Synthesis and structures of nitroxyalkyl methylphosphonates

The reactions of ethylene glycol mononitrate and glycerol 1,3-dinitrate with methylphosphonic dichloride afforded new nitroxyalkyl methylphosphonates.     

To the description of hadron mass spectrum in the nonrelativistic quark potential model

The comparison of different confinement models of hadrons in non-relativistic quark potential model with the use of hyperspherical functions is carried out in the present work. Numerical values of the masses of non-strange (the lightest) hadrons belonging to the meson octet and baryon decuplet are obtained in this model. The best values of masses are obtained with the potential which incorporates the quasi-relativistic one-gluon exchange and the confinement termAr ⁿ withn=2/3. The natural appearance of the Yukawa-type potential in this model is also discussed.     

Dominant structures in jet streams

A Hamiltonian version has been formulated for the model of axisymmetric equally rotating jet streams with a free boundary. In the framework of this approach, dominant structures, i.e., structure elements appearing in strongly disturbed jet streams at the preturbulent stage of their decay, are studied. It has been shown that compactons, i.e., solution with a compact support, can be such dominant structures. Analysis of the mechanism of the instability of compactons shows the possibility of collapse, which occurs almost without deformation of their shape but leads to the intensification of the vortex sheet at the boundary according to the law (t ₀ ? t)^?1, where t ₀ is the collapse time.     

Bragg diffraction of light in a restricted homogeneous system of tunnel-coupled waveguides

A system of tunnel-coupled rectilinear waveguides is studied. The dependence of the number of modes in this system on the number of waveguides N, the distance between the waveguides, and the number of modes in a separate waveguide is considered. It is shown that the modes of the m = N and N + 1 orders in such a system are Bragg modes; i.e., the angle between the direction of their propagation and the system axis is close to the Bragg angle. The effective refractive indices n ^* of these modes change stepwise. The step size Δn ^* is found to be dependent on the distance s between the waveguides and on the number of modes in a separate waveguide. A system of single-mode waveguides with the number of guided modes M = 34 < N = 50 is studied experimentally. It is shown that the Bragg modes of the system lie among the leakage modes of the system and have rather low losses. It is demonstrated that the localization of the Bragg modes among the leakage modes may be favorable for their selection upon light generation.     

NMR protocol for on-line Brix determination

Water suppression by diffusive attenuation was used to measure Brix in intact cellular tissue of apple and strawberry. Given the signal-to-noise ratio, the correlation for apple was established without repeated acquisition, so this protocol should also be useful for rapid, on-line measurements at low spectrometer frequencies. Water suppression by theT ₁-Null method fails with cellular tissue because of the considerable variation in the longitudinal relaxation times of vacuolar and cytoplasmic water.     

Temperature dependence of interband transition energy in InGaAsN strain-compensated quantum-well and ridge-waveguide lasers fabricated with pulsed anodic oxidation

Ridge-waveguide InGaAsN triple-quantum-well strain-compensated lasers grown by metal organic chemical vapor deposition were fabricated with pulsed anodic oxidation. The laser’s output power reached 145 mW in continuous-wave mode at room temperature for a 4-?m -stripe-width laser. Continuous-wave single longitudinal mode operation was maintained at a high injection current level with a wavelength of 1287.3 nm at room temperature. Single longitudinal mode operation at 1317.2 nm was achieved at twice the threshold current at 100 °C. The band gap of InGaAsN in the quantum wells at different temperatures was calculated and compared to the measured temperature-dependent laser wavelength.     

Anomalous electromagnetic waves in a multicomponent insulator

The permittivity of an amorphous insulator consisting of several types of molecules is found. The concepts of polarizability averaged over molecule types and of polarizability fluctuation are introduced, which, when taken into consideration, impart dispersive properties to the permittivity of the medium. It is shown that, near the frequencies at which the average polarizability vanishes, the permittivity depends on the average quadratic fluctuation of the molecular polarizability. Anomalous electromagnetic waves in these frequency intervals are considered.     

Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes

Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F₂Si(OCH₂CH₂)₂NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by ¹H, ¹³C, ¹⁵N, ¹⁹F, ²⁹Si NMR and IR spectroscopy.     

Global Optimization of Stochastic Black-Box Systems via Sequential Kriging Meta-Models

This paper proposes a new method that extends the efficient global optimization to address stochastic black-box systems. The method is based on a kriging meta-model that provides a global prediction of the objective values and a measure of prediction uncertainty at every point. The criterion for the infill sample selection is an augmented expected improvement function with desirable properties for stochastic responses. The method is empirically compared with the revised simplex search, the simultaneous perturbation stochastic approximation, and the DIRECT methods using six test problems from the literature. An application case study on an inventory system is also documented. The results suggest that the proposed method has excellent consistency and efficiency in finding global optimal solutions, and is particularly useful for expensive systems.     

Transverse susceptibility as the low-frequency limit of ferromagnetic resonance

A new theory of transverse susceptibility (TS) based on magnetization vector dynamics, as described by the Landau–Lifshitz equation of motion, is given. It is shown that the traditional TS experiment is, in fact, the zero-frequency limit of the ferromagnetic resonance (FMR). The importance of these results resides in the generality of the approach which allows one to find the TS for virtually any magnetic system if an expression for the magnetic free-energy density is known. Moreover, the effect of the frequency of excitatory AC field on the TS experiments and the effect of energy dissipation through the imaginary part of TS emerge coherently from the new TS model.