The critical behavior of the spin-1 bond and crystal field dilution Blume–Emery–Griffiths model have been investigated on simple-cubic lattice within the framework of the effective field theory. In particular, both bond dilution and random crystal field are considered at the same time. The interplay between bond and crystal field dilution constructs rich and interesting phase diagrams. Significant distinctions are exhibited. When positive ratio α changes in a certain range, there exist double tricritical points in phase-transition lines in T–D plane. Moreover, this first-order phase transition is enlarged with increasing of ratio α at a fixed crystal field dilution concentration, while this first-order phase transition will shrink when bond dilution concentration is fixed. In addition, we observe that there exist two bond percolation thresholds for negative crystal field and α>0 in T–P plane. 相似文献
Dy3+-doped NaGd(WO4)2 crystal with sizes of about Φ20×40 mm2 was grown by the Czochralski technique along the (0 0 1) orientation. Polarized absorption spectra, fluorescence spectra, and fluorescence decay curve of Dy3+-doped NaGd(WO4)2 have been recorded at room temperature. Based on the Judd-Ofelt (J-O) theory, the intensity parameters from the measured line strengths were evaluated. The J-O parameters were used to predict radiative transition probabilities, radiative lifetimes and branching ratios for various excited levels of Dy3+-doped NaGd(WO4)2 crystal. The luminescent quantum efficiency of the 4F9/2 level was determined to be approximately 63% for this material. The emission cross-section of the 4F9/2→6H13/2 transition was estimated by using the Füchtbauer-Ladengurg method. 相似文献
Acanthosphere-like gold microstructures (AGMs) were synthesized using a facile, two-step, seed-mediated method and butanediyl-1,4-bis(dimethylhexadecylammonium bromide) (16-4-16) as a structure-directing agent. The morphologies and sizes of the products were controlled during the synthesis process by adjusting the concentrations of 16-4-16, the AgNO3 feed, HAuCl4, ascorbic acid, the amount of Ag seeds and the types of gemini surfactants used through systematic inquiry; particle sizes ranging from 130 to 800 nm were well prepared. Correspondingly, the morphology of the products changed between regular and irregular AGMs, and the products presented a number of new morphologies, such as open-mouthed submicrostructures and ribbon nanowires. In particular, with the increase in the 16-4-16 concentration, the structural morphology of the thorns clearly changed from a tip to a lamellar structure. A UV-vis spectroscopic analysis indicated that the localized surface plasmon resonance (LSPR) peak of the AGMs could be adjusted by changing the above factors, which extended from 500 to 1350 nm in the near-infrared (NIR) region, enabling a tremendous potential for using the AGMs as platforms for various biomedical applications. Based on the intermediate products, we propose a two-stage growth mechanism for the AGMs in which their solid cores and tips are generated successively. Surface-enhanced Raman scattering (SERS) measurements indicate that the AGMs can serve as sensitive SERS substrates; a SERS detection limit of 5 × 10?7 M is presented for rhodamine B molecules.
Polycyclic aromatic hydrocarbons doped by metal have exhibited the potential of high temperature superconductivity. Understanding the basic properties of materials is the key to reveal the superconductivity. Here, a systemically theoretical study has been done to explore crystal structures and electronic properties of pristine and potassium-doped 1,2;8,9-dibenzopentacene, compared with [7]phenacenes case. We determined that vdW-DF2 functional is more suitable to describe the non-local interaction in a molecular crystal. Based on this functional, we predicted the crystal structures and investigated in detail the K atomic positions in a system. It was found that the intralayer doping leads to lower total energy. From the calculated formation energy, for each 1,2;8,9-dibenzopentacene molecule, the doping of two electrons is more stable under the relatively K-poor condition while the doping of four electrons is more stable under the K-rich condition. Between these two phases, the three-electron doping phase stabilises in a narrow region of K chemical potential. Combining with the electronic states at Fermi level, we analysed the reasons of superconductivity enhancement in doped 1,2;8,9-dibenzopentacene. This work further deepens the understanding of 1,2;8,9-dibenzopentacene superconductor. 相似文献
In this paper, a novel strategy for the fabrication of reduced graphene oxide (rGO)/Cu8S5/polypyrrole (PPy) composite nanosheets with Cu8S5 nanoparticles and PPy layer anchored on the surface of rGO as peroxidase‐like nanocatalyst is reported. During the synthesis, graphene oxide (GO)/CuO composite nanosheets are prepared first and used as templates, then the sulfuration of CuO and polymerization of pyrrole are accompanied with the reduction of GO, resulting in ternary rGO/Cu8S5/PPy composite nanosheets. The synthesized Cu8S5 nanoparticles with a diameter in the range from tens to hundreds of nanometers are dispersed within PPy decorated rGO nanosheets. The resultant ternary rGO/Cu8S5/PPy composite nanosheets exhibit a higher peroxidase‐like catalytic activity toward the oxidation of 3,3′,5,5′‐tetramethylbenzidine in the presence of H2O2 than GO/CuO and rGO/CuS composite nanosheets, revealing a synergistic effect on their activity. The as‐prepared rGO/Cu8S5/PPy platform provides a simple colorimetric approach for the detection of H2O2 and phenol with a high sensitivity. This work offers a new way for the fabrication of rGO‐based nanocomposite with superior enzyme‐like activity, which displays great potential applications in biocatalysis and environmental monitoring. 相似文献
Boolean functions have very nice applications in coding theory and cryptography. In coding theory, Boolean functions have been used to construct linear codes in different ways. The objective of this paper is to construct binary linear codes with few weights using the defining-set approach. The defining sets of the codes presented in this paper are defined by some special Boolean functions and some additional restrictions. First, two families of binary linear codes with at most three or four weights from Boolean functions with at most three Walsh transform values are constructed and the parameters of their duals are also determined. Then several classes of binary linear codes with explicit weight enumerators are produced. Some of the binary linear codes are optimal or almost optimal according to the tables of best codes known maintained at http://www.codetables.de, and the duals of some of them are distance-optimal with respect to the sphere packing bound.