全文获取类型
收费全文 | 11321篇 |
免费 | 1853篇 |
国内免费 | 1506篇 |
专业分类
化学 | 8515篇 |
晶体学 | 135篇 |
力学 | 660篇 |
综合类 | 105篇 |
数学 | 1147篇 |
物理学 | 4118篇 |
出版年
2024年 | 42篇 |
2023年 | 236篇 |
2022年 | 411篇 |
2021年 | 426篇 |
2020年 | 473篇 |
2019年 | 449篇 |
2018年 | 358篇 |
2017年 | 341篇 |
2016年 | 550篇 |
2015年 | 521篇 |
2014年 | 693篇 |
2013年 | 807篇 |
2012年 | 934篇 |
2011年 | 957篇 |
2010年 | 706篇 |
2009年 | 672篇 |
2008年 | 753篇 |
2007年 | 648篇 |
2006年 | 545篇 |
2005年 | 544篇 |
2004年 | 397篇 |
2003年 | 372篇 |
2002年 | 395篇 |
2001年 | 333篇 |
2000年 | 262篇 |
1999年 | 227篇 |
1998年 | 204篇 |
1997年 | 176篇 |
1996年 | 179篇 |
1995年 | 131篇 |
1994年 | 154篇 |
1993年 | 116篇 |
1992年 | 125篇 |
1991年 | 108篇 |
1990年 | 85篇 |
1989年 | 83篇 |
1988年 | 47篇 |
1987年 | 27篇 |
1986年 | 39篇 |
1985年 | 29篇 |
1984年 | 18篇 |
1983年 | 20篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1974年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
The optical-limiting property of an optically active phthalocyanine derivative with different configuration in chloroform solution was measured at 532 nm with 10 ns pulses. The excited state absorption cross-section σex of the derivative was determined with the Z-scan technique. The results showed that the phthalocyanine derivative possesses larger σex than the ground state absorption cross-section σ0, indicating that it is a material for reverse saturable absorption. And it is specially noticed that the change in the optically active configuration affects its optical-limiting property significantly. 相似文献
62.
Chunlin Li Yilu Fu Guozhu Bian Tiandou Hu Yaning Xie Jing ZhanDepartment of Chemical Physics University of Science and Technology of China Hefei China Institute of High Energy Physics Chinese Academy of Sciences Beijing China 《天然气化学杂志》2003,12(3)
The Ni/CeO2-ZrO2-Al2O3 catalyst with different Al2O3 and NiO contents were prepared by hydrothermal synthesis method. The catalytic performance for CO2 reforming of CH4 reaction, the interaction among components and the relation between Ni content and catalyst surface basicity were investigated. Results show that the interaction between NiO and Al2O3 is stronger than that between NiO and CeO2-ZrO2.The addition of Al2O3 can prevent the formation of large metallic Ni ensembles, increase the dispersion of Ni, and improve catalytic activity, but excess Al2O3 causes the catalyst to deactivate easily. The interaction between NiO and CeO2 results in more facile reduction of surface CeO2. The existence of a small amount of metallic Ni can increase the number of basic sites. As metallic Ni may preferentially reside on the strong basic sites, increasing Ni content can weaken the catalyst basicity. 相似文献
63.
64.
利用熔融KOH和Co3O4在较低温度(480℃)下反应制备出K0.36CoO2,然后用高锰酸钾溶液和饱和的过硫酸钾溶液进行氧化处理.氧化的同时伴随有水分子嵌入.K0.36CoO2用高锰酸钾和过硫酸钾溶液处理后分别得到K0.12CoO2·0.8H2O和K0.16CO2·0.6H2O.这两种化合物都属于六角晶系,表现出金属行为,脱水后主相变为正交结构并且呈现出半导体特性.K0.16CoO2·0.6H2O在56K附近可能存在自旋玻璃转变行为或其他涨落.随着钾含量的减少和水含量的增多,样品的自旋玻璃行为受到抑制或发生磁性相分离.样品K0.12CoO2·0.8H2O在零场冷却和有场冷却曲线上的分叉现象基本上消失.还讨论了产生KxCoO2与NaxCoO2体系结构和物性差别的原因. 相似文献
65.
QiaoHongYAO FuYouLI LuSHAN ChunHuiHUANG DongDongYIN 《中国化学快报》2003,14(11):1185-1188
A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%. 相似文献
66.
研究了L∞模的拟凸性质,利用极大熵方法得到极小化L∞模的Q算法.这是一种具有显式搜索方向的变尺度算法,在非线性参数估计中取得较好效果. 相似文献
67.
在HL-1托卡马克上进行了辅助加热、加料、电流驱动的物理实验研究。在改善等离子体约束方面,某些实验取得了较好的结果。在适当的稳定放电条件下,低杂波电流驱动和弹丸注入辅助加料,均能使等离子体能量约束得到一定程度的改善,与相同密度条件下的欧姆加热放电相比,能量约束时间提高了约30%。在电子回旋共振加热等离子体实验中,等离子体总能量明显增加,但与相同密度条件下的欧姆加热放电相比,能量约束时间减少了约20%。 相似文献
68.
Long-Mei Zeng Xiong Fu Jing-Yu Su Florecita De Guzman J. Francis Schmitz M. Bilayet Hossain Dick van Der Helm 《中国化学》1991,9(2):136-143
Three pyrrololactam alkaloids have been isolated from the marine sponge Phacellia fusca Schmidt collected from the South China Sea, and their structures were determined as 1–3 , on the grounds of spectral data. This is the first report of these compounds from this sponge. The structure of 1 was confirmed by X-ray analysis. 相似文献
69.
In this paper, we investigate strict stability of differential systems by variational Lyapunov function. We obtain some sufficient conditions and comparison theorems. 相似文献
70.
The wavelet and harmonic filtering method suggested by Zalevsky and Ouzieli is introduced in this paper and adopted in our volume holographic image recognition system. This composite filter combines several scaled versions of the cascaded wavelet and harmonic filter, obtaining high discrimination ability and wide dynamic range of rotation and scale deformations. Optical experiments are conducted to demonstrate the validity and practicability of the algorithm. To the best of our knowledge, this is the first report of using this algorithm in a volume holographic system. Moreover, the separate correlation approach proposed in this paper greatly simplifies the manufacturing process and reduces the cost of the system. 相似文献