全文获取类型
收费全文 | 27261篇 |
免费 | 4428篇 |
国内免费 | 3405篇 |
专业分类
化学 | 19284篇 |
晶体学 | 353篇 |
力学 | 1874篇 |
综合类 | 282篇 |
数学 | 3042篇 |
物理学 | 10259篇 |
出版年
2024年 | 101篇 |
2023年 | 569篇 |
2022年 | 1027篇 |
2021年 | 1133篇 |
2020年 | 1202篇 |
2019年 | 1136篇 |
2018年 | 948篇 |
2017年 | 890篇 |
2016年 | 1315篇 |
2015年 | 1385篇 |
2014年 | 1621篇 |
2013年 | 2082篇 |
2012年 | 2389篇 |
2011年 | 2530篇 |
2010年 | 1669篇 |
2009年 | 1597篇 |
2008年 | 1632篇 |
2007年 | 1492篇 |
2006年 | 1452篇 |
2005年 | 1164篇 |
2004年 | 1031篇 |
2003年 | 731篇 |
2002年 | 748篇 |
2001年 | 652篇 |
2000年 | 575篇 |
1999年 | 518篇 |
1998年 | 442篇 |
1997年 | 358篇 |
1996年 | 370篇 |
1995年 | 340篇 |
1994年 | 329篇 |
1993年 | 246篇 |
1992年 | 257篇 |
1991年 | 225篇 |
1990年 | 191篇 |
1989年 | 157篇 |
1988年 | 95篇 |
1987年 | 94篇 |
1986年 | 77篇 |
1985年 | 82篇 |
1984年 | 45篇 |
1983年 | 47篇 |
1982年 | 39篇 |
1981年 | 24篇 |
1980年 | 16篇 |
1979年 | 9篇 |
1977年 | 8篇 |
1975年 | 7篇 |
1971年 | 5篇 |
1957年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 296 毫秒
901.
为了解决相干反斯托克斯喇曼散射(CARS)光谱CARSFT计算程序在温度拟合过程中,对初值依赖大、测量光谱信噪比差、不易收敛的问题,通过分析非线性迭代算法,采用了阻尼最小二乘算法对氮气CARS光谱进行温度拟合。针对CARS理论光谱计算公式较为复杂的特点,采用数值差分的方式来获得迭代计算时所需要的设计矩阵。分析了横向偏移、纵向偏移和温度三个主要参量对拟合残差的影响,发现纵向偏移的初值设置对温度拟合影响较大。拟合温度2000 K时的标准理论CARS光谱,设置偏离较大的初始值,采用阻尼最小二乘法获得了较好的结果。迭代计算167步后,温度拟合为2 005.6 K,残差为0.027 463。拟合光谱信噪比较差的CARS光谱,阻尼最小二乘法也能稳定收敛。结果验证了阻尼最小二乘法对初值的依赖不大,并且当拟合谱信噪比较差时也能收敛,可用于在恶劣环境下CARS测量光谱的拟合。 相似文献
902.
利用三维粒子模拟仿真软件,对共焦波导结构的0.4 THz回旋行波管进行了注波互作用的模拟研究。以共焦波导的冷腔色散以及衍射损耗入手,最终选定HE06模作为互作用工作模式。为了对寄生振荡进行抑制,在互作用结构中引入了截断。在模拟过程中,通过调节束压、束流、工作磁场、电子束横纵速度比,得到了最优的工作参数。最终,在束压34 kV、磁场14.25、束流2 A、横纵速度比0.75的工作参数下,当输入信号为1 W时,得到了最高2.76 kW的功率输出,增益超过34 dB,3 dB带宽为8 GHz,效率达到4%。 相似文献
903.
904.
基于天文观测的相机标定及姿态测量技术研究 总被引:1,自引:0,他引:1
为利用相机进行天文观测以实现高精度的相机姿态测量,必须先对相机参数进行精确标定。针对传统相机标定方法工作距离有限的问题,提出了以恒星为控制点的相机标定方法,根据球面天文学方法计算观测时刻控制点的世界坐标,利用摄像测量原理建立了恒星观测模型,求解相机的内外参数并分析了误差因素。实验结果表明,该标定方法在不依赖于精密、复杂的外部设备情况下可达到较高精度,并具有较强的抗噪声能力。将标定结果用于天文观测并求解相机姿态,航向角和俯仰角的解算重复性优于10″,能够满足高精度姿态测量的需求。该方法可进一步推广应用于星敏感器的标定。 相似文献
905.
