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61.
We report on the Lamb-Dicke spectroscopy of the doubly forbidden (6s(2))(1)S(0)?(6s6p)(3)P(0) transition in (199)Hg atoms confined to a vertical 1D optical lattice. With lattice trapping of ?10(3) atoms and a 265.6 nm probe laser linked to the LNE-SYRTE primary frequency reference we have determined the center frequency of the transition for a range of lattice wavelengths and at two lattice trap depths. We find the Stark-free (magic) wavelength to be 362.53(0.21) nm-essential knowledge for future use of this line in a clock with anticipated 10(-18) range accuracy. We also present evidence of the laser excitation of a Wannier-Stark ladder of states in a lattice of well depth 10E(R).  相似文献   
62.
Adaptive regularized framework using cubics has emerged as an alternative to line-search and trust-region algorithms for smooth nonconvex optimization, with an optimal complexity among second-order methods. In this paper, we propose and analyze the use of an iteration dependent scaled norm in the adaptive regularized framework using cubics. Within such a scaled norm, the obtained method behaves as a line-search algorithm along the quasi-Newton direction with a special backtracking strategy. Under appropriate assumptions, the new algorithm enjoys the same convergence and complexity properties as adaptive regularized algorithm using cubics. The complexity for finding an approximate first-order stationary point can be improved to be optimal whenever a second-order version of the proposed algorithm is regarded. In a similar way, using the same scaled norm to define the trust-region neighborhood, we show that the trust-region algorithm behaves as a line-search algorithm. The good potential of the obtained algorithms is shown on a set of large-scale optimization problems.  相似文献   
63.
A tournament T=(V,A) is a directed graph such that for every x,yV, where xy, (x,y)∈A if and only if (y,x)?A. For example, the 3-cycle is the tournament ({1,2,3}, {(1,2),(2,3),(3,1)}). Up to an isomorphism, there are two tournaments with 4 vertices and containing an unique 3-cycle which we call diamonds. We prove that for any tournament T defined on n?9 vertices, either T contains at least 2n?6 diamonds or the number of diamonds contained in T is equal to 0, n?3 or 2n?8. Following the characterization of the tournaments without diamonds due to Gnanvo and Ille (Z. Math. Logik Grundlag. Math. 38 (1992) 283–291) and to Lopez and Rauzy (Z. Math. Logik Grundlag. Math. 38 (1992) 27–37), we study the morphology of the tournaments defined on n?5 vertices and which contain exactly n?3 or 2n?8 diamonds. To cite this article: H. Bouchaala, C. R. Acad. Sci. Paris, Ser. I 338 (2004).  相似文献   
64.
We study existentially closed CSA-groups. We prove that existentially closed CSA-groups without involutions are simple and divisible, and that their maximal abelian subgroups are conjugate. We also prove that every countable CSA-group without involutions embeds into a finitely generated one having, up to conjugacy, the same maximal abelian subgroups, except maybe the infinite cyclic ones. We deduce from this that there exist 20 countable existentially closed CSA-groups without involutions and that their first-order theories have 20 types over .  相似文献   
65.
    
The fabrication of a thermolysin-based biosensor capable of detecting ochratoxin A (OTA) from food samples is described. The electrochemical deposition of calcium cross-linked cellulose film (CCLC) and gold nanoparticles (AuNPs) on graphene (GR) for modification of a glassy carbon electrode (GCE) is the first step. Then the thermolysin (TLN) enzyme in a polyvinyl alcohol (PVA)/polyethylenimine (PEI) matrix is immobilized. The impedimetric biosensor response is linear from 0.2 nM to 100 nM with a detection limit of 0.2 nM. The obtained stable and reproducible biosensor is then applied for the detection of OTA in spiked extracts from coffee beans.  相似文献   
66.
    
