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排序方式: 共有985条查询结果,搜索用时 15 毫秒
1.
V. P. Kondilenko V. Ya. Chorny A. M. Eremenko 《Reaction Kinetics and Catalysis Letters》1993,50(1-2):203-207
The influence of temperature in the 20–100°C range on processes of bimolecular interaction in the aerosil-phenanthrene-trinitrobenzene system has been studied. Temperature-stimulated CTC accumulation on the surface is found. Activation energies of complex formation are estimated. Quenching of phenanthrene fluorescence by acceptor has a mixed static and dynamic character. 相似文献
2.
An approach called Schramm–Loewner evolution (SLE) provides a new method for dealing with a wide variety of scale-invariant problems in two dimensions. This approach is based upon an older method called Loewner Evolution (LE), which connects analytic and geometrical constructions in the complex plane. In this paper, the bases of LE and SLE are described and some simple applications are discussed in relatively non-technical form. A bibliography of the subject is presented. 相似文献
3.
Chi-Kwong Li Ilya M. Spitkovsky 《Journal of Mathematical Analysis and Applications》2003,282(1):329-340
Existence of the fractional powers is established in Banach algebra setting, in terms of the numerical ranges of elements involved. The behavior of the spectra and (for Hermitian ∗-algebras satisfying some additional hypotheses) the ∗-numerical range under taking these powers also is investigated. 相似文献
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6.
Merchant KA Noid WG Akiyama R Finkelstein IJ Goun A McClain BL Loring RF Fayer MD 《Journal of the American Chemical Society》2003,125(45):13804-13818
Spectrally resolved infrared stimulated vibrational echo data were obtained for sperm whale carbonmonoxymyoglobin (MbCO) at 300 K. The measured dephasing dynamics of the CO ligand are in agreement with dephasing dynamics calculated with molecular dynamics (MD) simulations for MbCO with the residue histidine-64 (His64) having its imidazole epsilon nitrogen protonated (N(epsilon)-H). The two conformational substate structures B(epsilon) and R(epsilon) observed in the MD simulations are assigned to the spectroscopic A(1) and A(3) conformational substates of MbCO, respectively, based on the agreement between the experimentally measured and calculated dephasing dynamics for these substates. In the A(1) substate, the N(epsilon)-H proton and N(delta) of His64 are approximately equidistant from the CO ligand, while in the A(3) substate, the N(epsilon)-H of His64 is oriented toward the CO, and the N(delta) is on the surface of the protein. The MD simulations show that dynamics of His64 represent the major source of vibrational dephasing of the CO ligand in the A(3) state on both femtosecond and picosecond time scales. Dephasing in the A(1) state is controlled by His64 on femtosecond time scales, and by the rest of the protein and the water solvent on longer time scales. 相似文献
7.
Comparability of analytical results obtained in proficiency testing based on a metrological approach
Ilya Kuselman 《Accreditation and quality assurance》2006,10(9):466-470
A “yes–no” type of criterion is proposed for the assessment of comparability of proficiency testing (PT) results when the PT scheme is based on a metrological approach, i.e. on the use of a reference material as the test sample, etc. The criterion tests a null hypothesis concerning the insignificance of a bias of the mean of the results from a traceable value certified in the reference material used for the PT. Reliability of such assessment is determined by the probabilities of not rejecting the null hypothesis when it is true, and rejecting it when it is false (the alternative hypothesis is true). It is shown that a number of chemical, metrological and statistical reasons should be taken into account for careful formulation of the hypotheses, enabling the avoidance of an erroneous assessment of the comparability. The criterion can be helpful for PT providers and laboratory accreditation bodies in analysis of PT results. 相似文献
8.
Israel Gohberg Naum Krupnik Ilya Spitkovsky 《Integral Equations and Operator Theory》1993,17(3):322-337
The Banach algebra generated by one-dimensional linear singular integral operators with matrix valued piecewise continuous coefficients in the spaceL
p
(,) with an arbitrary weight is studied. The contour consists of a finite number of closed curves and open arcs with satisfy the Carleson condition. The contour may have a finite number of points of selfintersection. The symbol calculus in this algebra is the main result of the paper. 相似文献
9.
Ilya I. Moiseev Tatiana A. Stromnova Irina N. Busygina Natalya Yu. Tihonova Natalya Yu. Kozitsyna Arkady M. Ellern Mikhail Yu. Antipin Yury T. Struchkov 《Journal of Cluster Science》1992,3(4):411-421
Thermolysis of tetranuclear palladium clusters Pd4(-Q)4 Pd4(-Q)4(-O2CR)4 (Q=CPh2 or CO;R=Me, CMe3, Ph, CH2Cl or CF3) has been found to involve innersphere oxidation of carbene or carbonyl ligands during which an oxygen atom transfer occurs from the carboxylate group to the carbene or carbonyl ligand. The thermolysis of the carbonyl clusters gives rise to the products of CO2 insertion into the C–H bond of benzene or toluene used as solvents forming benzoic acid from benzene and a mixture of phenylacetic and toluic acids from toluene. The reaction of [Pd(OAc)2(PPh3)]2 with HCO2H includes the transfer of an O atom from formate ligand to the P atom and cleavage of the P-Ph bond accompanied by transfer of the Ph group from PPh3 ligand to the palladium atom. The structure of the complex formed, [Pd(-O2PPh2)(C6H5)(PPh3)]2, has been resolved by X-ray analysis. 相似文献
10.
Weber JM Ioffe IN Berndt KM Löffler D Friedrich J Ehrler OT Danell AS Parks JH Kappes MM 《Journal of the American Chemical Society》2004,126(27):8585-8589
Ultraviolet photoelectron spectroscopy in an ion beam was used to investigate the electronic properties of isolated DNA oligonucleotides [dA(5)-4H](4-) and [dT(5)-4H](4-), carrying four excess negative charges. We find the fourth adiabatic electron affinity to be slightly negative for [dA(5)-4H](4-), while it is positive for [dT(5)-4H](4-). This implies a significant influence of the base composition on energetics, which is in turn relevant for analytic applications and also for charge transport properties. 相似文献