Dake Hu Tianqi Zhao Xiaofan Ping Husong Zheng Lei Xing Xiaozhi Liu Jingying Zheng Lifei Sun Lin Gu Chenggang Tao Dong Wang Liying Jiao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(21):7051-7055
Two‐dimensional (2D) PtSe2 shows the most prominent layer‐dependent electrical properties among various 2D materials and high catalytic activity for hydrogen evolution reaction (HER), and therefore, it is an ideal material for exploring the structure–activity correlations in 2D systems. Here, starting with the synthesis of single‐crystalline 2D PtSe2 with a controlled number of layers and probing the HER catalytic activity of individual flakes in micro electrochemical cells, we investigated the layer‐dependent HER catalytic activity of 2D PtSe2 from both theoretical and experimental perspectives. We clearly demonstrated how the number of layers affects the number of active sites, the electronic structures, and electrical properties of 2D PtSe2 flakes and thus alters their catalytic performance for HER. Our results also highlight the importance of efficient electron transfer in achieving optimum activity for ultrathin electrocatalysts. Our studies greatly enrich our understanding of the structure–activity correlations for 2D catalysts and provide new insight for the design and synthesis of ultrathin catalysts with high activity. 相似文献
906.
Xuan Zhang Xianhe Fang Miao Xu Yibo Lei Zibo Wu Xiangdong Hu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(23):7927-7931
Enantioselective total syntheses of pseudopteroxazole ( 1 ) and ileabethoxazole ( 2 ) are presented. The two original stereocenters were constructed in excellent enantioselectivity and good diastereoselectivity through Carreira's asymmetric dual catalytic allylation, which shows potential for accessing diastereoisomers at C2 and C3 of 1 and 2 . Cationic cyclizations of 13 and 24 demonstrated an effective pathway for the construction of the opposite configurations at C1 in 1 and 2 . Additionally, an approach for the introduction of methyl at C4 is a feasible solution for structural modifications at C4 in 1 and 2 . 相似文献
907.
Hang Xu Chun‐Shuai Cao Han‐Shi Hu Shi‐Bin Wang Jin‐Cheng Liu Peng Cheng Nikolas Kaltsoyannis Jun Li Bin Zhao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(18):6083-6088
Assembled from [Th48Ni6] nanocages, the first transition‐metal (TM)‐thorium metal–organic framework (MOF, 1 ) has been synthesized and structurally characterized. 1 exhibits high solvent and acid/base stability, and resistance to 400 kGy β irradiation. Notably, 1 captures ReO4? (an analogue of radioactive 99TcO4?, a key species in nuclear wastes) with a maximum capacity of 807 mg g?1, falling among the largest values known to date. Furthermore, 1 can enrich methylene blue (MB) and can also serve as an effective and recyclable catalyst for CO2 fixation with epoxides; there is no significant loss of catalytic activity after 10 cycles. Theoretical studies with nucleus‐independent chemical shifts and natural bond orbital analysis reveal that the [Th6O8] clusters in 1 have a unique stable electronic structure with (d–p)π aromaticity, partially rationalising 1 ′s stability. 相似文献
908.
909.
Yue Hu Wei Sun Tao Zhang Nuo Xu Jianeng Xu Yu Lan Chao Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(44):15960-15965
An unprecedented stereoselective synthesis of trisubstituted vinylboronates is reported to proceed by direct borylation of lithium ketone enolates under transition‐metal‐free conditions. The stereospecific C?O borylation of lithium enolates was triggered by a carbonyl‐induced 1,3‐metalate rearrangement via a C‐bound boron enolate. DFT calculations and control experiments revealed that the stereoselectivity is controlled by sterics. A variety of stereospecific trisubstituted vinylboronates, together with several tetrasubstituted vinylboronates, were conveniently synthesized with the newly developed methodology. Based on the transformation of stereospecific vinylboronate, a single isomer of Dienestrol was efficiently obtained. 相似文献
910.
Feng Sheng Ni Ziqiu Feng Shanshan Zhang Zhihui Liu Shuguang Wang Runbai Hu Jiawei 《Journal of Radioanalytical and Nuclear Chemistry》2019,319(3):737-748
Journal of Radioanalytical and Nuclear Chemistry - In this study, the UiO-66/Fe3O4/GO composite was prepared by one step method for removal of cesium ions (Cs+) in water and exhibited excellent... 相似文献