全文获取类型
收费全文 | 176篇 |
免费 | 32篇 |
国内免费 | 36篇 |
专业分类
化学 | 68篇 |
晶体学 | 3篇 |
力学 | 2篇 |
综合类 | 3篇 |
数学 | 31篇 |
物理学 | 137篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 5篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 8篇 |
2014年 | 9篇 |
2013年 | 9篇 |
2012年 | 4篇 |
2011年 | 6篇 |
2010年 | 5篇 |
2009年 | 9篇 |
2008年 | 15篇 |
2007年 | 13篇 |
2006年 | 7篇 |
2005年 | 17篇 |
2004年 | 10篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1983年 | 3篇 |
1972年 | 1篇 |
排序方式: 共有244条查询结果,搜索用时 463 毫秒
71.
A polynomial expansion is proposed as a new way to discretize the Griffin-Wheeler-Hartree-Fock equations of the Generator Coordinate Hartree-Fock method. The implementation of the polynomial expansion in the Generator Coordinate Hartree-Fock method discretizes the Griffin-Wheeler-Hartree-Fock equations through a numerical mesh which is not equally spaced. This procedure makes the optimization of Gaussian exponents in the Generator Coordinate Hartree-Fock method more flexible and more efficient. The results obtained with the polynomial expansion for atomic Hartree-Fock energies show this technique is very powerful when employed in the design of compact and high accurate Gaussian basis sets used in ab initio non-relativistic (Hartree-Fock) and relativistic (Dirac-Fock) calculations. 相似文献
72.
COMPONENT ALLEE EFFECTS AND STAGE‐SPECIFIC PREDATION: A BRIEF INSIGHT INTO CONSERVATION AND BIOLOGICAL CONTROL ISSUES
下载免费PDF全文
![点击此处可从《Natural Resource Modeling》网站下载免费的PDF全文](/ch/ext_images/free.gif)
In this paper, we propose a two‐stage structured population model subject to component Allee effects in fecundity and maturation, and with two disturbances (predation only and harvest and predation) acting on both stages. It is shown that this combination leads to a demographic Allee effect—a characteristic that could be exploited in pest biological control, but on the other hand, it represents a bane in conservation biology. The analysis is performed for disturbances with functional responses type 2 and 3, and the models show that they yield qualitatively similar results. This characteristic is discussed from the species conservation and biological control point of view, together with possible extensions of this work. 相似文献
73.
74.
75.
76.
Heyne K Huse N Dreyer J Nibbering ET Elsaesser T Mukamel S 《The Journal of chemical physics》2004,121(2):902-913
Ultrafast vibrational dynamics of cyclic hydrogen bonded dimers and the underlying microscopic interactions are studied in temporally and spectrally resolved pump-probe experiments with 100 fs time resolution. Femtosecond excitation of the O-H and/or O-D stretching mode gives rise to pronounced changes of the O-H/O-D stretching absorption displaying both rate-like kinetic and oscillatory components. A lifetime of 200 fs is measured for the v=1 state of the O-H stretching oscillator. The strong oscillatory absorption changes are due to impulsively driven coherent wave packet motions along several low-frequency modes of the dimer between 50 and 170 cm(-1). Such wave packets generated via coherent excitation of the high-frequency O-H/O-D stretching oscillators represent a clear manifestation of the anharmonic coupling of low- and high-frequency modes. The underdamped low-frequency motions dephase on a time scale of 1-2 ps. Calculations of the vibrational potential energy surface based on density functional theory give the frequencies, anharmonic couplings, and microscopic elongations of the low-frequency modes, among them intermolecular hydrogen bond vibrations. Oscillations due to the excitonic coupling between the two O-H or O-D stretching oscillators are absent as is independently confirmed by experiments on mixed dimers with uncoupled O-H and O-D stretching oscillators. 相似文献
77.
78.
A fluorocarbon-modified poly(N-isopropylacrylamide) has been synthesized by copolymerization of N-isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( > 0.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol% ) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding Nad and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbo 相似文献
79.
80.
Interest in zirconia as a chromatography support has increased considerably recently because of its chemical inertness and its promise as a useful support. We have reported the preparation of spherical zirconia and characterization of its chromatographic behavior. However, the zirconia was found unsatisfactory for its chromatographic efficiency, probably owing to the poor pore structure of it. In this paper, we for the first time report the preparation of alkylphosphonic acid modified zirconia-magnesia stationary phase, and characterization of its structure and chromatographic behavior. 相似文献