The present work was carried out to investigate separately the effect of Fe2+ and Fe3+ on the precipitation kinetics and the microstructure of CaCO3. For this an experimental procedure was proposed. Precipitation tests were made by using the dissolved‐CO2 degassing method. Both air and nitrogen were employed to strip the CO2 from a Ca(HCO3)2 solution initially rich in this gas. At anoxic medium, it was shown that iron (II) prolongs the nucleation step and decelerates the crystalline growth rate. X‐ray diffraction analysis shows that its presence inhibits calcite and promotes aragonite variety. By using air, the reaction medium is rich in oxygen and iron (II) is rapidly oxidized. Seeing the higher solution pH (> 6.5), iron hydroxide forms before the onset of CaCO3 precipitation and plays a role of seed permitting to initiate CaCO3 nucleation. So, contrary to the observed effect of iron (II), the presence of iron (III) accelerates the precipitation rate of CaCO3. As for iron (II), iron (III) inhibits calcite formation but favored the vaterite variety instead of the aragonite one.  相似文献   
67.
Highly crystalline ZnO–SiO2 films obtained by a sol–gel method at different ZnO contents were deposited on silicon substrate (P(100)) using spin coating process. The XRD results revealed that the strong ZnO(100) peak is grown with highly c-axis oriented film and the crystallinity is progressively improved with increasing ZnO contents. SEM micrographs of the films deposited on silicon substrate show a homogeneous and uniformity structure at different ZnO content. The prepared ZnO–SiO2 films are compared with either a film prepared from a commercial photocatalysts Hombikat UV-100 or Pilkington Glass Activ? by the determination of their photonic efficiencies for degradation of methylene blue. The photocatalytic efficiency of the 10 wt% ZnO–SiO2 film was found to be about four times higher than film prepared from UV-100 or Pilkington Glass Activ?. The photocatalytic efficiencies of ZnO–SiO2 films are increased with increasing ZnO content from 1 wt% to 10 wt% ZnO and then decreased at 15 wt% ZnO. The order of photocatalytic efficiencies of ZnO–SiO2 films at different ZnO content and commercial photocatalysts after 6 h illumination were as following: 10 wt% ZnO > 15 wt% ZnO > 1 wt% ZnO > as-prepared 10 wt% ZnO–SiO2 film > UV-100 > Pilkington Glass Activ?, which suggested that the ZnO–SiO2 films are photoactive than commercial photocatalysts. The improved efficiency and potentially the low-cost synthesis suggest that this material might be practically useful as a photocatalyst film.  相似文献   
68.
Applied Biochemistry and Biotechnology - In this study, peroxidases (PODs) from three waste by-products: broad bean pods (BBP), pea pods (PP), and artichoke stems (ARS) were purified and their...  相似文献   
69.
This paper is concerned with lineshifts of hydrogen-like ions due to electron collisions in dense and hot plasmas. These collisions are treated by including all effects due to monopole, dipole, and quadrupole interactions between radiator and electron perturbers. The latter follow exact hyperbolic trajectories with a possible penetrating part inside atomic orbits. A simple closed form for the line shift has been derived. Comparison between our semi-classical results and the quantum mechanical ones shows good agreement for a large range of high electron densities and temperatures. Received: 30 June 1997 / Revised: 28 April 1998 / Accepted: 29 April 1998  相似文献   
70.
    
This article presents the results of experimental and theoretical studies of the vO H and vO D band shapes in the polarized infrared spectra of 3‐thiophenic acid crystals measured at room temperature and at 77 K. The line shapes are studied theoretically within the framework of the anharmonic coupling theory, Davydov coupling, Fermi resonance, direct and indirect damping, as well as the selection rule breaking mechanism for forbidden transitions. The adiabatic approximation allowing to separate the high‐frequency motion from the slow one of the H‐bond bridge is performed for each separate H‐bond bridge of the dimer and a strong nonadiabatic correction is introduced via the resonant exchange between the fast‐mode excited states of the two moieties. The spectral density is obtained within the linear response theory by Fourier transform of the damped autocorrelation functions. The approach correctly fits the experimental line shape of the hydrogenated compound and predicts satisfactorily the evolution in the line shapes with temperature and the change in the line shape with isotopic substitution. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2010  相似文献   
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