全文获取类型
收费全文 | 831篇 |
免费 | 20篇 |
国内免费 | 2篇 |
专业分类
化学 | 649篇 |
晶体学 | 18篇 |
力学 | 17篇 |
数学 | 48篇 |
物理学 | 121篇 |
出版年
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 7篇 |
2019年 | 16篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 12篇 |
2015年 | 17篇 |
2014年 | 13篇 |
2013年 | 51篇 |
2012年 | 46篇 |
2011年 | 40篇 |
2010年 | 20篇 |
2009年 | 25篇 |
2008年 | 40篇 |
2007年 | 45篇 |
2006年 | 46篇 |
2005年 | 33篇 |
2004年 | 45篇 |
2003年 | 26篇 |
2002年 | 24篇 |
2001年 | 10篇 |
2000年 | 17篇 |
1999年 | 8篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 14篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 11篇 |
1984年 | 18篇 |
1983年 | 5篇 |
1982年 | 12篇 |
1981年 | 15篇 |
1980年 | 15篇 |
1979年 | 7篇 |
1978年 | 9篇 |
1977年 | 11篇 |
1976年 | 18篇 |
1975年 | 14篇 |
1974年 | 18篇 |
1973年 | 15篇 |
1968年 | 4篇 |
排序方式: 共有853条查询结果,搜索用时 15 毫秒
41.
42.
Moon Jeon-Yeol Miura Takatsugu Imae Ichiro Park Dae-Won Kawakami Yusuke 《Silicon Chemistry》2002,1(2):139-143
Disiloxane-arylene polymers having phenylene, biphenylene, and fluorenylene groups as arylene units were synthesized by dehydrocoupling polymerization of corresponding bis(silane) derivatives with water. The reactivity of Si-H was not affected by the structure of aromatic groups in the reaction. The polymers containing biphenylene and fluorenylene units are amorphous and show higher glass transition temperatures than the polymer from 1,4-bis(dimethylsilyl)benzene. 相似文献
43.
Koichiro Shirota Ichirou Yamaguchi Kiyoshi Kanie Tomiki Ikeda Tamejiro Hiyama Ichiro Kobayashi 《Liquid crystals》2013,40(5):555-558
The optical properties of two kinds of photochromic antiferroelectric liquid crystal (AFLC) containing an azo group have been examined. Depending on the substituting group at the chiral centre, these AFLCs showed different photoinduced phase transitions by Ar+ laser light irradiation. This phase transition has led to a new form of optical switching controlled by a bias voltage. In addition, it was found that these AFLCs caused an azimuthal photoalignment effect regulated by linearly polarized Ar+ laser light irradiation. These phenomena were applied to image storage. 相似文献
44.
45.
Miyagawa T Nagai K Yamada A Sugihara Y Fukuda T Fukuda T Uchida R Tomoda H Omura S Nagamitsu T 《Organic letters》2011,13(5):1158-1161
The first total synthesis of citridone A has been achieved through regioselective intramolecular iodocyclization and regio- and stereoselective Pd(0)-catalyzed coupling as key reactions. 相似文献
46.
Hirao I Mitsui T Kimoto M Yokoyama S 《Journal of the American Chemical Society》2007,129(50):15549-15555
Expansion of the genetic alphabet by an unnatural base pair system provides a powerful tool for modern biotechnology. As an alternative to previous unnatural base pairs, we have developed a new pair between 7-(2-thienyl)imidazo[4,5-b]pyridine (Ds) and 2-nitropyrrole (Pn), which functions in DNA amplification. Pn more selectively pairs with Ds in replication than another previously reported pairing partner, pyrrole-2-carbaldehyde (Pa). The nitro group of Pn efficiently prevented the mispairing with A. High efficiency and selectivity of the Ds-Pn pair in PCR amplification were achieved by using a substrate mixture of the gamma-amidotriphosphate of Ds and the usual triphosphates of Pn and the natural bases, with Vent DNA polymerase as a 3' to 5' exonuclease-proficient polymerase. After 20 cycles of PCR, the total mutation rate of the Ds-Pn site in an amplified DNA fragment was approximately 1%. PCR amplification of DNA fragments containing the unnatural Ds-Pn pair would be useful for expanded genetic systems in DNA-based biotechnology. 相似文献
47.
