全文获取类型
收费全文 | 748篇 |
免费 | 15篇 |
国内免费 | 5篇 |
专业分类
化学 | 595篇 |
晶体学 | 17篇 |
力学 | 14篇 |
数学 | 42篇 |
物理学 | 100篇 |
出版年
2022年 | 7篇 |
2021年 | 8篇 |
2019年 | 12篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 13篇 |
2014年 | 11篇 |
2013年 | 42篇 |
2012年 | 38篇 |
2011年 | 31篇 |
2010年 | 17篇 |
2009年 | 19篇 |
2008年 | 31篇 |
2007年 | 37篇 |
2006年 | 43篇 |
2005年 | 27篇 |
2004年 | 33篇 |
2003年 | 22篇 |
2002年 | 17篇 |
2001年 | 8篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 11篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 12篇 |
1984年 | 19篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 15篇 |
1980年 | 15篇 |
1979年 | 8篇 |
1978年 | 10篇 |
1977年 | 12篇 |
1976年 | 18篇 |
1975年 | 16篇 |
1974年 | 19篇 |
1973年 | 16篇 |
1968年 | 4篇 |
排序方式: 共有768条查询结果,搜索用时 0 毫秒
61.
Satoru Hommura Yasuhiro Kunisa Ichiro Terada Masaru Yoshitake 《Journal of fluorine chemistry》2003,120(2):151-155
Characteristics of fibril reinforced membranes developed by Asahi Glass Company are reviewed. PTFE-fibrils <1 μm in diameter are dispersed in ion-exchange membranes uniformly. Mechanical properties, such as tensile strength, tear strength, creep property and compressive property were examined and compared with non-reinforced membranes. Fibril reinforced membranes, even by the addition of a small amount of PTFE-fibrils (2.7 wt.%), show excellent mechanical strength, especially in creep and tear strength. Cell performance is nearly equal to the one using a non-reinforced membrane and cell voltage stays about the same during the cell operation at 80 °C for 3000 h. 相似文献
62.
A highly sensitive and simple visual autocatalytic method has been developed for the determination of trace cobalt. The cobalt ion released by the oxidative decomposition of inert bis[2-(5-bromo-2-pyridylazo)-5-(N-propyl-N-sulfopropyl-amino-phenolato] cobaltate (Co(III)-5-Br-PAPS) with peroxomonosulfate acts as a catalyst for the oxidative degradation of the complex. Thus a definite time lapse of degradation is observed by the sudden disappearance of colored Co(III) complexes. The degradation time varies inversely with the logarithm of the initial concentration of cobalt(II). The determination range of cobalt(II) was from 3x10(-9) to 2x10(-7) M in the presence of 5x10(-6) M of 5-Br-PAPS. The relative standard deviation of the spot size method (10 mul) was 3.5% at 1x10(-7) M cobalt(II). This autocatalytic indicator reaction system has been successfully applied for the visual determination of urinary cobalt. 相似文献
63.
Chifei Wu Tada‐Aki Yamagishi Yoshiaki Nakamoto Shin‐Ichiro Ishida Saburo Kubota Koh‐Hei Nitta 《Journal of Polymer Science.Polymer Physics》2000,38(11):1496-1503
The viscoelastic properties and stabilities of those properties of organic hybrids consisting of chlorinated polyethylene (CPE) and tetrakis[methylene‐3‐(3‐5‐di‐tert‐butyl‐4‐hydroxy phenyl)propionyloxy]methane (AO‐60) and triethylene glycol bis[3‐(3‐tert‐butyl‐4‐hydroxy‐5‐methyl phenyl)propionyloxy] (AO‐70) were investigated. The CPE/AO‐70 hybrids show only one transition, whereas for the CPE/AO‐60 hybrids, one novel relaxation appears above the glass‐transition temperature of CPE. This relaxation on the higher temperature side in the mechanical spectrum for CPE/AO‐60 is associated with the appearance of the AO‐60‐rich phase. Furthermore, the stabilities of the viscoelastic properties and microstructures of the organic hybrids consisting of CPE and multifunctional hindered phenols are dominated by the strength of the intermolecular interaction between CPE and phenols and the conformations of the middle skeletal parts of hindered phenols. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1496–1503, 2000 相似文献
64.
Takahiro Takayama Toshiki Mochizuki Kenichiro Todoroki Jun Zhe Min Hajime Mizuno Koichi Inoue Hiroyasu Akatsu Ichiro Noge Toshimasa Toyo'oka 《Analytica chimica acta》2015
Chiral metabolites are found in a wide variety of living organisms and some of them are understood to be physiologically active compounds and biomarkers. However, the overall analysis of chiral metabolomics is quite difficult due to the high number of metabolites, the significant diversity in their physicochemical properties, and concentration range from metabolite-to-metabolite. To solve this difficulty, we developed a novel approach for chiral metabolomics fingerprinting and chiral metabolomics extraction, which is based on the labeling of a pair of enantiomers of chiral derivatization reagents (i.e., DMT-(S,R)-Pro-OSu and DMT-3(S,R)-Apy) and precursor ion scan chromatography of the derivatives. The multivariate statistics is also required for this strategy. The proposed procedures were evaluated by the detection of a diagnostic marker (i.e., d-lactic acid) using the saliva of diabetic patients. This method was used for the determination of biomarker candidates of chiral amines and carboxyls in Alzheimer's disease (AD) brain homogenates. As the results, l-phenylalanine (L-Phe) and l-lactic acid (L-LA) were identified as the decreased and increased biomarker candidates in the AD brain, respectively. Therefore, the proposed approach seems to be helpful for the determination of non-target chiral metabolomics possessing amines and carboxyls. 相似文献
65.
Mizobe Y Ito H Hisaki I Miyata M Hasegawa Y Tohnai N 《Chemical communications (Cambridge, England)》2006,(20):2126-2128
Solid-state fluorescence enhancement was achieved by preparation of rigid packing that was afforded by disposition of benzylamine into tubulate spaces, serving as a powerful and useful strategy for the enhancement. 相似文献
66.
67.
Systematic synthesis of high-mannose-type sugar chains of asparagine-linked glycoproteins is described. To construct the target sugar chains, we employed the convergent route, using three oligosaccharide components, the common hexasaccharide, branched tri-, tetra- and pentasaccharides, and mono-, di-, and triglucosyl fragments. Construction of the β-mannoside linkage was performed using p-methoxybenzyl-assisted intramolecular aglycon delivery. The hexasaccharide fragment was coupled with the branched mannooligosaccharide donors such as M5, M4B, M4C, and M3 to give undecasaccharide (M9), decasaccharide (M8B and M8C), and nonasaccharide (M7), respectively. Incorporation of mono-, di-, and triglucosyl fragments toward them gave tetradecasaccharide (G3M9), tridecasaccharide (G2M9), dodecasaccharide (G1M9), undecasaccharide (G1M8B and G1M8C), and decasaccharide (G1M7), respectively. 相似文献
68.
69.
70.
Hayakawa I Ueda M Yamaura M Ikeda Y Suzuki Y Yoshizato K Kigoshi H 《Organic letters》2008,10(9):1859-1862
Second-generation total synthesis of haterumalide NA, a potent cytotoxic marine macrolide, was achieved by using B-alkyl Suzuki-Miyaura coupling and Nozaki-Hiyama-Kishi coupling as key steps (1.2% in 33 steps). Compared to our first-generation approach, the second-generation synthesis is much improved in the yield of key intermediate. 相似文献