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51.
地质样品中金,银,铊等元素的连续原子吸收光谱法测定 总被引:4,自引:0,他引:4
本文提出了一个一次称样连续测定金、银、铊的简便、快速的新方法。该法是以泡塑吸附金、铊,使银等定量地保留在溶液中。泡塑上的铊用EDTA解脱后,再用硫脲溶液继续解脱金,然后,采用原子吸收光谱法连续测定金、银、铊。方法用于黄铁矿、方铅等单矿矿物及岩石、土壤样品中xng/g~xxxμg/g金、银、铊的测定,获得满意结果。 相似文献
52.
J C Zhu C H Li Y Liu Z H Zhang A X Hou S S Qu 《Journal of Thermal Analysis and Calorimetry》2006,83(1):181-186
After the occurrence of 'Minamata disease' in 1950,
mercury aroused much more attention, and lots of studies concerned have been
made. The purpose of the present paper is to study the effect of mercuric
chloride on the mitochondria suspension isolated from the liver tissue of Cyprinus carpio from the direct viewpoint of energy
by using the microcalorimetric method. The metabolic thermogenic curves of
the mitochondria suspension at 25°C were obtained, and the mitochondria
metabolic thermokinetic equations were established, from which we obtained
the thermodynamic and thermokinetic parameters: thermogenic rate constant
(k), heat output (Q),
average heat power (Pav),
etc. Experimental results indicated that low concentration of mercuric chloride
(5 nmol Hg2+/(mg protein)) stimulates the thermogenesis
of mitochondria, suggesting a strong effect of uncoupling action, while high
concentration of mercuric chloride (20 nmol Hg2+/(mg
protein)) inhibits the metabolism of mitochondria completely, suggesting a
fatal effect on the phosphorylation system. The effect of Hg2+
on mitochondria is concentration-depended, from which the probable reaction
mechanism of Hg2+ to the mitochondria was proposed.
So the microcalorimetric method can be used in the toxicology research. 相似文献
53.
Ultra-long single-crystalline trigonal selenium submicrotubes were synthesized using a facile one-step solution-phase approach with the assistance of nonionic surfactant Polyoxyethylene(20)sorbitan monolaurate (Tween-20), which turned out to be significant for the formation of ultra-long Se submicrotubes. XRD, Raman, SEM, and TEM were adopted to characterize the morphology, structure and phase composition of the as-prepared Se products. It was found that the length of the obtained Se submicrotubes was over 100 microm. By variation of the experimental parameters, the t-Se spheres, nanowires, and broken microtubes can be prepared. The possible growth mechanism of the ultra-long selenium submicrotubes was explained. In addition, we have also demonstrated that the synthesized ultra-long t-Se submicrotubes using the Tween-20-assisted approach can electrochemically charge and discharge with the high capacity of 265 mAh/g (corresponding to 0.97 wt % hydrogen in SWNTs) under normal atmosphere at room temperature. Cyclic voltammetry was adopted to investigate the adsorption-oxidation behavior of ultra-long selenium submicrotubes. It was observed that the morphology of the synthesized selenium products had a remarkable influence on their capacity of electrochemical hydrogen storage. These differences in hydrogen storage capacity are likely due to the size and density of tubes as well as the microcosmic morphology of different Se samples. The as-obtained ultra-long Se submicrotubes are expected to find wide applications in hydrogen storage, high-energy batteries, and optoelectronic, biologic, and catalytic fields as well as in the studies of structure-property relationships. This simple Tween-assisted approach might be extended to the preparations of one-dimensional nanostructures of tellurium and other anisotropic materials. 相似文献
54.
55.
Dielectric properties and frequency response of self-assembled monolayers of alkanethiols 总被引:1,自引:0,他引:1
Wang B Luo J Wang X Wang H Hou JG 《Langmuir : the ACS journal of surfaces and colloids》2004,20(12):5007-5012
This paper presents dielectric properties of alkanethiol self-assembled monolayers (SAMs) under an ac electric field. Using a Hg-SAM/SAM-Hg junction, we measured the ac impedance of alkanethiol SAMs using a sinusoidal perturbation of 30 mV (peak-to-peak) with frequency ranging from 1 Hz to 1 MHz at zero bias. Semicircles at higher frequencies and at middle frequencies along with Warburg lines at lower frequencies were observed in complex plane impedance plots, that is, Nyquist plots. The frequency response of SAMs was analyzed by modeling the junction using an equivalent circuit and fitting the Nyquist plots. The semicircles at higher frequencies are attributed to the effect of the SAM/SAM interfaces, and the ones at middle frequencies are attributed to the effect of alkanethiol SAMs. The comparison in the plots of the imaginary part of the impedance Z against frequency for the bare Hg electrodes (in pure ethanal) and the SAM-covered Hg electrodes (in alkanethiol solution) supports the analysis. The Warburg lines are attributed to a certain ionic impurity. The dielectric loss spectra are further analyzed. Chain-length-dependent peaks, which correspond to different relaxation mechanisms, at higher frequencies and middle frequencies were observed in the spectra of the dissipation factor (tan delta vs frequency). The peaks move to small frequency with the increase of chain length of alkanethiols. Using a correlation of peak position with the chain length, we then derived active energies of 39-99 meV for alkanethiol SAMs of C7-C18 under an ac electric field. 相似文献
56.
