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81.
The canonical quantization of the photon field in covariant gauge is studied in the presence of static boundaries, on which the field satisfies either “bag” or superconductor boundary conditions. The inclusion of the Fadeev-Popov ghost fields is found to be essential for agreement with Coulomb gauge calculations of the Casimir energy. 相似文献
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84.
Hughes CE Carravetta M Levitt MH 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,167(2):306-265
Cogwheel phase cycles are often significantly shorter than traditional nested phase cycles. However, optimal solutions for cogwheel cycles are often difficult to find. This paper presents techniques and conjectures which the authors have found useful for generating cogwheel phase cycles either without the need for computer searches or with significantly smaller searches than would otherwise be necessary. The conjectures presently lack proofs but have been tested successfully for a large number of cases. 相似文献
85.
F. C. Camargo A. F. Lehner J. D. Harkins C. G. Hughes W. Karpiesiuk J. Boyles W. E. Woods T. Tobin 《Chromatographia》2004,60(7-8):371-378
Trimetoquinol (TMQ) (1-(3,4,5-trimethoxybenzyl)-6,7-dihydroxy-1,2,3,4-tetrahydroisoquinoline, m.w. 345) is the prototype tetrahydroisoquinoline pharmaceutical. TMQ is marketed as a bronchodilator in human medicine; in horse racing, TMQ is listed as an Association of Racing Commissioners International (ARCI) class 3 foreign substance. As such, TMQ is considered to have the potential to affect racing performance in horses, and a validated qualitative confirmatory method is required to regulate its use in racing. We selected 8 g kg–1 of TMQ IV as a safe and effective dose for studies on its metabolism and analytical detection in horses. We developed a solid phase extraction method for recovery of TMQ and its metabolites from equine urine, identified suitable high performance liquid chromatographic conditions for these substances and our internal standard, papaverine, and developed a highly sensitive ESI(+)-LC-MS-MS method (estimated LOD, 100 pg mL–1) for TMQ and its major metabolites in equine urine. Multiple Reaction Monitoring (MRM) analysis of unhydrolyzed post-administration urine showed small amounts of unchanged TMQ, along with glucuronide, methylated, and sulfated metabolites, with glucuronide metabolites predominating. Following glucuronidase hydrolysis, recovered parent TMQ peaked at relatively high concentrations (>300 ng mL–1) within 1 h of administration and thereafter declined. The methylated metabolites of TMQ peaked later and at comparable total concentrations, and thereafter declined more slowly. These data suggest that glucuronide hydrolysis of post-administration urine samples will allow recovery of readily identifiable quantities of parent TMQ. These findings, combined with the highly sensitive LC-MS-MS detection of parent TMQ described herein suggest that glucuronide hydrolysis of post-administration urine, followed by LC-MS-MS or other analysis, will allow effective regulatory control of this agent in racing horses.Published as # 351 from the Equine Pharmacology, Therapeutics and Toxicology Program at the Maxwell H. Gluck Equine Research Center and Department of Veterinary Science, University of Kentucky. Published as Kentucky Agricultural Experiment Station Article # 04-14-048 with the approval of the Dean and Director, College of Agriculture and the Kentucky Agricultural Experimental Station.Revised: 8 June and 12 July 2004 相似文献
86.
An efficient synthesis of o-nitrobenzylcarbonyl compounds is demonstrated through the Swern-type oxidation of readily accessible phenethanol analogues. Reductive cyclization of o-nitrobenzylcarbonyl 3 using catalytic Raney nickel gives 1H-indol-2-yl-1H-quinoline 2 in 95% yield. Hydrolysis of 2 affords the KDR kinase inhibitor 1 in quantitative yield. The examination of the reductive cyclization reaction and optimization of conditions is described. 相似文献
87.
Rigal LB Schmadel DC Drew HD Maiorov B Osquiguil E Preston JS Hughes R Gu GD 《Physical review letters》2004,93(13):137002
The infrared (900-1100 cm(-1)) Faraday rotation and circular dichroism are measured in the normal state of underdoped High T(c) superconductors and used to study the magnetotransport. YBa2Cu3O6+x thin films are investigated in the temperature range 10-300 K in magnetic fields up to 8 T and as a function of oxygen concentration. A dramatic increase of the Hall frequency is observed for underdoped samples, which is not consistent with the approach to a Mott transition but is consistent with a partial gapping of the Fermi surface as predicted in density wave models. 相似文献
88.
Hughes S 《Optics letters》2004,29(22):2659-2661
A theoretical formalism is presented to investigate enhanced radiative decay of excited dipoles in photonic crystal waveguides and nanocavities with a view to achieving efficient single-photon emission from embedded quantum dots. Surprisingly, large enhancement effects are achievable in both waveguides and nanocavities, and enhanced emission in the waveguide is shown to scale proportionally (inversely) with the photon group index (velocity). Further, a way to include radiative coupling of the quantum dot is shown, and the importance of its inclusion is subsequently demonstrated. 相似文献
89.
A semiclassical analysis of a two-dimensional electron droplet in a high, nonuniform magnetic field predicts that the droplet will form "fingered" patterns upon increasing the number of electrons. We construct explicit examples of these patterns using methods first developed for the flow of two-dimensional viscous fluids. We complement our analytical results with Monte Carlo simulations of the droplet wave function, and find that at the point where the semiclassical analysis predicts a cusp on the interface, the droplet fissions-a type of "quantum breakup" phenomenon. 相似文献
90.