Synthesis of hexagonal nickel hydroxide nanosheets by exfoliation of layered nickel hydroxide intercalated with dodecyl sulfate ions

One-nanometer-thick nickel hydroxide nanosheets were prepared by exfoliation of layered nickel hydroxides intercalated with dodecyl sulfate (DS) ions. The shape of the nanosheets was hexagonal, as was that of the layered nickel hydroxides intercalated with DS ions. The nickel hydroxide nanosheets exhibited charge-discharge properties in strong alkaline electrolyte. The morphology of the nanosheet changed during the electrochemical reaction.     

Chemoenzymatic synthesis of naturally occurring benzyl 6-O-glycosyl-beta-D-glucopyranosides

Direct beta-glucosidation between benzyl alcohol and D-glucose (5) using the immobilized beta-glucosidase from almonds with the synthetic prepolymer ENTP-4000 gave a benzyl beta-D-glucoside (1) in 53% yield. The coupling of the benzyl beta-D-glucopyranoside congener (8) derived from 1 with phenyl 2,3,4-tri-O-acetyl-1-thio-beta-D-xylopyranoside (9), ethyl 2,3,4-tri-O-acetyl-1-thio-alpha-L-rhamnopyranoside (13), and 2,3,4-tri-O-acetyl-alpha-L-arabinopyranosyl bromide (15) afforded 10, 14, and 16, respectively, as coupled products. Deprotection of 10, 14, and 16 provided the synthetic benzyl beta-D-xylopyranosyl-(1-->6)-beta-D-glucopyranoside (2), benzyl alpha-L-rhamnopyranosyl-(1-->6)-beta-D-glucopyranoside (3), and benzyl alpha-L-arabinopyranosyl-(1-->6)-beta-D-glucopyranoside (4), respectively.     

Study of the Torino meteorite

Mössbauer spectroscopy has been applied to the study of the Torino H6 meteorite. An identification of the principal components has been attempted.     

Thermochemistry of Alane Complexes for Hydrogen Storage: A Theoretical and Experimental Investigation

Knowledge of the relative stabilities of alane (AlH(3)) complexes with electron donors is essential for identifying hydrogen storage materials for vehicular applications that can be regenerated by off-board methods; however, almost no thermodynamic data are available to make this assessment. To fill this gap, we employed the G4(MP2) method to determine heats of formation, entropies, and Gibbs free energies of formation for 38 alane complexes with NH(3-n)R(n) (R = Me, Et; n = 0-3), pyridine, pyrazine, triethylenediamine (TEDA), quinuclidine, OH(2-n)R(n) (R = Me, Et; n = 0-2), dioxane, and tetrahydrofuran (THF). Monomer, bis, and selected dimer complex geometries were considered. Using these data, we computed the thermodynamics of the key formation and dehydrogenation reactions that would occur during hydrogen delivery and alane regeneration, from which trends in complex stability were identified. These predictions were tested by synthesizing six amine-alane complexes involving trimethylamine, triethylamine, dimethylethylamine, TEDA, quinuclidine, and hexamine and obtaining upper limits of ΔG° for their formation from metallic aluminum. Combining these computational and experimental results, we establish a criterion for complex stability relevant to hydrogen storage that can be used to assess potential ligands prior to attempting synthesis of the alane complex. On the basis of this, we conclude that only a subset of the tertiary amine complexes considered and none of the ether complexes can be successfully formed by direct reaction with aluminum and regenerated in an alane-based hydrogen storage system.     

Biological Activity of Amidino-Substituted Imidazo [4,5-b]pyridines

A series of cyano- and amidino-substituted imidazo[4,5-b]pyridines were synthesized using standard methods of organic synthesis, and their biological activity was evaluated. Biological evaluation included in vitro assessment of antiproliferative effects on a diverse selection of human cancer cell lines, antibacterial activity against chosen Gram-positive and Gram-negative bacterial strains, and antiviral activity on a broad panel of DNA and RNA viruses. The most pronounced antiproliferative activity was observed for compound 10, which contained an unsubstituted amidino group, and compound 14, which contained a 2-imidazolinyl amidino group; both displayed selective and strong activity in sub-micromolar inhibitory concentration range against colon carcinoma (IC₅₀ 0.4 and 0.7 μM, respectively). All tested compounds lacked antibacterial activity, with the exception of compound 14, which showed moderate activity against E. coli (MIC 32 μM). Bromo-substituted derivative 7, which contained an unsubstituted phenyl ring (EC₅₀ 21 μM), and para-cyano-substituted derivative 17 (EC₅₀ 58 μM) showed selective but moderate activity against respiratory syncytial virus (RSV).     

Accelerating flames in tubes—an analysis

Flame acceleration in tubes is studied. A tube filled with flammable mixture is closed at one end and open to the atmosphere at its second end. When ignition takes place near the closed end, it is well-known from experiments that the flame may accelerate, oscillate and eventually reach considerable speeds. A one-dimensional analysis is presented, based upon the assumption that the flame front propagates at a speed that is small compared to the speed of sound. The analysis leads to a construction of the complete unsteady solution. Results from the analysis and from a numerical simulation are compared. They are similar enough to validate the analysis. The tube acoustics are set in motion by the expansion of the fluid due to ignition at the closed end. Subsequently, both spectrum and amplitude evolve because of the motion of the temperature interface, and because of forcing by the flame front, which the analysis precisely quantifies. Oscillations in the front position are strong enough to result in flow reversal. In addition, the induced periodic acoustic acceleration of the temperature and density interface will periodically make the flame front Rayleigh–Taylor unstable, which should result in the dramatic increase in the propagation speed seen in experiments.     

Curie temperature of Ni−Fe alloys in the region (24÷35)% Ni from Mössbauer experiments

Summary The ferromagnetic-transition temperatureT _c of carefully homogeneized Ni−Fe alloys has been determined by means of M?ssbauer transmission experiments down to liquid-nitrogen temperature, for Ni contents ranging between 24% and 35% (atomic). The results show thatT _c decreases rapidly with decreasing Ni concentration, according to a nonlinear behaviour different from the linear one usually observed in other Ni alloys. The present data agree with the ones of other authors, but differ from other data probably obtained in less homogeneized samples.

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Riassunto La temperatura di transizione ferromagneticaT _c di leghe Fe−Ni preparate in laboratorio con cura particolare per garantire l'omogeneità è stata misurata mediante misure M?ssbauer fino alla temperatura dell'azoto liquido per concentrazioni di Ni variabili tra 24 e 35% (atomico). I risultati mostrano cheT _c è una funzione rapidamente decrescente al diminuire della concentrazione di Ni con un andamento non lineare caratteristico di tali leghe e diverso da quello lineare osservato su altre leghe di Ni. I dati ottenuti sono in accordo con quelli di altri autori, ma differiscono da altri risultati probabilmente ottenuti su campioni non sufficientemente omogenei.

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Реэюме Проводится иэмерение температуры ферромагнитного переходаT _c в сплавах Ni−Fe с контролируемой однородностъю. Иэмерения проводятся с помощъю мессбауэровских экспериментов при температурах вплоть до температуры жидкого азота и для концентраций никеля в области от 24 до 35 атомных процентов. Полученные результаты показывают, чтоT _c уменьшается быстро с уменьшением концентрации Ni, согласно нелинейному поведению, которое отлично от линейного поведения, обычно наблюдаемого в других сплавах никеля. Полученные данные согласуются с даннымн других авторов, но отличаются от других данных, которые, вероятно, получены на менее однородных образцах.