Guangyun Zheng Jiemin Jiang Yuping Wu Renxi Zhang Huiqi Hou 《Plasma Chemistry and Plasma Processing》2003,23(1):59-68
Non-equilibrium plasma, which was engendered by dielectric barrier discharge (DBD) was used to analyze the mutual conversion between CO2 and CO. The results showed that the conversion ratio of CO increased monotonously with the increasing voltage. But CO2 was not so. Its conversion ratio reached maximum when the voltage was 3600 V in Ar system. It also showed that the existence of water molecules was more advanageous for the conversion of CO to CO2 in Air system than in oxygen system, and the conversion ratio could reach 75.8% when the relative humidity was 100%. We also discussed the energy yield and energy efficiency, and the result was that high voltage and high concentration of reactant was disadvantageous for energy utilization. 相似文献
57.
The precise location of C C bonds in bioactive molecules is critical for a deep understanding of the relationship between their structures and biological roles. However, the traditional ultraviolet light-based approaches exhibited great limitations. Here, we discovered a new type of visible-light activated [2 + 2] cycloaddition of carbonyl with C C bonds. We found that carbonyl in anthraquinone showed great reactivities towards C C bonds in lipids to form oxetanes under the irradiation of visible-light. Combined with tandem mass spectrometry, this site-specific dissociation of oxetane enabled precisely locating the C C bonds in various kinds of monounsaturated and polyunsaturated lipids. The proof-of-concept applicability of this new type of [2 + 2] photocycloaddition was validated in the global identification of unsaturated lipids in a complex human serum sample. 86 monounsaturated and polyunsaturated lipids were identified with definitive positions of C C bonds, including phospholipids and fatty acids even with up to 6 C C bonds. This study provides new insights into both the photocycloaddition reactions and the structural lipidomics.A new visible-light activated [2 + 2] cycloaddition reaction was discovered and enabled pinpointing carbon–carbon double bonds in lipids. 相似文献
58.
Hui Jin Yan-bing Hou Xian-guo Meng Feng Teng 《高分子科学》2006,(6):553-558
In this paper, photoexcitation processes in the bilayer devices based on inorganic materials and poly(N-vinylcarbazole) (PVK) were investigated. In order to clarify the roles of inorganic materials in photoconductive properties of bilayer devices, TiO2 and ZnS were chosen to combine with PVK. A model for generation of photocurrent (Iph) in single layer device of PVK was obtained. It is deduced that the recombination rate constant (Pcomb) and the ionization rate constant (y) ofexcitons should be considered as the most important factors for Iph. For inorganic materials (TiO2 or ZnS)/PVK bilayer devices, in reverse bias of-4 V, the photocurrent of 115 mA/cm^2 in the TiO2/PVK device was observed, but the photocurrent in the ZnS/PVK device was only 10 mA/cma under the illumination light of 340 nm and the light intensity of 14.2 mW/cm^2. The weaker photocurrent is attributed to the absorption of ZnS within UV region and the energy offset at the interface between PVK and ZnS, which impedes the transport of charge carriers. 相似文献
59.
The Ramanujan Journal - Let $$k\ge 2$$ be an even integer, and let M be a positive integer. We prove a hybrid subconvexity bound for $$L(1/2,\text {sym}^2 f\otimes \chi )$$ with the associated... 相似文献
60.
In this paper, a tumor immune model with time delay is studied. First, the stability of nonnegative equilibria is analyzed. Then the time delay τ is selected as a bifurcation parameter and the existence of Hopf bifurcation is proved. Finally, by using the canonical method and the central manifold theory, the criteria for judging the direction and stability of Hopf bifurcation are given. 相似文献