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991.
992.
993.
An HPLC method with polarographic detection for the trace determination of artemether in plasma and whole blood was developed and applied to pharmacokinetic and clinical pharmacological studies. The method showed high sensitivity and selectivity because of the easy reduction of the peroxide linkage of artemether at the mercury drop electrode. The detection limit was 10 ng and the detector response was linear over the range of 10 ng to 1 microgram artemether injected onto the column. The largest relative standard deviation of 10 replicate measurements of standard solutions (concentrations of 10 ng/mL-1 microgram/mL) was 8%. The recovery from whole blood and plasma of added drug (concentrations of 15-480 ng/mL) was 71-100%. 相似文献
994.
995.
The template-directed fabrication of highly-ordered porous film is of significant importance in implementation of the photonic band gap structure. The paper reports a simple and effective method to improve the electrodeposition of metal porous film by utilizing highly-ordered polystyrene spheres (PSs) template. By surface-modification method, the hydrophobic property of the PSs template surfaces was changed into hydrophilic one. It was demonstrated that the surface modification process enhanced the permeability of the electrolyte solution in the nanometer-sized voids of the colloidal template. The homogeneously deposited copper film with the highly-ordered voids in size of less than 500 nm was successfully obtained. In addition, it was found that large defects, such as microcracks in the template, strongly influenced the macroporous films quality. An obvious preferential growth in the cracked area was observed. 相似文献
996.
997.
This paper is concerned with coupled linear forward-backward stochastic differential equations(FBSDEs, for short). When the homogeneous coefficients are deterministic(the non-homogeneous coefficients can be random), we obtain an Lp-result(p > 2), including the existence and uniqueness of the p-th power integrable solution, a p-th power estimate, and a related continuous dependence property of the solution on the coefficients, for coupled linear FBSDEs in the monotonicity framework ... 相似文献
998.
Xiangdong Xie 《Mathematische Zeitschrift》2008,259(2):249-253
We establish a Bowen type rigidity theorem for the fundamental group of a noncompact hyperbolic manifold of finite volume
(with dimension at least 3).
相似文献
999.
Photoionization Detector for Portable Rapid GC 总被引:1,自引:0,他引:1
With the development of portable rapid gas chromatography (GC) for environmental monitoring the photoionization detector (PID)
has potential application. The frequent calibration required and the relatively large dead volume have limited the use of
the PID, however. An improved PID which resolves these problems is proposed in this paper. Compared with a commercial instrument,
signal generation, the main aspect of the improved PID, has also been optimized. In the improved PID the sample is directed
to flow across the lamp window, rather than toward the lamp, and a new, simple automatic self-cleaning technique, which effectively
eliminates contaminants and substantially reduces drift, has also been adopted. Use of new electrodes has effectively reduced
the background noise and dead volume of the PID. As a result of this new design the PID should be more compatible with rapid
portable GC in environmental monitoring, because of elimination of most of the tedious cleaning and calibration previously
necessary. 相似文献
1000.
为了探究丝氨酸蛋白酶催化效率的来源,本文分别研究了丝氨酸酶催化水解多肽CI2、MCTI-A和六肽(SUB)的过程中催化三元组内的氢键所起的作用. 首先采用QM/MM-MD方法计算了在酶-底物复合物和过渡态下组氨酸和天冬氨酸之间质子转移的自由能曲线. 结果表明低能垒氢键仅在CI2酰化反应的过渡态区域形成,而在MCTI-A和SUB酰化反应中均是正常氢键. 与MCTI-A相比,CI2和SUB体系中氢键强度在过渡态时显著增强,因此相应的酰化反应能垒明显降低. 过渡态区域形成的低能垒氢键显然有助于加速酰化反应,同时研究也表明正常氢键也有可能降低能垒. 氢键降低能垒的关键则在于过渡态下氢键强度的增加程度,而不是其是否生成了低能垒氢键. 本文为研究催化三元组间的氢键在丝氨酸蛋白酶中的作用提供了新思路,并有助于理解丝氨酸蛋白酶中催化三元组的催化机制. 相似文献