Photovoltaic effect of TiO2 thick films with an ultrathin BiFeO3 as buffer layer

The photovoltaic (PV) effect of a bilayer anatase TiO₂/BiFeO₃ (BFO) film has been studied. The 20-nm ultrathin BFO layers were deposited on the fluorine-doped tin oxide (FTO) glass substrates by the chemical solution deposition method. An anatase TiO₂ layer is deposited subsequently on the BFO surface via a screen-printing technique. It is found that the FTO/TiO₂/Au cell exhibits negligible PV effect under solar exposure, while the one after introducing an ultrathin BFO film between TiO₂ and FTO leads to a considerable PV effect with an open-circuit voltage of ?0.58 V and a photocurrent density of 18.27 µA/cm². The FTO/BiVO₄ (BVO)/TiO₂/Au cell was constructed to investigate the underlying mechanism for the observed effect. A negligible PV effect of the FTO/BVO/TiO₂/Au cell indicates that the PV effect of the FTO/BFO/TiO₂/Au cell arises mainly from a built-in electric field in the BFO film induced by the self-polarization. Our work opens up a new path to utilize TiO₂ and may influence the future design of solar cells.     

Evaluation of an oral carrier system in rats: bioavailability and gastrointestinal absorption properties of curcumin encapsulated PBCA nanoparticles

A new oral delivery system, polybutylcyanoacrylate nanoparticles (PBCNs), was introduced to improve the oral bioavailability of curcumin (CUR), a poorly soluble drug. The formulation was optimized by orthogonal design and the optimal PBCNs loading CUR exhibited a spherical shape under transmission electron microscopy with a range of 40?C400?nm. Physicochemical state of CUR in PBCN was investigated by X-ray diffraction and the possible structure changes occurring in CUR after conjugating with polybutylcyanoacrylate were studied with FTIR. The results indicated that CUR in PBCN was in a non-crystalline state and CUR was encapsulated in PBCN without chemical reaction. The oral pharmacokinetic study was conducted in rats and the relative bioavailability of CUR encapsulated PBCNs to the crude CUR was more than 800%. The in situ absorption experiment in rat intestine indicated the absorption was first order with passive diffusion mechanism. The absorption results in various segments of intestine showed that the main absorption sites were ileum and colon. It can be concluded that PBCNs as an oral carrier can significantly improve the oral absorption of a poorly soluble drug.     

Local trimer orbital ordering in LiNiO2 studied by quantitative convergent beam electron diffraction technique

A local trimer orbital ordering model of LiNiO₂ was studied by means of theoretical calculation and experimental measurement of electron structure factors. Based on the trimer model, the electron structure factors were calculated by using the scattering factor of non-spherical Ni³⁺ ion. From these results, it is found that the effect of local orbital ordering on the electron structure factors of several subtle reflections, such as (202) and (107), is very large. The electron structure factors of these subtle reflections were measured by quantitative convergent beam electron diffraction method. The experimentally measured electron structure factor values of these reflections indicate that the trimer orbital ordering model is more close to the true structure of LiNiO₂.     

Metal/semiconductor hybrids consisting of self-assembled CdS nanoparticles on Cd nanowires

We report on the synthesis and the characterisation of metal/semiconductor hybrids consisting of self-assembled CdS nanoparticles on Cd nanowires, which are grown by thermal evaporation of the mixture of CdS and Cr. The growth of the hybrids is attributed to the decomposition of CdS at high temperature and the strain relieving that arises mainly from the lattice mismatch between Cd and CdS. Temperature dependence of zero-field resistance of single nanohybrid indicates that the as-produced Cd/CdS nanohybrid undergoes a metal--semiconductor transition as a natural consequence of hybrid from metallic Cd and semiconducting CdS. The metal/semiconductor hybrid property provides a promising basis for the development of novel nanoelectronic devices.     

Time evolution of information entropy for a stochastic system with double singularities driven by quasimonochromatic noise

<正>This paper deals with the time evolution of information entropy for a stochastic system with double singularities driven by quasimonochromatic noise.The dimension of the Fokker-Planck equation is reduced by the linear transformation. The exact expression of the time dependence of information entropy is obtained based on the definition of Shannon’s information entropy.The relationships between the properties of dissipative parameters,system singularity strength parameter,quasimonochromatic noise,and their effects on information entropy are discussed.     

