Formation of Diol Divinyl Diethers in the Synthesis of 1,2-Epoxy-3-(vinyloxyalkoxy)propanes

Russian Journal of Organic Chemistry -     

Dynamics of a pair of coupled nonlinear oscillators

A pair of coupled classical oscillators with a general potential and general form of coupling is investigated. For general potentials, the single-frequency solution is shown to be stable for small excitations. For special potentials, such system remains stable for an arbitrary excitation. In both cases, the stability does not depend on the form of coupling. Transition to the instability regime follows from the way how nonlinear potential entrains the energy transfer between the oscillators. Relation between the existence of multi-frequency quasi-periodic or periodic solutions and the instability of single-frequency ones is discussed.     

Teaching analytical properties

A new way of expounding analytical properties based on their mutual dependence (complementary and contradictory relationships) and their unequivocal connection with analytical quality facets is presented. To this end, the paper provides answers to the obvious questions that arise in dealing with the subject: why?, how?, when? and where to teach analytical properties in the Analytical Chemistry curriculum?     

Weather Risk in Offshore Projects

Risk analysis tools have been used to help manage various projects. This paper describes a case study in which an extension to the stochastic project network model was developed for a risk analysis of an oil platform installation, quantifying the possible impact of the weather on the project's schedule. Examination of the weather data suggested the use of a Markov weather model combined with a separate residence time distribution for key states. The weather model was incorporated into the stochastic project network allowing the interactions of the various project uncertainties to be examined. While the weather introduced a significant additional risk to the project, analysis of management's options indicated that much of the risk might be avoided. In particular, the analysis quantified the benefits of scheduling the project start to take advantage of the seasonal variations and hiring heavy duty equipment to operate in more arduous conditions.     

Specific high performance liquid chromatographic determination of the molecular weight and concentration of hyaluronic acid in complex mixtures by labelled hyaluronate binding proteins.

A simple High performance liquid chromatographic (HPLC) method for the specific determination of the molecular weight and concentration of hyaluronic acid (HA) in complex mixtures has been developed. Hyaluronate-binding proteins isolated from bovine cartilage labelled by 125I or fluoresceinisothiocyanate were used as specific markers. The specific binding affinities of the markers were compared and were found to have association constants of 1.6 x 10(7) M-1 and 1.2 x 10(7) M-1 respectively. The HA levels and molecular weight distributions can be easily determined in the range 10-500 ng/mL in complex mixtures by the use of markers, molecular sieving HPLC columns and appropriate detectors. It has been demonstrated clearly that the method is useful for the highly specific determination of the parameters in complex biological samples such as serum and synovial fluids and is recommended for clinical applications.     

Analysis of appearance of moving ionospheric disturbances of the “sickle” type at middle latitudes

We present the results of analysis of the data of vertical ionospheric sounding at the Zimenki test site (Nizhny Novgorod). The January and July ionograms are used to plot the dependences of the number of “sickle” type disturbances on the time of the day for the period from 1996 to 1992. A comparison with the scattering in an ionospheric F-layer for the same period is performed. A trend in the time series of the phenomenon observed is recorded. Radiophysical Research Institute, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 40, No. 12, pp. 1455–1462, December, 1997.