SYNTHESIS AND CHARACTERIZATION OF PHTHALAZINONE POLY(ARYL ETHER SULFONE KETONE)WITH CARBONYL GROUP*

A kind of novel heat-resistant, high performance engineering thermoplastic phthalazinone poly(aryl ether sulfoneketone) (PPESK) containing a carboxyl group in its side chain was prepared by the nucleophilic displacement reaction of 4-(4-hydroxylphenyl)-1(2H)-phthalazinone with di(4-chlorophenyl) sulfone, 4,4'-difluoro-benzophenone and phenolphthalin insulfolane in the presence of K_2CO_3 to produce high molecular weight polymers which can be dissolved in some polarsolvents such as chloroform and nitrobenzene at room temperature and can be easily can into flexible, yellowish andtransparent films. PPESK is an amorphous polymer having a decomposition temperature above 400℃, which indicates that ithas high thermal stability. At the same time, the thermal properties of PPESKs with dicyandiamide (DICY) as curing agentindicated that the heat-resistance properties of the PPESKs are improved after curing. The apparent activation energy (ΔE) ofthe cross-linking reaction and the reaction order (n) of PPESK/DICY were found to be 52.2 kJ/mol and ca. 1.0, respectively.Therefore, the cross-linking reaction is approximately a first order reaction.     

Theoretical study on structures and stability of C4P isomers

The structures, energetics, spectroscopies, and stabilities of doublet C(4)P isomeric species are explored at the DFT/B3LYP, QCISD, and CCSD(T) (singlet-point) levels. A total of 12 minimum isomers and 27 interconversion transition states are located. At the CCSD(T)/6-311G(2df)//QCISD/6-311G(d)+ZPVE level, the lowest-lying isomer is a floppy CCCCP 1 (0.0 kcal/mol) mainly featuring a cumulenic structure |C=C=C=C=P*|, which differs much from the analogous C4N radical (|*C-C[triple bond]C-C[triple bond]N|). The quasi-linearity and the low bending mode of 1 are in contrast to the previous prediction. The second energetically followed isomer PC-cCCC 3 (14.9 kcal/mol) possesses a CCC ring-bonded to CP. The two low-lying isomers are separated by a high-energy ring-closure/open transition state (26.5 kcal/mol) and thus are very promising candidates for future laboratory and astrophysical detection. Furthermore, four high-energy isomers, that is, two bent isomers CCPCC 2 (68.4 kcal/mol) and CCPCC 2' (68.5 kcal/mol) and two cagelike species 10 (56.0 kcal/mol) and 11 (67.9 kcal/mol), are also stabilized by considerable barriers. The present work is the first detailed potential energy survey of CnP clusters and can provide useful information for the investigation of larger CnP radicals and for understanding the isomerism of P-doped C vaporization processes.     

Studies on the properties of ionic liquid EMIInCl4

This paper reports that an ionic liquid (IL) has been prepared by directly mixing InCl₃ and 1-methyl-3-ethylimidazolium chloride (EMIC) with molar ratio 1/1 under dry argon atmosphere. The densities, and surface tension of the pure IL were determined at temperature range of 293.15 to 343.15 ± 0.1 K. The volumetric properties and the properties of surface for ionic liquid based on group III were discussed by Glasser's theory and Yang's interstice model.     

Validation of the extended simultaneous kinetics and ringdown model by measurements of the reaction NH2 + NO

The determination of rate constants for fast chemical reactions from nonexponential cavity ringdown profiles requires a consideration of the interfering laser bandwidth effect that arises if the line width of the ringdown probe laser exceeds the absorption line width of the detected species. The deconvolution of the kinetics and the bandwidth effect can be accomplished with the extended simultaneous kinetics and ringdown (eSKaR) model presented by Guo et al. (Guo, et al. Phys. Chem. Chem. Phys. 2003, 5, 4622). We present a detailed validation of this eSKaR model by a corresponding investigation of the well-known rate constant for the reaction NH2 + NO. Line profiles of the pulsed ringdown probe laser and the NH2 absorption line were determined from forward modeling of experimental ringdown profiles and verified by narrow-bandwidth laser absorption measurements. In addition, the rate constant for the title reaction was evaluated using the eSKaR model and also by means of a conventional pump-probe approach with variable time delays between the photolysis (pump) and ringdown (probe) laser pulses. The resulting room temperature rate constant for the NH2 + NO reaction, k1= (8.5 +/- 1.0) x 10(12) cm(3) mol(-1) s(-1), and the room temperature pressure broadening coefficient of NH2, = 2.27 GHz/bar, measured on the A2A1<-- X2B1 transition at wavelengths around lambda = 597 nm, were found to be in excellent agreement with the available literature data.     

Fe(II) in different macrocycles: electronic structures and properties

A theoretical comparative study of complexes of porphyrin (P), porphyrazine (Pz), phthalocyanine (Pc), porphycene (Pn), dibenzoporphycene (DBPn), and hemiporphyrazine (HPz) with iron (Fe) has been carried out using a density functional theory (DFT) method. The difference in the core size and shape of the macrocycle has a substantial effect on the electronic structure and properties of the overall system. The ground states of FeP and FePc were identified to be the 3A2g [(d(xy))2(d(z)2)2(d(pi))2] state, followed by 3E(g) [(d(xy))2(d(z)2)1(d(pi))3]. For FePz, however, the 3E(g)-3A2g energy gap of 0.02 eV may be too small to distinguish between the ground and excited states. When the symmetry of the macrocycle is reduced from D4h to D2h, the degeneracy of the d(pi) (d(xz), d(yz)) orbitals is removed, and the ground state becomes 3B2g [(d(xy))2(d(z)2)1(d(yz))2(d(xz))1] or 3B3g [...(d(yz))1(d(xz))2] for FePn, FeDBPn, and FeHPz. The calculations also show how the change of the macrocycle can influence the axial ligand coordination of pyridine (Py) and CO to the Fe(II) complexes. Finally, the electronic structures of the mono- and dipositive and -negative ions for all the unligated and ligated iron macrocycles were elucidated, which is important for understanding the redox properties of these compounds. The differences in the observed electrochemical (oxidation and reduction) properties between metal porphycenes (MPn) and metal porphyrins (MP) can be accounted for by the calculated results (orbital energy level diagrams, ionization potentials, and electron affinities).     

The stability of RDDE\ddot x(t) + p_1 (t)\dot x(t) + q_1 (t)x(t) + p_2 (t)\dot x(t - r(t)) + q_2 (t)x(t - r(t)) = O

In this paper, the author considered the stability of zero solution of linear RDDE $$\begin{gathered} \ddot x(t) + p_1 (t)\dot x(t) + q_1 (t)x(t) + p_2 (t)\dot x(t - r(t)) + q_2 (t)x(t - r(t)) = O, \hfill \\ \ddot x(t) + p_1 (t)\dot x(t) + q_1 (t)x(t) + p_2 (t)\dot x(t - r(t)) = O \hfill \\ \end{gathered} $$ using Liapunov-Razumikhin functional and transformations and obtained some sufficient conditions for the stability of Eqs.(1) and (2). These results are suitable both for boundedp _i (t),q _i (t) andr(t).i=1,2.