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91.
I. Vasiliu M. Gartner M. Anastasescu L. Todan L. Predoana M. Elisa C. Grigorescu C. Negrila C. Logofatu M. Enculescu A. Moldovan G. Pavelescu M. Zaharescu 《Optical and Quantum Electronics》2007,39(4-6):511-521
We intend to prepare periodic multilayered structures for photonic applications. With this goal we have performed a study
of some characteristics of SiO
x
-P2O5 films deposited by the sol–gel method on glass and ITO (InSnO
x
)-coated glass. The as prepared films were annealed to different temperatures (150 and 200°C). The chemical composition of
the samples was determined by X-ray Photoelectron Spectroscopy (XPS). The XPS results revealed the presence of P in the as-deposited
films. The structural an optical properties were examined by Fourier Transform Infrared Spectroscopy (FTIR), Spectroellipsometry
(SE) and UV Transmission Spectroscopy. IR spectra of the deposited films attest the interaction of an amorphous SiO2 with the H3PO4 used as a P-precursor. Refractive indices for individual SiO
x
-P2O5 determined from SE measurements show a densification of the layer structure with the increasing temperature in the thermal
treatment. The UV transmission spectra revealed a lower transmission for the sol-gel SiO
x
-P2O5 films as compared to ITO/glass substrate. AFM images proved the densification of the films with annealing in agreement with
the ellipsometric results.
The work was originally presented at “Physics of Photonic Crystals and Metamaterials (PPCM)” Workshop, Brussels, 12–15 June,
2006. 相似文献
92.
Three polynuclear thorium(IV) molecular complexes have been synthesized under ambient conditions from reactions of an amorphous Th precipitate, obtained via hydrolysis, with carboxylate functionalized ligands. The structures of Th(6)(OH)(4)O(4)(H(2)O)(6)(HCO(2))(12)·nH(2)O (1), Th(6)(OH)(4)O(4)(H(2)O)(6)(CH(3)CO(2))(12)·nH(2)O (2), Th(6)(OH)(4)O(4)(H(2)O)(6)(ClCH(2)CO(2))(12)·4H(2)O (3) each consist of a hexanuclear Th core wherein six 9-coordinate Th(IV) cations are bridged by four μ(3)-hydroxo and four μ(3)-oxo groups. Each Th(IV) center is additionally coordinated to one bound "apical" water molecule and four oxygen atoms from bridging carboxylate functionalized organic acid units. "Decoration" of the cationic [Th(6)(μ(3)-O)(4)(μ(3)-OH)(4)](12+) cores by anionic shells of R-COO(-) ligands (R = H, CH(3), or CH(2)Cl) terminates the oligomers and results in the formation of discrete, neutral molecular clusters. Electronic structure calculations at the density functional theory level predicted that the most energetically favorable positions for the protons on the hexanuclear core result in the cluster with the highest symmetry with the protons separated as much as possible. The synthesis, structure, and characterization of the materials are reported. 相似文献
93.
Hossam Al‐Suod Ileana‐Andreea Ratiu Ryszard Grecki Bogusaw Buszewski 《Journal of separation science》2019,42(6):1265-1272
Cyclitols and sugars were obtained as a mixture from Medicago sativa L., in a comparative study by using maceration, and pressurized liquid extraction, as a modern and green extraction techniques. The influence of extraction parameters including: extraction temperature, time and number of cycles on the content of sugars and cyclitols was investigated based on response surface methodology. The highest total amount of sugars and cyclitols (62.27 ± 2.30 and 50.35 ± 0.77 mg/g of dry material, respectively) was obtained when extraction was performed at 88°C, for 22 min, in two cycles. The methodology used involved extraction, purification, selective separation (using yeast and anion exchange resin) and derivatization, followed by gas chromatography ‐mass spectrometry analysis. The use of yeast treatment realized an effective fractionation of cyclitols and sugars, which allowed the removal of most sugars. The involvement of anion exchange resin after yeast allowed the removal of sugar alcohols and lactose, together with other sugar traces remained and to obtain a solution containing six cyclitols. The recrystallization of dry residue after solvent evaporation, from ethanol, allowed us to obtain 14.65 mg of white pure crystals identified with NMR spectroscopy, liquid chromatography with mass spectrometry, gas chromatography with mass spectrometry, optical rotation and melting point as analysis D‐pinitol. 相似文献
94.
95.
The results of magnetic measurements and ferromagnetic resonance study on Ni0.87Cu0.13?xAlx and Ni0.77Cu0.23?xAlx alloys with x ? 10 at 10 % Al are reported. The saturation magnetization and the Curie temperatures are linearly dependent on the mean electronic concentration of the CuAl matrix. The ferromagnetic resonance measurements show that the g values are not dependent on composition, g = 2.19 ± 0.01. The magnetic behaviour of NiCuAl alloys is analysed in the coherent potential approximation. 相似文献
96.
