四角晶相HfO2(001)表面原子和电子结构研究

采用基于第一性原理的密度泛函理论研究了四角晶相二氧化铪(t-HfO₂)体相及 其(001)表面的原子几何与电子结构.理论计算结果表明，t-HfO₂(001)表面不会 产生重构现象.与体相电子结构相比, t-HfO₂(001)表面态密度明显高于体相态 密度.其次，表面原子的态密度更靠近费米能级(E_F)，价带往低能量处移动，并 有表面态产生.计算结果表明了t-HfO₂表面禁带宽度明显低于体相的禁带宽度. t-HfO₂(001)的表面态产生以及表面禁带宽度减小是由于Hf原子与O原子的配位 数减少，表面原子周围的环境发生变化而引起的. 关键词： 密度泛函理论 2(001)')" href="#">t-HfO₂(001) 表面电子结构     

基于Polytec激光测振仪和第二代小波的齿轮箱故障诊断

齿轮箱是机械设备中一种必不可少的通用零部件,也是故障多发部件,而齿轮失效又是诱发其故障的重要因素。因此发展新型齿轮箱故障诊断技术具有重要意义。搭建了基于Polytec激光测振仪的光学测量系统,拾取齿轮箱振动信号,采用第二代小波提取故障特征,达到了故障诊断的目的,可用于齿轮箱故障预知和智能维修。     

Passively mode-locked Tm,Ho:YVO4 laser based on a semiconductor saturable absorber mirror

We report the demonstration of passively continuous-wave mode-locking(CWML) of diode-pumped Tm,Ho:YV04 laser using an InGaAs/GaAs multiple quantum-well(MQW) structure semiconductor as the saturable absorber.Stable mode-locking pulses at the central wavelength of 2 041 nm are obtained. The maximum output power is 151 mW.The pulse duration is 10.5 ps at the repetition rate of 64.3 MHz.     

颗粒聚集对纳米流体强化换热影响浅析

本文采用数值模拟的方法初步研究了颗粒聚集对纳米流体强化换热性能的影响。在流体中随机生成纳米颗粒团聚状态,并对其热性能进行数值模拟,结果表明,纳米颗粒的聚集将会导致流体换热性能的下降,降低程度与纳米颗粒体积分数以及聚集程度有关。     

多层绝热材料规模化干燥处理时温度场的测试与分析

对大批量处理多层绝热材料的大型专用干燥箱满负荷运行时工作区域的温度场进行测试,通过温度分布和温度场均匀性的分析,得出了最高温度发生点的位置与成因以及影响温度场均匀性的主要因素,并对温度的控制方法、多层材料的布置方案和干燥设备的改进提出了建议。     

Synthesis of starfish-like Cu2O nanocrystals through ��-irradiation and their application in lithium-ion batteries

In this study, single-crystalline starfish-like cuprous oxide (Cu₂O) nanocrystals with the backbones lengths in the range of 660 nm~16 ??m are successfully prepared through ??-irradiation, the cetyltrimethylammonium bromide (CTAB) is used as a capping material or soft colloidal templates. Without the addition of CTAB in the reaction system, irregular Cu₂O nanoclusters were obtained and their diameter is about 200 nm~1 ??m. Controlling the concentration ratio of CTAB to the copper ions, starfish-like morphology of Cu₂O can be obtained in high yield. Their structures are characterized by X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. The possible growth mechanism of the starfish structure is discussed in the text. For potential application in lithium-ion batteries, an electrode made of the starfish-like Cu₂O shows excellent electrochemical cycling performance and high-rate capability. Compared with the Cu₂O nanoclusters, the starfish-like Cu₂O exhibits an improved electrochemical cycling stability. The capacity of the starfish-like Cu₂O can maintain 340 and 215 mAh g^?1 after 50 cycles at the rate of 0.1 C and 5 C, respectively. The reversible capacity holds 60% as the discharge?Ccharge rate even increases by 50 times.     

Donor impurity states in zinc-blende GaN/AlGaN quantum well: Quantum confinement and laser-dressed effects

Within the framework of effective-mass approximation, the effects of a laser field on the ground-state donor binding energy in zinc-blende (ZB) GaN/AlGaN quantum well (QW) have been investigated variationally. Numerical results show that the donor binding energy is highly dependent on QW structure parameters and Al composition in ZB GaN/AlGaN QW. The laser field effects are more noticeable on the donor binding energy of an impurity localized inside the QW with small well width and low Al composition. However, for the impurity located in the vicinity of the well edge of the QW, the donor binding energy is insensible to the variation of Al composition, well width and laser field intensity in ZB GaN/AlGaN QW. In particular, the competition effects between laser field and quantum confinement on impurity states have also been investigated in this paper.     

Bi-large Neutrino Mixing See-Saw Mass Matrix with Texture Zeros and Leptogenesis

We study constraints on neutrino properties for a class of bi-large mixing See-Saw mass matrices with texture zeros and with the related Dirac neutrino mass matrix to be proportional to a diagonal matrix of the form diag(ε,1,1). Texture zeros may occur in the light (class a) or in the heavy (class b) neutrino mass matrices. Each of these two classes has 5 different forms which can produce non-trivial three generation mixing with at least one texture zero. We find that two types of texture zero mass matrices in both class a and class b can be consistent with present data on neutrino masses and mixing. None of the neutrinos can have zero masses and the lightest of the light neutrinos has a mass larger than about 0.046 eV for class a and 0.0027 eV for class b. In these models although the CKM CP violating phase vanishes, the non-zero Majorana phases can exist and can play an important role in producing the observed baryon asymmetry in our universe through leptogenesis mechanism. The requirement of producing the observed baryon asymmetry can further distinguish different models and also restrict the See-Saw scale to be in the range of 10¹²～10¹⁵ GeV. We also discuss RG effects on V₁₃.     

Effective-Field Theory on High Spin Systems with Biaxial Crystal Field

Based on the effective-field theory with self-spin correlations and the differential operator technique,physical properties of the spin-2 system with biaxial crystal field on the simple cubic, body-centered cubic, as well as faced-centered lattice have been studied. The influences of the external longitudinal magnetic field on the magnetization,internal energy, specific heat, and susceptibility have been discussed in detail. The phenomenon that the magnetization in the ground state shows quantum effects produced by the biaxial transverse crystal field has been found.