Improvement of polyacrylate coating by filling modified nano-TiO2

Nano-TiO₂ is modified by a method, by which nano-TiO₂ first reacts with silane coupling agent WD-70 with double bond group which subsequently copolymerizes with methyl methacrylate and butyl acrylate to produce a thin polymer shell on the nanoparticles. The modified nanoparticles have stable organophilicity. They are applied to polyacrylate coating and performances of the coating are measured by different methods. The modification of nano-TiO₂ particles can improve their dispersibility in coating, enhance hardness of coating and reduce water absorption and permeability of polyacrylate coating. The mechanism has been analyzed in this paper.     

The Khler-Einstein metric for some Hartogs domains over symmetric domains

We study the complete Kahler-Einstein metric of a Hartogs domainΩbuilt on an irreducible bounded symmetric domainΩ, using a power Nμof the generic norm ofΩ.The generating function of the Kahler-Einstein metric satisfies a complex Monge-Ampere equation with a boundary condition. The domainΩis in general not homogeneous, but it has a subgroup of automorphisms, the orbits of which are parameterized by X∈[0,1[. This allows us to reduce the Monge-Ampere equation to an ordinary differential equation with a limit condition. This equation can be explicitly solved for a special valueμ0 ofμ.. We work out the details for the two exceptional symmetric domains. The special valueμ0 seems also to be significant for the properties of other invariant metrics like the Bergman metric; a conjecture is stated, which is proved for the exceptional domains.     

Electronic properties of the single-domain Li/Si(001) surface

Received: 14 October 1996/Accepted: 17 December 1996     

Synthesis of new dibenzo nitrogen-oxygen donor macrocycles containing two amide groups

Four new nitrogen-oxygen, dibenzo macrocyclic ligands containing two amide groups have been prepared by combining a dibenzo-containing diamidodialdehyde with an appropriate diamine followed by reduction of the intermediate bis Schiff-base. The starting dibenzo-containing diamidodialdehyde was prepared by treating 2 equivalents of salicylaldehyde with a bis(α-chloroamide).     

视觉极限衬比测试仪设计

本文介绍了人眼视觉极限衬比测试仪的原理、设计方法、功能及主要参数.其主要原理是在主光路和辅助光路中分别置一偏振片,其偏振方向相互垂直.旋转组合光路中的检偏镜,即可得到可供观察用的变衬比鉴别率图象.文章指出,使用这种仪器检测人眼视觉衬比的良好结果表明,新仪器研制是成功的.     

二异丁基锌控制高密度聚乙烯分子量的研究

本文报告了TiCl_4-MgCl_2-AlCl_3/Al(i-Bu)_3-Zn(i-Bu)_2催化体系的乙烯聚合反应中,二异丁基锌对产物分子量和聚合活性的影响。结果表明:在适宜的聚合条件下,二异丁基锌可以有效地控制产物的分子量。     

Cobalt-catalyzed oxidative arylmethylation of phosphorylamides

A cobalt-catalyzed strategy for N-arylmethylation of phosphorylamides was herein achieved with the assistance of azodiisobutyronitrile as the radical initiator and di-tert-butyl peroxide as the oxidant. Both methylarenes and diaryl methanes were compatible under the oxidative conditions, expressing broad substrate scope (51 examples) and high efficiency (up to 87% yield).     

Oxidative kinetic resolution of heterocyclic sulfoxides with a porphyrin-inspired manganese complex by hydrogen peroxide

We have successfully reported here the low loading porphyrin-inspired high-valent manganese (IV)-oxo complex was applied in oxidative kinetic resolution (OKR) of racemic heterocyclic sulfoxides using the environmentally benign hydrogen peroxide for the first time. This approach allows for rapid OKR (0.5?h) of a variety of racemic sulfoxides (including pyridine, pyrimidine, pyrazine, thiazole, benzothiazole, thiophene) in excellent enantioselectivity (up to?>?99%?ee), simultaneously generating the corresponding sulfones in high yield (up to 80%). The catalytic system also showed an unexceptionable chemoselectivity for the sulfoxide substrates with hydroxyl groups in which only the sulfoxide group was oxidized. The practical utility of the method has been demonstrated in the OKR of gram-scale sulfoxides.