Nicolae Baranov Stefania Racovita Silvia Vasiliu Ana Maria Macsim Catalina Lionte Valeriu Sunel Marcel Popa Jacques Desbrieres Corina Cheptea 《Molecules (Basel, Switzerland)》2021,26(11)
New polymer-bioactive compound systems were obtained by immobilization of triazole derivatives onto grafted copolymers and grafted copolymers carrying betaine units based on gellan and N-vinylimidazole. For preparation of bioactive compound, two new types of heterocyclic thio-derivatives with different substituents were combined in a single molecule to increase the selectivity of the biological action. The 5-aryl-amino-1,3,4 thiadiazole and 5-mercapto-1,2,4-triazole derivatives, each containing 2-mercapto-benzoxazole nucleus, were prepared by an intramolecular cyclization of thiosemicarbazides-1,4 disubstituted in acidic and basic medium. The structures of the new bioactive compounds were confirmed by elemental and spectral analysis (FT-IR and 1H-NMR). The antimicrobial activity of 1,3,4 thiadiazoles and 1,2,4 triazoles was tested on gram-positive and gram-negative bacteria. The triazole compound was chosen to be immobilized onto polymeric particles by adsorption. The Langmuir, Freundlich, and Dubinin–Radushkevich adsorption isotherm were used to describe the adsorption equilibrium. Also, the pseudo-first and pseudo-second models were used to elucidate the adsorption mechanism of triazole onto grafted copolymer based on N-vinylimidazole and gellan (PG copolymer) and grafted copolymers carrying betaine units (PGB1 copolymer). In vitro release studies have shown that the release mechanism of triazole from PG and PGB1 copolymers is characteristic of an anomalous transport mechanism. 相似文献
97.
Miguel Melndez-Zamudio Ileana Bravo-Flores Eulalia Ramírez-Oliva Antonio Guerra-Contreras Gilberto lvarez-Guzmn Ramn Zrraga-Nuez Antonio Villegas Merced Martínez-Rosales Jorge Cervantes 《Molecules (Basel, Switzerland)》2021,26(4)
Stone consolidants have been widely used to protect historical monuments. Consolidants and hydrophobic formulations based on the use of tetraethoxysilane (TEOS) and alkylalkoxysilanes as precursors have been widely applied, despite their lack of solubility in water and requirement to be applied in organic media. In the search for a “greener” alternative based on silicon that has potential use in this field, the use of tetrakis(2-hydroxyethyl)silane (THEOS) and tris(2-hydroxyethyl)methyl silane (MeTHEOS) as precursors, due their high water solubility and stability, is proposed in this paper. It is already known that THEOS and MeTHEOS possess remarkable compatibility with different natural polysaccharides. The investigated approach uses the water-soluble silanes THEOS–chitosan and MeTHEOS–chitosan as a basis for obtaining hybrid consolidants and hydrophobic formulations for the conservation of siliceous and calcareous stones. In the case of calcareous systems, their incompatibility with alkoxysilanes is known and is expected to be solved by the developed hybrid consolidant. Their application in the conservation of building stones from historical and archeological sites from Guanajuato, México was studied. The evaluation of the consolidant and hydrophobic formulation treatment was mainly conducted by determining the mechanical properties and contact angle measurements with satisfactory results in terms of the performance and compatibility with the studied stones. 相似文献
98.
Legendrian submanifolds in Sasakian space forms play an important role in contact geometry. Defever et al. (Boll Unione Mat Ital B 7(11):365–374, 1997) established the first Chen inequality for C-totally real submanifolds in Sasakian space forms. In this article, we improve this first Chen inequality for Legendrian submanifolds in Sasakian space forms. 相似文献
99.
Dr. Richard J. Burford Dr. Bo Li Dr. Monica Vasiliu Prof. Dr. David A. Dixon Prof. Dr. Shih‐Yuan Liu 《Angewandte Chemie (International ed. in English)》2015,54(27):7823-7827
Diels–Alder reactions employing 1,2‐azaborine heterocycles as 1,3‐dienes are reported. Carbocyclic compounds with high stereochemical and functional complexity are produced, as exemplified by the straightforward two‐step synthesis of an amino allyl boronic ester bearing four contiguous stereocenters as a single diastereomer. Whereas electron‐deficient dienophiles undergo irreversible Diels–Alder reactions, a reversible Diels–Alder reaction with the less electron‐deficient methyl acrylate is observed. Both the N and the B substituent of the 1,2‐azaborine exert significant influence on the [4+2] cycloaddition reactivity as well as the aromatic character of the heterocycle. The experimentally determined thermodynamic parameters of the reversible Diels–Alder reaction between 1,2‐azaborines and methyl acrylate correlate with aromaticity trends and place 1,2‐azaborines approximately between furan and thiophene on the aromaticity scale. 相似文献
100.
The extraction of two specimens of Pseudopterogorgia elisabethae, each collected from a different location at the San Andrés Archipelago, afforded two new norditerpenes, caribenols A (1) and B (2). Metabolites 1 and 2 contain unusual carbon skeletons that are previously undescribed and therefore constitute new classes of C19 rearranged terpenes. Their molecular structures were established by a combination of single-crystal X-ray analysis and comprehensive 2D NMR measurements. 相似文献