金纳米四面体增强有机太阳电池光吸收及光伏性能研究

为增强有机太阳能电池的光利用率,提高能量转换效率,本文合成了金四面体形状的纳米粒子,并用聚苯乙烯磺酸钠(PSS)包裹形成了核壳结构的金纳米四面体(Au@PSS tetrahedra NPs).将其掺杂到有机太阳能电池空穴提取层与活性层的界面处,利用表面等离子体共振效应来增强活性层对光的吸收,从而提高有机太阳能电池的能量转换效率.研究了掺杂浓度和PSS包裹厚度对电池性能的影响.结果表明:掺杂浓度为6%时,器件性能最佳,能量转换效率达到3.08%; PSS壳层厚度优化为2.5 nm时,转换效率达到3.65%,较标准电池提升了22.9%.电池性能的改善主要源于金四面体纳米粒子的共振吸收峰位于给体材料吸收谱范围内,纳米粒子的共振促进了给体的吸收,同时PSS壳层的引入促进了激子的解离和电荷的转移,上述因素的改善提升了电池的短路电流、填充因子和转换效率.     

Graphene: Nanostructure engineering and applications

Single-crystal erbium silicate nanowires have attracted considerable attention because of their high optical gain. In this work, we report the controlled synthesis of silicon-erbium ytterbium silicate core-shell nanowires and fine-tuning the erbium mole fraction in the shell from x = 0:3 to x = 1:0, which corresponds to changing the erbium concentration from 4:8 × 10²¹ to 1:6 × 10²² cm^-3. By controlling and properly optimizing the composition of erbium and ytterbium in the nanowires, we can effectively suppress upconversion photoluminescence while simultaneously enhancing near-infrared emission. The composition-optimized nanowires have very long photoluminescence lifetimes and large emission cross-sections, which contribute to the high optical gain that we observed. We suspended these concentration-optimized nanowires in the air to measure and analyze their propagation loss and optical gain in the near-infrared communication band. Through systematic measurements using wires with different core sizes, we obtained a maximum net gain of 20±8 dB·mm^-1, which occurs at a wavelength of 1534 nm, for a nanowire with a diameter of 600 nm and a silicon core diameter of 300 nm.

     

教师超标准绩效激励与高校发展方向、成就分析

本文以长三角及附近地区高校教师绩效收入为样本,基于高校发展方向分别从教师超标准收入三个方面分析教师超标准的薪酬激励将会对高校发展结果产生何种影响。分析结果表明高校在选择教师绩效激励模式时应尽量做到绩效激励的标准化。对于高校教师薪酬激励体系设计具有一定的现实意义。     

中国散裂中子源直线射频低电平远程控制软件研制

中国散裂中子源一期工程的直线加速器,共有8套数字化射频低电平控制单元,射频低电平的本地控制属于EPICS的异构系统,无法直接与EPICS客户端进行通信。通过在射频低电平本地控制上位机程序中嵌入一个C#类型的EPICS服务器程序,实现了使用EPICS客户端对射频低电平系统的远程控制, 从而把射频低电平控制系统接入基于EPICS框架的控制系统中。直线射频低电平远程控制投入在线运行以来,运行稳定可靠。     

Growth and properties of wide spectral white light emitting diodes

Wide spectral white light emitting diodes have been designed and grown on a sapphire substrate by using a metal-organic chemical vapor deposition system. Three quantum wells with blue-light-emitting, green-light-emitting and red-light-emitting structures were grown according to the design. The surface morphology of the film was observed by using atomic force microscopy. The films were characterized by their photoluminescence measurements. X-ray diffraction θ/2θ scan spectroscopy was carried out on the multi-quantum wells. The secondary fringes of the symmetric ω/2θ X-ray diffraction scan peaks indicate that the thicknesses and the alloy compositions of the individual quantum wells are repeatable throughout the active region. The room temperature photoluminescence spectra of the structures indicate that the white light emission of the multi-quantum wells is obtained. The light spectrum covers 400-700 nm, which is almost the whole visible light spectrum.     

利用252 Cf快裂变室测量BC501A液闪探测器的相对探测效率和响应函数

本文利用²⁵²Cf快裂变室和多参数数据采集系统,逐事例的同时记录了自发裂变中子和瞬发伽马的飞行时间(TOF),脉冲形状甄别(PSD)和反冲能量(RE,裂变中子是通过测量反冲质子;瞬发伽马是通过测量康普顿反冲电子)三维信息.详细介绍了通过离线数据分析完全扣除三维信息中的伽马事例贡献,以获得Φ50.8 mm×50.8 mm的BC501A液闪探测器的相对探测效率和响应函数的方法.在不通过探测器响应函数进行数据转换的条件下,利用中子的能量直接确定了中子的有效测量阈值.得到的中子 关键词： 252Cf快裂变室')" href="#">²⁵²Cf快裂变室 BC501A液闪探测器 相对探测效率 响应函数     

Positive ground state solutions for Schrödinger–Poisson system with critical nonlocal term in ℝ3

This paper is dedicated to studying the following Schrödinger–Poisson system $$\left\{\begin{array}{ll}-\mathrm{\Delta }u+V(x)u-K(x)\varphi |u{|}^{3}u=a(x)f(u),& x\in {ℝ}^3,\\ -\mathrm{\Delta }\varphi =K(x)|u{|}^5,& x\in {ℝ}^3.\end{array}\right.$$ Under some different assumptions on functions V(x), K(x), a(x) and f(u), by using the variational approach, we establish the existence of positive ground state solutions.     

Adaptive full state hybrid projective synchronization of chaotic systems with the same and different order

This Letter further investigates the full state hybrid projective synchronization (FSHPS) of chaotic and hyper-chaotic systems with fully unknown parameters. Based on the Lyapunov stability theory, a unified adaptive controller and parameters update law can be designed for achieving the FSHPS of chaotic and/or hyper-chaotic systems with the same and different order. Especially, for two chaotic systems with different order, reduced order MFSHPS (an acronym for modified full state hybrid projective synchronization) and increased order MFSHPS are first studied in this Letter. Five groups numerical simulations are provided to verify the effectiveness of the proposed scheme. In addition, the proposed FSHPS scheme is quite robust against the effect of noise.     

微波消解-CTAB增敏-HG-ICP-AES法测定中药黄芪中的痕量铅

采用微波消解技术处理样品,建立了CTAB增敏-氢化物发生-电感耦合等离子体发射光谱法(HG-ICP-AES)测定中药黄芪中痕量铅的分析方法。讨论了微波消解试剂、微波消解参数对消解效果的影响,系统地研究了氢化物发生的最佳条件。采用HNO₃+H₂O₂+H₂O为微波消解最佳试剂,在选定的最佳氢化物发生条件下,铅的线性范围为0.23～800 μg·L-1, 相关系数为0.999 9,检出限为0.23 μg·L-1,相对标准偏差为1.02%, 样品加标回收率为98.8%～100.1%。结果表明,微波消解法处理中草药,具有快速、简便、节省试剂、消解完全等特点,测定结果的精密度和准确度令人满意。