全文获取类型
收费全文 | 242篇 |
免费 | 19篇 |
国内免费 | 2篇 |
专业分类
化学 | 161篇 |
晶体学 | 7篇 |
力学 | 5篇 |
数学 | 32篇 |
物理学 | 58篇 |
出版年
2023年 | 5篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 14篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 8篇 |
2016年 | 16篇 |
2015年 | 13篇 |
2014年 | 10篇 |
2013年 | 24篇 |
2012年 | 12篇 |
2011年 | 23篇 |
2010年 | 10篇 |
2009年 | 15篇 |
2008年 | 12篇 |
2007年 | 16篇 |
2006年 | 14篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1980年 | 3篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有263条查询结果,搜索用时 218 毫秒
41.
42.
Ambujakshan KR Madhavan VS Varghese HT Panicker CY Temiz-Arpaci O Tekiner-Gulbas B Yildiz I 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(3):782-788
FT-IR spectra of 5-methyl-2-(p-methylaminophenyl)benzoxazole was recorded and analysed. The vibrational frequencies of the compound have been computed using the Hartree-Fock/6-31G* basis and compared with the experimental values. 相似文献
43.
This paper is concerned with the existence of positive solutions of second-order impulsive boundary value problem with integral boundary conditions on time scales. Existence results of at least three positive solutions are established via a new fixed point theorem in a cone. Also, an example is given to illustrate the effectiveness of our result. 相似文献
44.
1-Bromo-1-fluoro-[1a,2,7,7a]-tetrahydro-1H-cyclopropa[b]naphthalene (19) has been prepared by the addition of bromofluorocarbene to 1,4-dihydronaphthalene (18). Treatment of a solution of 19 in dry ether with MeLi afforded the tricyclic hydrocarbon 17, resulting from the intramolecular C-H insertion of carbene 16, and two dimerization products, the head-to-head 20 and head-to-tail 21 allene dimers, confirming the formation of title cycloallene 15 as a reactive intermediate. B3LYP/6-31G(d) calculation predicts the activation barriers for insertion product 17 and allene product 15 as 3.70 and 9.52 kcal/mol, respectively. This prediction was in good agreement with our experimental results. 相似文献
45.
ÜMIT ÇAKIR Y. Kemal Yildiz Mahir Alkan 《Journal of inclusion phenomena and macrocyclic chemistry》1999,34(2):155-167
Liquid-liquid extractive-spectrophotometric studies of sodium ion complexes of 18-crown-6(18C6), dibenzo-18-crown-6(DB18C6), 15-crown-5(15C5), and 12-crown-4(12C4) and anionic dyes [4-(2-pyridylazo)-resorcinol monosodium salt monohydrate (PAR), Eriochrom Black T (EBT), and methyl orange (MOR)] and sodium picrate (PICRAT) as the counter ion are described. The overall extraction equilibrium constants for the 1 : 1 complexes of the above crown ethers with sodium dyes between different organic solvents and water have been determined at 25deg;C. They were conducted in various solvent-water systems maintaining an identical initial cation concentration in water, [M0+]w, and macrocyclic ligand concentration in the organic phase, [L0]org}, so that in all extractions [M0+]w : [L0]org ratios were 1 : 1, 1 : 10, 1 : 20, 1 : 50, and 1 : 62.5. An ion association complex formed between the sodium-crown ether complex ion and a dye anion was extracted into the organic solvent, and then the dye concentration of the separated aqueous phase was measured with an ultraviolet-visible spectrophotometer. PAR was the best associated dye with all crown ethers sodium-dyes and the extracted dye occurs as the ion-pair complex. Methylene chloride was found to be better than other extractive solvents used in this study. 相似文献
46.
47.
S.B. Lisesivdin H. Altuntas A. Yildiz M. Kasap E. Ozbay S. Ozcelik 《Superlattices and Microstructures》2009,45(6):604-611
Experimental Hall data that were carried out as a function of temperature (60–350 K) and magnetic field (0–1.4 T) were presented for Si-doped low Al content (x=0.14) n–AlxGa1−xAs/GaAs heterostructures that were grown by molecular beam epitaxy (MBE). A 2-dimensional electron gas (2DEG) conduction channel and a bulk conduction channel were founded after implementing quantitative mobility spectrum analysis (QMSA) on the magnetic field dependent Hall data. An important decrease in 2DEG carrier density was observed with increasing temperature. The relationship between the bulk carriers and 2DEG carriers was investigated with 1D self consistent Schrödinger–Poisson simulations. The decrement in the 2DEG carrier density was related to the DX-center carrier trapping. With the simulation data that are not included in the effects of DX-centers, 17 meV of effective barrier height between AlGaAs/GaAs layers was found for high temperatures (T>300 K). With the QMSA extracted values that are influenced by DX-centers, 166 meV of the DX-center activation energy value were founded at the same temperatures. 相似文献
48.
C. Yohannan Panicker Hema Tresa Varghese Asha Raj K. Raju Tugba Ertan-Bolelli Ilkay Yildiz Ozlem Temiz-Arpaci Carlos M. Granadeiro Helena I.S. Nogueira 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(1):132-139
The FT-IR and FT-Raman spectra of 2-phenoxymethylbenzothiazole were recorded and analyzed. The surface enhanced Raman scattering (SERS) spectrum was recorded in a silver colloid. The vibrational wavenumbers of the compound have been computed using the Hartree–Fock/6-31G* basis and compared with the experimental values. The appearance of the Ag–O stretching mode at 237 cm−1 in the SERS spectrum along with theoretically calculated atomic charge density, leads us to suggest that the molecule is adsorbed through the oxygen atom with the molecular plane tilted on the colloidal silver surface. The direction of charge transfer contribution to SERS has been discussed from the frontier orbital theory. 相似文献
49.
Sansal K. Yildiz J. Fraser Forbes Biao Huang Yale Zhang Fred Wang Vit Vaculik Mike Dudzic 《Applied Mathematical Modelling》2009
Hot rolling is an essential industrial process in the production of sheet steel, a widely used product in manufacturing and construction. A finishing mill performs a set of operations in a hot strip rolling mill, and is a complex unit including many processes and control loops. Its modelling is a challenging task due to the variety of phenomena that occur within the mill, and variable transport delays. Model validation is also challenging due to a scarcity of measurements. On the other hand, a dynamic model that adequately reflects the numerous interactions between the mill units can be very useful for tasks such as high performance control design or vibration analysis. In this study, a one-dimensional model has been developed and validated against real plant data. The end use of the model is intended to be looper control analysis, but the model is kept sufficiently general so that it can be used or easily extended for other applications. 相似文献
50.
Koksal Yildiz Unal Akgul Hartmut S. Leipner Yusuf Atici 《Applied Physics A: Materials Science & Processing》2014,117(3):1387-1392
The film of thermoelectric ternary p-type (Bi0.15Sb0.85)2Te3 was deposited on polyimide foil substrate at 168 °C using direct-current magnetron sputtering. Microstructural investigations of the film were performed by electron microscopy techniques. SEM observations showed that the film surface consisted of large-sized particulates with small-sized particles and also mound-like crystal agglomerates in some areas. Chemical composition of the film was analyzed using energy-dispersive X-ray spectrometer (EDS). It has been observed that the EDS results were in an agreement with nominal composition for the film. Detailed microstructural investigations were carried out using transmission electron microscopy (TEM). TEM images and selected area electron diffraction patterns showed that the film has randomly oriented polycrystalline grain structure. High-resolution TEM images indicated that the microstructure of film also contained nano-crystal structure, smaller than 10 nm. 相似文献