Five‐State Molecular Shuttling of a Pair of [2]Rotaxanes: Distinct Outputs in Response to Acid and Base Stimuli 下载免费PDF全文
Masahiro Ueda Shoya Terazawa Yasuaki Deguchi Masaki Kimura Naoki Matsubara Shinobu Miyagawa Tsuneomi Kawasaki Yuji Tokunaga 《化学:亚洲杂志》2016,11(16):2291-2300
In this study we synthesized two acid‐/base‐controllable [2]rotaxanes featuring aminodiazobenzene and aminocoumarin units, respectively, as chromophores and dibenzo[24]crown‐8 and dibenzo[25]crown‐8 units, respectively, as their macrocyclic components. Each [2]rotaxane contained N‐alkylarylamine (ammonium) and N,N‐dialkylamine (ammonium) centers as binding sites for their crown ether components. The absorption patterns of the chromophores were dependent on the position of the encircling macrocyclic component and the degree of protonation, with three distinct states (under acidic, neutral, and basic conditions) evident for each [2]rotaxane. The mixed [2]rotaxane system displayed stepwise and independent molecular shuttling behavior based on the degree of protonation of the amino groups in response to both the amount and strength of added acids or bases; as such, the system provided five different absorption signals as outputs that could be read using UV/Vis spectroscopy. 相似文献
48.
The perovskite transition-metal oxide ABO3 has been extensively studied in various areas in solids. While the B ion determines the electronic properties, e.g., ferroelectricity, ferromagnetism, and superconductivity, the A site has been regarded as a “back-seat player” to change the doping level or the bandwidth. However, in the ordered perovskite oxide AA′3B4O12, the A site order is closely related to the peculiar electronic states. In CaMn3Mn4O12, the unusually small bandwidth justifies to extrapolate the transport data to the high-temperature limit, and in CaCu3Ru4O12, a novel heavy-fermion state is realized through the Cu–O–Ru interaction. 相似文献
49.
Tomoyuki Manaka Shin‐Ichiro Nagayama Wannaporn Desadee Naoki Yajima Takuya Kumamoto Toshiko Watanabe Tsutomu Ishikawa Masatoshi Kawahata Kentaro Yamaguchi 《Helvetica chimica acta》2007,90(1):128-142
Nucleophilic ring‐opening reactions of 3‐aryl‐1‐benzylaziridine‐2‐carboxylates were examined by using O‐nucleophiles and aromatic C‐nucleophiles. The stereospecificity was found to depend on substrates and conditions used. Configuration inversion at C(3) was observed with O‐nucleophiles as a major reaction path in the ring‐opening reactions of aziridines carrying an electron‐poor aromatic moiety, whereas mixtures containing preferentially the syn‐diastereoisomer were generally obtained when electron‐rich aziridines were used (Tables 1–3). In the reactions of electron‐rich aziridines with C‐nucleophiles, SN2 reactions yielding anti‐type products were observed (Table 4). Reductive ring‐opening reaction by catalytic hydrogenation of (+)‐trans‐(2S,3R)‐3‐(1,3‐benzodioxol‐5‐yl)aziridine‐2‐carboxylate (+)‐trans‐ 3c afforded the corresponding α‐amino acid derivative, which was smoothly transformed into (+)‐tert‐butyl [(1R)‐2‐(1,3‐benzodioxol‐5‐yl)‐1‐methylethyl]carbamate((+)‐ 14 ) with high retention of optical purity (Scheme 6). 相似文献
50.
The trityl group is an important and useful protecting group for primary hydroxy groups on carbohydrates. However, during deprotection, neighboring acetyl groups can easily migrate to the deprotected hydroxy groups. Hence, deprotection of trityl groups was optimized using a microreactor with regard to flow rate, reagent concentration, reaction time, and substrate concentration. The optimized microflow reaction conditions inhibited migration and could be applied to large-scale reactions and other substrates. 相似文献