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51.
A Metal–Organic Framework with Cooperative Phosphines That Permit Post‐Synthetic Installation of Open Metal Sites 下载免费PDF全文
Samuel G. Dunning Gianne Nandra Adam D. Conn Wenrui Chai R. Eric Sikma Ji Sun Lee Pranaw Kunal Joseph E. Reynolds III Jong‐San Chang Alexander Steiner Graeme Henkelman Simon M. Humphrey 《Angewandte Chemie (International ed. in English)》2018,57(30):9295-9299
PCM‐101 is a phosphine coordination material comprised of tris(p‐carboxylato)triphenylphosphine and secondary pillaring groups coordinated to [M3(OH)]5+ nodes (M=Co, Ni). PCM‐101 has a unique topology in which R3P: sites are arranged directly trans to one another, with a P???P separation distance dictated by the pillars. Post‐synthetic coordination of soft metals to the P: sites proceeds at room temperature to provide X‐ray quality crystals that permit full structural resolution. Addition of AuCl groups forces a large distortion of the parent framework. In contrast, CuBr undergoes insertion directly between the trans‐P sites to form dimers that mimic solution‐phase complexes, but that are geometrically strained due to steric pressure exerted by the MOF scaffold. The metalated materials are active in heterogeneous hydroaddition catalysis under mild conditions, yielding different major products compared to their molecular counterparts. 相似文献
52.
John P. Smith III Lorraine M. Males Funda Gonulates 《Mathematical Thinking and Learning》2016,18(4):239-270
Research has found that elementary students face five main challenges in learning area measurement: (1) conserving area as a quantity, (2) understanding area units, (3) structuring rectangular space into composite units, (4) understanding area formulas, and (5) distinguishing area and perimeter. How well do elementary mathematics curricula address these challenges? A detailed analysis of three U.S. elementary textbook series revealed systematic deficits. Each presented area measurement in strongly procedural terms using a shared sequence of procedures across grades. Key conceptual principles were infrequently expressed and often well after related procedures were introduced. Particularly weak support was given for understanding how the multiplication of lengths produces area measures. The results suggest that the content of written curricula contributes to students’ weak learning of area measurement. 相似文献
53.
We prove that if the quotient surface of a properly embedded doubly–periodic minimal surface in ℝ3 has genus zero, then the surface is one of the classical Scherk examples. Oblatum 30-IX-1998 & 18-II-2000?Published online: 30 October 2000 相似文献
54.
Stephen M. Gagola III 《代数通讯》2013,41(4):1436-1448
We prove that if L is a finite Moufang loop and p is a Sylow prime for L then the number of Sylow p-subloops of L is congruent to one modulo p. 相似文献
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We prove that a connected properly immersed minimal surface in with infinite symmetry group and area growth constant less than is a plane, a catenoid, or a Scherk singly-periodic minimal surface. As a consequence, the Scherk minimal surfaces are the only connected periodic minimal desingularizations of the intersections of two planes.
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W.C. Chen R. Erwin J.W. McIver III S. Watson C.B. Fu T.R. Gentile J.A. Borchers J.W. Lynn G.L. Jones 《Physica B: Condensed Matter》2009,404(17):2663-2666
At the NIST Center for Neutron Research (NCNR), we have applied 3He neutron spin filters (NSFs) to the instruments where 3He NSFs are advantageous, such as thermal triple-axis spectrometry, small-angle neutron scattering, and diffuse reflectometry. We present the status of our development and application of this method, including polarized gas production by spin-exchange optical pumping, magnetostatic cavities for storage of the polarized gas on the beam line, and nuclear magnetic resonance (NMR)-based, on-line monitoring and reversal of the 3He polarization. We present the status of developing user-friendly interfaces incorporated into the instrument software to handle these 3He neutron spin filters while taking data and performing data analysis. Finally we discuss the status of development of a polarization capability on the multi-axis crystal spectrometer, which requires polarization analysis over a 220° angular range. 相似文献
59.
Per JensenSteven S. Wesolowski Nicole R. BrinkmannNancy A. Richardson Yukio YamaguchiHenry F. Schaefer III P.R. Bunker 《Journal of Molecular Spectroscopy》2002,211(2):254-261
The potential energy surface and dipole moment surfaces of the ã4A2 electronic state of CH2+ are calculated ab initio using an augmented correlation-consistent polarized valence quadruple-ζ (aug-cc-pVQZ) basis set, with the incorporation of dynamical correlation using the coupled cluster method with single and double excitations and perturbatively connected triple excitations [CCSD(T)]. We use these surfaces in the MORBID program system to calculate rotation and rotation-vibration term values for ã-state CH2+, CD+2, and CHD+ and to simulate the rotation and rotation-vibration absorption spectrum of CH2+ in the ã4A2 electronic state. Our work is motivated by studies of CH2+ that use the Coulomb explosion imaging technique and by the goal of predicting spectra that may be obtained from discharge sources. Although the ã state is the lowest-lying excited state above the X?/Ã ground state pair, it turns out to be relatively high-lying, and we determine that Te(ã)=30447.5 cm−1. The equilibrium bond angle for ã-state CH2+ is only 77.1°; as a result the asymmetric top κ value is close to 0, and the molecule is equally far from the oblate and prolate symmetric top limits in this electronic state. 相似文献
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