Asymptotic approach to the truncated cosh-Gaussian beams

The propagation behavior and M ²-factor of truncated cosh-Gaussian (ChG) beams are studied by using the asymptotic approach. Detailed numerical results are given to illustrate the dependence of M ²-factor on the beam decentered parameter , truncation fraction p and power fraction f. Our results are self-consistent and reduce to those of Pare and Belanger [Opt. Commun. 123, p. 679 (1996a); Proc. SPIE 2870, p. 104 (1996b)]. The advantage of the approach is shown, and the problems introduced by the hard-aperture diffraction and the approach used are discussed.     

Characterisation of precipitate phases in magnesium alloys using electron microdiffraction

Recent results of the characterisation of the structure, morphology and orientation of fine-scale, strengthening precipitate phases in selected magnesium alloys using transmission electron microscopy and microdiffraction are reviewed. The strengthening precipitate phases in Mg–Y–Nd alloys, aged to maximum hardness at 250°C, have been found to include two metastable precipitate phases β′ and β₁, and the equilibrium precipitate β. The β′ phase has a globular form, a base-centred orthorhombic structure (potential point group of mmm), and an orientation relationship such that (100)_β′//(1 10)_α, [001]_β′//[0001]_α. The β₁ phase has an f.c.c. structure (space group and an orientation relationship that may be described by (100)_β1//[0001]_α, and forms as plates parallel to The β phase has an f.c.c. structure (space group ) and also forms as plates on with an orientation relationship with the matrix phase that is identical to that observed for β₁ phase. Precipitates in Mg–Al alloys, aged isothermally at 200°C, invariably have the b.c.c. structure of the equilibrium precipitate phase β (Mg₁₇Al₁₂). Three orientation relationships have been observed between β and the matrix phase. Most precipitates have an irrational orientation relationship that approximates to the Burger's relationship, (001)_β//(0001)_α, and a faceted lath morphology with habit plane parallel to (0001)_α. A minor fraction of precipitates posses an orientation relationship that is of the form

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and have a prismatic rod morphology. The long axes of these rods are parallel to [0001]_α, and their faceted surfaces are parallel to A few precipitates are observed to have an orientation relationship such that

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and a rod shape, with their long axes apparently inclined with respect to [0001]_α.     

Characterization of spiroiminodihydantoin as a product of one-electron oxidation of 8-Oxo-7,8-dihydroguanosine

[reaction: see text] Further oxidation of the common DNA lesion 8-oxo-7,8-dihydroguanosine by one-electron oxidants such as IrCl6(2-), Fe(CN)6(3-), or SO4-* leads to two major products, depending upon reaction conditions. In nucleosides at pH 7, 22 degrees C, the principal product is shown herein to be a spiroiminodihydantoin nucleoside, as a diastereomeric mixture, that can be characterized by NMR, ESI-MS/MS, and independent synthesis.     

Pd与CeO2(111)面的相互作用的第一性原理研究

采用基于广义梯度近似的投影缀加平面波(projector augmented wave) 赝势和具有三维周期性边界条件的超晶胞模型，用第一性原理计算方法，计算并分析了Pd在CeO₂(111)面上不同覆盖度时的吸附能，价键结构和局域电子结构. 考虑了单层Pd和1/4单层Pd两种覆盖度吸附的情况. 结果表明：1)在单层吸附时，Pd的最佳吸附位置是O的顶位偏向Ce的桥位；在1/4单层吸附时，Pd最易在O的桥位偏向次层O的顶位吸附.2) 单层覆盖度吸附时，吸附原子Pd之间的作用较强；1/4单 关键词： 三元催化剂 Pd 2')" href="#">CeO₂ 吸附 密度泛函理论     

Lagrange系统一类新型的非Noether绝热不变量——Lutzky型绝热不变量

研究了Lagrange系统的Lie对称性摄动与新型的非Noether绝热不变量. 列出了未受扰Lagrange系统的Lie对称性导致的Lutzky型精确不变量；基于力学系统的高阶绝热不变量的定义，研究在小扰动作用下Lagrange系统Lie对称性的摄动，得到了系统的一类Lutzky形式的绝热不变量.举例说明方法和结果的应用.     

电功率20 GW重复频率强流电子束二极管研究

采用静电场模拟对二极管结构及导引磁场位形分布进行了优化设计，并在20GW脉冲功率源上进行了重复频率运行实验研究，二极管输出电子束电压超过1MV，电流达20kA，脉冲宽度45ns，重复频率100Hz，达到了设计指标.     

同时实现介电常数和磁导率为负的H型结构单元左手材料

基于用一种结构同时实现材料介电常数和磁导率为负的思想，提出了H型结构单元左手材料模型.采用矩形波导法测试表明，H型结构单元在微波频率范围出现左手透射峰，并且可以由参数t对左手特性区域进行调控.同时利用相位法、棱镜折射法和散射参量法从实验和理论证明了在左手透射峰区域材料的折射率为负值，介电常数和磁导率亦同时为负.相对由金属开口谐振环与金属线两种结构组合实现的左手材料，H型结构集磁谐振与电谐振于一体，结构简单、制备方便，对微波器件左手材料表现出更多的优越性.     

高纯硅低能粒子辐照E′色心形成动力学研究

考虑固有点缺陷形成E′色心的情况，建立了E′色心形成的动力学模型，得到了高纯硅低能粒子辐照E′色心浓度与辐照剂量的关系式.结果表明，在低辐照剂量下，E′色心浓度随剂量的变化呈线性增长；随着辐照剂量的增加，E′色心浓度随剂量的变化呈饱和趋势.如果进一步考虑E′色心和其他物质反应形成新的稳定结构，E′色心浓度随剂量的变化呈双指数关系，E′色心浓度随剂量的变化不再趋于饱和状态，而是偏离饱和状态.理论结果和实验结果很好地符合，说明建立的模型是有效的.     

Al2O3Hx(x=1—3)分子团簇的结构与光谱研究

用密度泛函理论(DFT)的B3lyp方法在6-311++g(d,p)水平上对Al₂O₃H_x(x=1—3)分子的几何构型, 电子结构, 振动频率等性质进行了系统研究. 并给出了它们可能基态结构的总能量(E_T), 零点能(E_z), 摩尔热容(C_v), 标准熵(S), 原子化能(ΔE_m), 垂直电离能(IP)及垂直电子亲和能(E_A). Al₂O₃H和Al₂O₃H₂分子可能的基态的几何构型都为平面结构. Al₂O₃H₃的两个可能为基态的几何构型都是在立体Al₂O₃(D_3h)的几何结构基础上加三个氢原子构成. 这三个分子的能量最低结构为Al₂O₃H(²A′)C_s, Al₂O₃H₂(¹A′) C_s, Al₂O₃H₃ (²A) C₁.