中低变质程度煤显微组分结构的13 C-NMR研究

利用13C-NMR核磁共振技术对中低变质程度煤显微组分（镜质组和惰质组）的分子结构进行了研究,计算了5种煤9个显微组分的13C-NMR结构参数,获得了样品的结构特征及变化规律。结果表明,惰质组结构中芳构化程度要高于镜质组;脂碳数量则少于镜质组,芳环上的烷烃侧链也没有镜质组长;随着煤变质程度的提高,煤分子中芳构化程度不断提高,但惰质组的芳香度随变质程度变化的规律明显不如镜质组;在中低变质阶段,对煤化进程起主导作用的的是芳构化作用而不是环缩合作用,但在惰质组中脂碳断裂形成芳环的现象不明显。惰质组中含氧官能团的总量要低于同等变质程度的镜质组。     

Synthesis and photophysical characterization of a titanium(IV) phthalocyanine-C60 supramolecular dyad

An axially substituted titanium(IV) phthalocyanine-fullerene donor-acceptor supramolecular dyad has been prepared by two different approaches, one of them representing a convenient convergent strategy. The dyad system exhibits photoinduced electron transfer upon irradiation with visible light to produce a microsecond lived charge separated state.     

Intersections and Translative Integral Formulas for Boundaries of Convex Bodies

Let K, L ⊂ ℝⁿ be two convex bodies with non–empty interiors and with boundaries ∂K, ∂L, and let χ denote the Euler characteristic as defined in singular homology theory. We prove two translative integral formulas involving boundaries of convex bodies. It is shown that the integrals of the functions t ↦ χ(∂K ∩ (∂L + t)) and t ↦ χ(∂K ∩ (L + t)), t ∈ ℝⁿ, with respect to an n–dimensional Haar measure of ℝⁿ can be expressed in terms of certain mixed volumes of K and L. In the particular case where K and L are outer parallel bodies of convex bodies at distance r > 0, the result will be deduced from a recent (local) translative integral formula for sets with positive reach. The general case follows from this and from the following (global) topological result. Let K_r, L_r denote the outer parallel bodies of K, L at distance r ≥ 0. Establishing a conjecture of Firey (1978), we show that the homotopy type of ∂K_r ∩ ∂L_r and ∂K_r ∩ L_r, respectively, is independent of r ≥ 0 if K° ∩ L° ≠ ∅︁ and if ∂K and ∂L intersect almost transversally.As an immediate consequence of our translative integral formulas, we obtain a proof for two kinematic formulas which have also been conjectured by Firey .     

Excimer laser pumped by an intense, high-energy heavy-ion beam

High-energy heavy ions are an ideal tool to generate homogeneously excited, extended volumes of nonthermal plasmas. Here, the high-energy loss (dE/dx) and absolute power deposition of heavy ions interacting with matter has been used to pump an ultraviolet laser. A pulsed 70 MeV/u 238U beam with up to 2.5 x 10(9) particles in approximately 100 ns beam bunches was stopped in a 1.2 m long laser cell filled with a 1.6 bar Ar-Kr-F2 mixture (typically 50%:49.9%:0.1%). Laser effect on the 248 nm KrF* excimer transition is clearly demonstrated.     

Poisson polyhedra in high dimensions

The zero cell of a parametric class of random hyperplane tessellations depending on a distance exponent and an intensity parameter is investigated, as the space dimension tends to infinity. The model includes the zero cell of stationary and isotropic Poisson hyperplane tessellations as well as the typical cell of a stationary Poisson Voronoi tessellation as special cases. It is shown that asymptotically in the space dimension, with overwhelming probability these cells satisfy the hyperplane conjecture, if the distance exponent and the intensity parameter are suitably chosen dimension-dependent functions. Also the high dimensional limits of the mean number of faces are explored and the asymptotic behaviour of an isoperimetric ratio is analysed. In the background are new identities linking the f-vector of the zero cell to certain dual intrinsic volumes.     

Kinetics and mechanism of sensitized photooxidation of tetramethylammonium salt of 2-(phenylthio)acetic acid in solution: Steady-state and flash photolysis studies

The mechanism for the photo-induced oxidation of the tetramethylammonium salt of 2-(phenylthio)acetic acid was elucidated. The photosensitizer was the benzophenone triplet in acetonitrile solutions. Time-resolved absorption spectra and kinetics were used to follow the intermediates which included the triplet of benzophenone, the ketyl radical of benzophenone, and an ion pair consisting of a radical anion of benzophenone and a tetramethylammonium cation. Rate constants for the growth and decay of the transients were determined along with the quantum yields of the transients. The intermediacy of other radicals was inferred by the products observed following steady-state photolysis. Quantum yields were also determined for photoproducts resulting from the steady-state irradiation. The mechanism was proposed that rationalized the quantitative observations. Of particular note was how the nature of the counter ion effected the secondary reactions of the radicals and the radical ions.     

Isotope ratio monitoring gas chromatography/Mass spectrometry of D/H by high temperature conversion isotope ratio mass spectrometry

Of all the elements, hydrogen has the largest naturally occurring variations in the ratio of its stable isotopes (D/H). It is for this reason that there has been a strong desire to add hydrogen to the list of elements amenable to isotope ratio monitoring gas chromatography/mass spectrometry (irm-GC/MS). In irm-GC/MS the sample is entrained in helium as the carrier gas, which is also ionized and separated in the isotope ratio mass spectrometer (IRMS). Because of the low abundance of deuterium in nature, precise and accurate on-line monitoring of D/H ratios with an IRMS requires that low energy helium ions be kept out of the m/z 3 collector, which requires the use of an energy filter. A clean mass 3 (HD(+.)) signal which is independent of a large helium load in the electron impact ion source is essential in order to reach the sensitivity required for D/H analysis of capillary GC peaks. A new IRMS system, the DELTA(plus)XL(trade mark), has been designed for high precision, high accuracy measurements of transient signals of hydrogen gas. It incorporates a retardation lens integrated into the m/z 3 Faraday cup collector. Following GC separation, the hydrogen bound in organic compounds must be quantitatively converted into H(2) gas prior to analysis in the IRMS. Quantitative conversion is achieved by high temperature conversion (TC) at temperatures >1400 degrees C. Measurements of D/H ratios of individual organic compounds in complicated natural mixtures can now be made to a precision of 2 per thousand (delta notation) or, better, with typical sample amounts of approximately 200 ng per compound. Initial applications have focused on compounds of interest to petroleum research (biomarkers and natural gas components), food and flavor control (vanillin and ethanol), and metabolic studies (fatty acids and steroids). Copyright 1999 John Wiley & Sons, Ltd.