1982,43(11):853-855
A LEED, Auger photoemission study of ultra-thin overlayers of iron on palladium (111) is reported. At room temperature and below, the overlayer grows epitaxially in a simultaneous multi-layer mode. On annealing a sub-monolayer coverage to create flat two-dimensional platelets it was found that the density of the Fe 3d states at the Fermi level was reduced and the local iron magnetic moment could not be detected. 相似文献
75.
D.T. Ling J.N. Miller D.L. Weissman P. Pianetta P.M. Stefan I. Lindau W.E. Spicer 《Surface science》1983,124(1):175-187
Normal emission ARPES data for Cu(100) with a p(2x2)S overlayer were obtained in the photon energy range hv=11 to 34 eV. These spectra have been compared, within a framework proposed previously, with spectra from clean Cu(100). Changes were found in the Cu emission features, which could be explained by the relaxation of momentum conservation perpendicular to the surface in the optical excitation step and by the relaxation of momentum conservation parallel to the surface in the escape step. These changes include a broadening of the d-band peak and the strong attenuation of the sp-band peak. In addition, a prominent feature appears at about ?4.0 eV at normal emission upon sulfur chemisorption. We tentatively attribute its appearance at normal emission to a new surface umklapp process induced by the overlayer. Changes in the spectrum of scattered electrons were related to modifications of evanescent final states. The sulfur 3pz? and 3px.y-components could be separated at normal emission and are located at ?4.7 and ?5.4 eV, respectively. No dispersion of the sulfur 3p-bands was detected when the and symmetry lines of the surface Brillouin zone were probed. Sulfur-induced emission above the Cu d-bands was observed and attributed to antibonding states. This emission was directed towards the bulk [011] directions. 相似文献
76.
77.
The surface electronic structure of cleaved single crystals of the organic superconductor κ-(ET)2Cu(NCS)2 has been studied using photoemission microscopy. Two types of cleaved surfaces were observed, displaying different valence band photoemission spectra and different spectral behavior near the Fermi level, EF. In particular, spectra from one surface type display relatively broad spectral features in the valence band and finite spectral intensity at EF, while spectra from the other surface type show well-defined valence band emission features and zero photoemission intensity at EF. We propose that the spectral differences are due to a very short electron mean free path in this material, and our results are used to explain the differences between previously published photoemission spectra from this superconductor. We also report the results of an investigation of the electronic structure of defects in this material. 相似文献
78.
Perry Skeath I. Lindau P. Pianetta P.W. Chye C.Y. Su W.E. Spicer 《Journal of Electron Spectroscopy and Related Phenomena》1979,17(4):259-265
A room-temperature reaction between Al adsorbate atoms and a GaAs (110) surface is observed by means of soft X-ray photoemission techniques. Evidence of two states of Al which are distinct from the bulk Al metal is seen at submonolayer coverages. The sequential appearance of these states suggest that both Al chemisorbed on the surface and Al replacing Ga in the surface lattice are present. The possible influence of surface lattice reconstruction and Al proximity effects on the replacement reaction is discussed. The replacement reaction is important in the context of metal contacts to GaAs (both ohmic and Schottky barriers) as well as for GaAs—AlGaAs heterojunctions. 相似文献
79.
The use of the ring oven technique in enzymatic analysis is described. The “segment technique” for catalyzed reactions is applied for the determination of enzymes, inhibitors and substrates. Three different methods have been worked out for this purpose, none of them needs a stable standard scale. These methods are illustrated by various examples: determinations of the enzymes acid and alkaline phosphatase, hyaluronidase, acetylcholinesterase, lipase and alcohol dehydrogenase; indirect determinations of the inhibitors copper, beryllium, molybdenum, the insecticides carbaryl and paraoxon, the herbicides 2, 4-D, mecoprop and bentazcn, and the fungicide phenylmercury acetate; and determinations of the substrates ethanol and glucose. 相似文献
80.
A. Kahn D. Kanani P. Mark P.W. Chye C.Y. Su I. Lindau W.E. Spicer 《Surface science》1979,87(2):325-332
Cleaved GaAs(110) surfaces were exposed to oxygen (106 ? 5 × 1010 L) and analysed by LEED and UPS. Very important changes in the electron diffraction occur at 108 L and the analysis of the LEED pattern shows a bulk-like diffraction superposed on a high background, implying that a thin layer (1–3 Å) disordered by the oxidation covers the GaAs lattice relaxted to its bulk structure. 相似文献