New solvent for polyrotaxane. II. Dissolution behavior of polyrotaxane in ionic liquids and preparation of ionic liquid‐containing slide‐ring gels

The dissolution behavior of polyrotaxanes, consisting of α‐cyclodextrin and poly(ethylene glycol), with different molecular weights (2000 and 35,000) was investigated. Halogen‐containing ionic liquids, such as chlorides or bromides, were found to be good solvents for polyrotaxanes, regardless of their cations. Dissolution required a high temperature (above 90 °C), while intensive heating over 105 °C seemed to cause decomposition of the polyrotaxane. The discovery of new solvents for polyrotaxane was applied in the preparation of ionic liquid‐containing slide‐ring gels (SR gels), that is supramolecular networks of polyrotaxane swollen with ionic liquids, using a devised “non‐drying” technique accompanied by solvent exchange. Significant swelling of the SR gels with the ionic liquids was confirmed by dynamic mechanical measurements. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1985–1994, 2006     

Radical reactions initiated by the photochemical cleavage of carbon-indium bonds of organoindium compounds

Intra- and intermolecular reactions of carbon-centered radicals generated by photolysis of organoindium compounds were examined. The photolysis of vinylindium compounds and indium acetylides provided vinyl and alkynyl radicals, respectively, which were trapped with ethyl iodoacetate giving the corresponding β,γ-unsaturated esters. Allylic indium compounds, prepared from 8-bromo- or 8-iodooct-1,6-dienes and powdered indium metal, underwent an intramolecular radical cyclization to afford the 5-exo-trig product.     

Determination of a merocyanine J-aggregate structure and the significant contribution of the electric dipole interaction to the exciton band wavelength

The molecular alignment of a merocyanine (MC) J-aggregate monolayer at the air-water interface was determined by a grazing incidence x-ray diffraction method. The obtained molecular arrangement apparently shows that the conventional formula, which accounts only for the transition dipole interaction, is not sufficient to figure out the exciton band wavelength, suggesting the importance of the electric dipole (ED) interaction. We derived a simple formula for the ED interaction energy under an extended dipole approximation and clarified the ED contribution in the MC J aggregate.     

Measurement of neutrino oscillation with KamLAND: evidence of spectral distortion

We present results of a study of neutrino oscillation based on a 766 ton/year exposure of KamLAND to reactor antineutrinos. We observe 258 nu (e) candidate events with energies above 3.4 MeV compared to 365.2+/-23.7 events expected in the absence of neutrino oscillation. Accounting for 17.8+/-7.3 expected background events, the statistical significance for reactor nu (e) disappearance is 99.998%. The observed energy spectrum disagrees with the expected spectral shape in the absence of neutrino oscillation at 99.6% significance and prefers the distortion expected from nu (e) oscillation effects. A two-neutrino oscillation analysis of the KamLAND data gives Deltam(2)=7.9(+0.6)(-0.5)x10(-5) eV(2). A global analysis of data from KamLAND and solar-neutrino experiments yields Deltam(2)=7.9(+0.6)(-0.5)x10(-5) eV(2) and tan((2)theta=0.40(+0.10)(-0.07), the most precise determination to date.     

Synthetic key intermediates of glycocinnamoylspermidines ; diaminohexosyloxycinnamate and aminopentose disaccharide moieties

Two key intermediates for the total synthesis of glycocinnamoylspermidines were derived from the corresponding 2-azido sugars.     

Golden-Thompson and Peierls-Bogolubov inequalities for a general von Neumann algebra

Some inequalities for a general von Neumann algebra, which reduces to Golden-Thomspon and Peierls-Bogolubov inequalities when the von Neumann algebra has a trace, are proved.     

Collision cross sections in terms of local observables

Asymptotic relations for matrix elements of quasilocal operators are given which generalize and extend the Lehmann-Symanzik-Zimmermann relations. These relations allow the simulation of a coincidence arrangement of particle detectors in the mathematical frame of the theory and thereby the expression of collision cross sections in terms of expectation values of observables.This paper results from the collaboration of the authors during the winter semester 63/64 at Urbana, Illinois and was partly supported by the NSF.     

Coherent apodization problems

Apodization problems in coherent imagery of removing the edge ringing effect are proposed by considering the edge shifting phenomenon and the passivity of the optical imaging system and are solved by means of the calculus of variations. The resultant pupil functions and corresponding edge image intensity distributions are presented and discussed.     

A remark on transition probability

Uhlmann's transition probability P(ψ, φ) of two normal states of a von Neumann algebra M, which is the supremum of |(Ψ, Φ)|² for all possible choices of representative vectors Ψ and Φ of ψ and φ, is shown to be the infimum of (∫d(μ_{ψ, e})^1/2)² for the induced measures μ_{ω, e}(B)=ω(e(B)) (B: Borel set in ℝ, ω=ψ, φ) for all possible projection-valued measures e belonging to M.