Poly(methyl methacrylate‐co‐pentaerythritol tetraacrylate‐co‐butyl methacrylate)‐g‐polystyrene: Synthesis and high oil‐absorption property

Well‐defined high oil‐absorption resin was successfully prepared via living radical polymerization on surface of polystyrene resin‐supported N‐chlorosulfonamide group utilizing methyl methacrylate and butyl methacrylate as monomers, ferric trichloride/iminodiacetic acid (FeCl₃/IDA) as catalyst system, pentaerythritol tetraacrylate as crosslinker, and L ‐ascorbic acid as reducing agent. The polymerization proceeded in a “living” polymerization manner as indicated by linearity kinetic plot of the polymerization. Effects of crosslinker, catalyst, macroinitiator, reducing agent on polymerization and absorption property were discussed in detail. The chemical structure of sorbent was determined by FTIR spectrometry. The oil‐absorption resin shows a toluene absorption capacity of 21 g g^?1. The adsorption of oil behaves as pseudo‐first‐order kinetic model rather than pseudo‐second‐order kinetic model. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Synthesis of a benzoxazine with precisely two phenolic OH linkages and the properties of its high‐performance copolymers

A phenolic OH‐containing benzoxazine ( F‐ap ), which cannot be directly synthesized from the condensation of bisphenol F, aminophenol, and formaldehyde by traditional procedures, has been successfully prepared in our alternative synthetic approach. F‐ap was prepared by three steps including (a) condensation of 4‐aminophenol and 5,5'‐methylenebis(2‐hydroxybenzaldehyde) (1) , (b) reduction of the resulting imine linkage by sodium borohydride, and (c) ring closure condensation by formaldehyde. The key starting material, (1) , was prepared from 2‐hydroxybenzaldehyde and s‐trioxane in the presence of sulfuric acid. F‐ap is structurally similar to bis(3,4‐dihydro‐2H‐3‐phenyl‐1,3‐benzoxazinyl)methane ( F‐a, a commercial benzoxazine based on bisphenol F/aniline/formaldehyde) except for two phenolic OHs. The phenolic OHs can provide reaction sites with epoxy and 1,1'‐(methylenedi‐p‐phenylene)bismaleimide (BMI). The structure–property relationships between the thermosets of F‐ap /epoxy, F‐a /epoxy, F‐ap /BMI, and F‐a /BMI were discussed. Experimental data showed that thermosets based on F‐ap /epoxy and F‐ap /BMI provided much better thermal properties than those based on F‐a /epoxy and F‐a /BMI. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2686–2694     

Polymeric ytterbium(ii) complex with pyridyl amido ligands

The reaction of potassium pyridyl amido ligand {L = [N(R)(2-C5H3N-6-Me)]–, R = CH2But} with YbI2(thf)2 afforded the linear polymeric complex [K0.5(L)3YbiiK0.5]n, which was characterized by X-ray structure analysis.     

The global topological meaning of cocycles in a Gauge group

This Letter shows explicitly that the descent sequence of cocycles in a gauge group realizes the ech-de Rham double complex. Meanwhile the ech complex corresponds to finite gauge transformations. This Letter also shows how the indices of each order of cocycles characterizes the obstructions on overlapping spheres in different dimensions and how these indices are equal to a common one.     

制备XS(X=Ca,Sr)的一种优化工艺

本文利用一种新的制备工艺进行了XS(X=Ca,Sr)基质发光材料的合成;利用X-射线衍射等手段进行了反应效率、产物纯度、化学稳定性和材料的结晶学参数等研究实验结果表明,该方法比目前广泛采用的工艺具备更多优点。     

1.3μm场助TE光阴极In1-xGaxAsyP1-y/InP的能带计算及外延层的设计

本文首先简述了1.3μm场助TE光阴极InP(衬底)/In_1-xGa_xAs_yP_1-y(光吸收层)/InP(发射层)/Ag/CsO的工作原理,并对其能带结构进行了计算,得到了In_1-xGa_xAs_yP_1-y(光吸收层)/InP(发射层)的势垒高度、掺杂、InP发射层厚度、组份、渐变区宽度,偏压及耗尽层宽度间的定量关系。并由此出发,对光阴极各参数的设计进行了分析讨论。     

Photoinduced charge injection in the metal/organic interface studied by transient photovoltage measurements with bias

Transient photovoltage of ITO/organic/Al cells is studied under different bias polarities and voltages.It is found that for an ITO/NPB/Al cell,light incidence on the Al side induces more bias-dependent transient photovoltage variation when the photovoltage is positive than when it is negative.However,for an ITO/C60 /Al cell,the variation characteristics of transient photovoltage is reversed.These results support the previously proposed mechanism that Al could inject charges into the organic layer upon photon excitation,indicating that the absorption of electrode can also contribute to photovoltaic effect.     

紫外光激发下氧化锌纳米线的发光特性研究

室温条件下,用355 nm的激光激发氧化锌纳米线,测量了其发光光谱.观察到半宽度较小、峰值波长约382 nm的紫光峰和半宽度较宽、峰值波长约507 nm的绿光峰;两峰的发光强度随激发光功率密度的变化而变化,且均存在饱和效应,但各自的变化规律及饱和值的大小不同;紫光峰的中心波长随激发光功率密度的增加而发生了明显的红移.对两峰产生的机理、强度饱和值存在的原由、强度随激发光功率密度变化及紫光峰红移的起因进行了分析.