Radiation heterogeneous processes of14C-acetic acid adsorbed in Na-Montmorillonite

This research addresses itself to the study of the mechanism of the acetic acid decarboxylation in Na-Montmorillonite exposed to ionizing radiation. The results obtained indicated that the decarboxylation reaction is enhanced several times by the irradiation. This behavior is probably due to an oxidation reaction at the edges of the clay. Also it is by energy transfer from the clay to adsorbed molecules by an interaction of non-equilibrium charge carriers with the adsorbed molecules.     

Hamiltonian circle actions on symplectic manifolds and the signature

Let M be a symplectic manifold with a Hamiltonian circle action with isolated fixed points. We prove that σ (M) = b₀(M) − b₂(M) + b₄(M) − b₆(M) + … where σ (M) is the signature of M and b_i(M) is the ith Betti number of M.     

Resonance effects in a phased antenna array constructed from rectangular waveguides

Translated from Matematicheskie Modeli i Optimizatsiya Vychislitel'nykh Algoritmov, pp. 131–143, 1993.     

Determination of tributyltin oxide in coastal marine sediments and mussels by electrothermal atomic absorption spectrometry

We have devised a new method for bis(tributyltin)oxide (TBTO) determination in marine sediments and mussels. This technique involves an n-hexane/methylene chloride mixture extraction and extract purification with a sodium hydroxide wash in order to eliminate interfering compounds. TBTO is then extracted again by nitric acid and converted into an inorganic tin species; the analysis has been effected using Zeeman graphite furnace-atomic absorption spectrophotometry. The method detection limit for the matrices examined is 0.004 μg TBTO g^?1 (wet weight) and is sufficient for the analysis in real samples. The percentage recovery of TBTO from sediments and mussels samples is higher than 85% and 95% respectively. This method has been applied to TBTO level determination in sediments and mussels (Mytilus galloprovincialis) sampled in the harbour area in Taranto, where mussel culture activities are much developed; the TBTO levels obtained in sediments and mussels were in the range 15-47 ng g^?1 (wet weight) and 11-30 ng g^?1 (wet weight) respectively. Such values are comparable with those found in other harbour areas in the Mediterranean Sea.     

Certification of the sulphur content of three rapeseed reference materials

Summary The sulphur content of three rapeseed reference materials has been certified on the basis of measurements made by inductively coupled plasma-optical emission spectroscopy, isotope-dilution mass spectrometry and ion chromatography. Their suitability for the calibration of x-ray fluorescence spectrometers used for measuring sulphur in rapeseed samples was established.     

Strings at nonzero temperature

String theory at nonzero temperature is reviewed. A bosonic string at nonzero temperature is studied and the calculation of its free energy in both the one-loop approximation and the case of arbitrary genus (multiloop analysis) is discussed. A string at nonzero temperature is compared with a string compacted on a one-dimensional torus. The properties of modular invariance and dual symmetry are discussed at both the one-loop and multiloop levels. The thermodynamics of superstrings, including also superstrings compactified on a torus, is also studied. Possible cosmological applications are briefly considered. It is shown that many features of string thermodynamics (in particular, the existence of the Hagedorn temperature and dual symmetry) also occur in the theory of noncritical strings.Translated from Izvestiya Vysshykh Uchebnykh Zavedenii, Fizika, No. 12, pp. 3–49, December, 1991.     

Estimation of the exchange constants in the Fe sublattice of the Y2Fe17 and Y2Fe17N3−δ compounds from the analysis of Mössbauer measurements

From the analysis of Mössbauer data for Y₂Fe₁₇ and Y₂Fe₁₇N_3−δ at various temperatures the hyperfine fields for 4f, 6g, 12j, 12k iron sites were estimated as a function of temperature. The reduced magnetizations calculated from the values of the hyperfine fields are fitted with a mean field model for four interacting sublattices using a computer program. The estimated exchange interaction from the fitting procedure between the 4f sites is found strongly negative (antiferromagnetic) in Y₂Fe₁₇ whereas in Y₂Fe₁₇N_3−δ it increases and becomes weak negative following a modified Slater-Néel curve. The rest of the exchange interactions are found positive or weak negative depending on the distances between the Fe atoms.