Analysis on electrical characteristics of high-voltage GaN-based light-emitting diodes

<正>In order to investigate their electrical characteristics,high-voltage light-emitting-diodes(HV-LEDs) each containing four cells in series are fabricated.The electrical parameters including varying voltage and parasitic effect are studied. It is shown that the ideality factors(IFs) of the HV-LEDs with different numbers of cells are 1.6,3.4,4.7,and 6.4.IF increases linearly with the number of cells increasing.Moreover,the performance of the HV-LED with failure cells is examined.The analysis indicates that the failure cell has a parallel resistance which induces the leakage of the failure cell.The series resistance of the failure cell is 76.8Ω,while that of the normal cell is 21.3Ω.The scanning electron microscope(SEM) image indicates that different metal layers do not contact well.It is hard to deposit the metal layers in the deep isolation trenches.The fabrication process of HV-LEDs needs to be optimized.     

Analysis of the coupled thermoelastic vibration for axially moving beam

The coupled thermoelstic vibration characteristics of the axially moving beam are investigated. The differential equation of motion of the axially moving beam under the thermoelastic coupling is established based to the equilibrium equation and the thermal conduction equation involving deformation term. The eigenequation is deduced and the dimensionless complex frequencies of the axially moving beam with different boundary conditions under the coupled thermoelastic case are calculated by the differential quadrature method. The curves of the real parts and imaginary parts of the first three-order dimensionless complex frequencies versus the dimensionless axially moving speed are obtained. The effects of the dimensionless coupled thermoelastic factor, the ratio of length to height, the dimensionless moving speed on the stability of the beam are analyzed.     

Incoherently coupled Hermite-Gaussian breather and soliton pairs in strongly nonlocal nonlinear media

We theoretically investigate the propagation of incoherently coupled Hermite-Gaussian breather and soliton pairs in strongly nonlocal nonlinear media. It is found that multipole-mode soliton pairs with arbitrary different orders of Hermite-Gaussian shape can exist when the total power of two beams equals the critical power and the ratio of the beam widths for the Gaussian part is inversely proportional to the square root of the ratio of the wave numbers. When the total power does not equal the critical power, the Hermite-Gaussian breather pair exists and their beam widths evolve analogously. For general cases where the ratio of the beam widths is arbitrary, soliton-breather pairs or breather-breather pairs can be formed and their beam widths evolve synchronously in-phase or out-of-phase. Numerical simulations directly based on the nonlocal nonlinear Schrödinger equation are conducted for comparison with our theoretical predictions. The numerical stability analysis shows the higher-order Hermite-Gaussian solitons can not be stable for small nonlocality or for some media like liquid crystals.     

脉冲激光二极管侧面抽运Nd:YAG激光器晶体时变热效应

采用数值计算的方法,对脉冲激光二极管三向侧面抽运固体激光器中,激光晶体的温度场时变分布进行了计算. 分析了三向侧面抽运情况下晶体内光强分布,在此基础上,采用有限元法,以脉冲激光二极管侧面抽运Nd:YAG激光器为例,对单脉冲过程中晶体温度分布及其影响因素进行分析. 结果表明,晶体升温过程受到抽运条件以及散热条件的影响,但是主要受到抽运条件即抽运光强度和光束半径的影响,降温过程受到晶体热物性参数和晶体半径以及散热条件的影响. 当晶体温度达到周期性分布后,由于晶体径向温度梯度的周期性变化,引起通过晶体的平面光波的中心和边缘光线相对光程差也随时间作周期性变化.     

一种估计半导体激光器1/f噪声参数的新方法

对含白噪声的1/f分形信号小波变换系数的方差随尺度变化的关系进行适当的变换,提出了一种基于最小二乘法的估计半导体激光器1/f噪声参数的新方法.实验表明,该方法可以有效地提取出淹没在白噪声中的激光器1/f噪声,而且估计出的噪声信号的功率谱与对比仪器的测量结果有较好的一致性.