基于光导开关的Blumlein型PFN能量转换效率

为了驱动低能重复频率高阻抗X光管,采用低感陶瓷电容构建了一套电长度约33.5 ns、阻抗约8 的Blumlein型脉冲形成网络（BPFN）,在匹配负载条件下研究了采用GaAs光导开关（PCSS）作为脉冲输出开关时PCSS工作场强、激光触发能量与能量转换效率的关系。实验表明:PCSS截止场强为3.21～4.94 kV/cm,在工作场强高于20 kV/cm时,截止场强引起的能量损失对能量转换效率的影响不大;PCSS较高的导通电阻是影响PFN能量转换效率的主要因素,随着工作场强、激光触发能量的上升,能量转换效率呈指数上升趋势。     

In situ template synthesis of SnO nanoparticles on nickel foam with high electrochemical performance

A solution strategy performed at room temperature was presented for the in situ synthesis of SnO nanoparticles. SnO nanoparticles were prepared through the following sequent procedure: (1) preparation of rod-like Cd(OH)Cl utilizing the reaction between Cd²⁺ ions and epoxide; (2) production of Sn₂₁Cl₁₆(OH)₁₄O₆ template through the cation exchange reaction between Cd(OH)Cl and Sn²⁺ ions; (3) formation of SnO nanoparticles on nickel foam by the in situ reaction in strong alkaline electrolyte solution before electrochemical measurement. The as-prepared SnO had very small particle size and ordered nanostructure of particulate sheet, therefore resulting in its excellent electrochemical performance including high specific capacitance and high electrochemical stability for the charge-discharge cycle. Hence, the SnO nanoparticles synthesized in this work could be considered as one promising metal oxide for the utilization as electrode material in supercapacitor.

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SnO nanoparticles were prepared by an in situ template strategy. The synthetic procedure included the production of rod-like Cd(OH)Cl precursor at room temperature, preparation of platelet-like Sn₂₁Cl₁₆(OH)₁₄O₆ template through a cation exchange reaction, and the in situ synthesis of SnO nanoparticles from the template on nickel foam. Due to the small particle size, SnO presented high electrochemical performance as electrode material for application in supercapacitor.

     

限域单分子层冰-水两相平衡体系的分子动力学模拟

限域水因有极其丰富的结构物相变化而成为近年来水科学研究的一个热点.然而,不同相限域水之间的相平衡结构与性质却鲜有报道.论文提出一套分子动力学模拟技术,可实现纳米尺度限域条件下冰和水的不同结构相间形成的低维固-液界面（线）的平衡态模拟.应用此模拟技术,我们探索了0.65 nm限域尺寸、5000 bar限域压强条件下,单分子层厚度的冰-水（固-液）两相平衡,计算了该平衡体系一系列热力学量在界线附近的分布.平衡态的分子模拟结果直观地展示了粗糙型固-液界线的热毛细涨落、界线固-液结构转变的微观机制、以及缺陷在固-液相变区附近的形成与输运.各种热力学量分布函数呈现了二维限域冰-水共存界面（线）的特殊性质,如：相平衡区域的尺寸异于块体材料固-液界面,固-液界线处于切向压缩状态等.     

Fast release of lipophilic agents from circulating PEG-PDLLA micelles revealed by in vivo forster resonance energy transfer imaging

Understanding the in vivo behavior of nanoparticles is critical for the translation of nanomedicine from laboratory research to clinical trials. In this work, in vivo Forster resonance energy transfer (FRET) imaging was employed to monitor the release of hydrophobic molecules from circulating poly(ethylene glycol)-poly( D, L-lactic acid) (PEG-PDLLA) micelles. A lipophilic FRET pair (DiIC(18) and DiOC(18)) was physically entrapped into micelle cores by mimicking the loading of hydrophobic drugs. The FRET efficiency was found significantly reduced within 15 min after intravenous injection, implying that DiIC(18) and DiOC(18) quickly escaped from the circulating micelles. FRET spectroscopy studies further demonstrated that alpha- and beta-globulins were major factors for the observed fast release, while gamma-globulins, albumin, and red blood cells played minor roles. These results provide useful information for developing blood-stable micelles to deliver hydrophobic drugs to the target site via prolonged circulation and extravasation from the vascular system.     

Dynamic Self‐Assembly Adhesion of a Paraquat Droplet on a Pillar[5]arene Surface

The adhesion of herbicide droplets on leaf surfaces plays an important role in the herbicide's adsorption by crops. How to control the adhesive binding which occurs through dynamic self‐assembly between the macroscopic droplet and the surface is a challenging task. We introduce a host onto surfaces that controls the binding of guests in the paraquat droplets. The pillar[5]arene‐functional surface showed the selective binding of paraquat droplets via the host–guest interaction. The work is promising for improving the efficiency of herbicides.     

铋(Ⅲ)-卤素络阴离子选择电极的研究

我们曾报导了PVC膜四碘络铋离子选择电极的研制。现又研制了铋(Ⅲ)-溴,铋(Ⅲ)-氯的络阴离子PVC膜选择电极。本文比较了三种铋(Ⅲ)-卤素络阴离子选择电极的主要性能,并对络阴离子电极配位体的选择条件及阳离子的干扰规律进行了讨论。     

Design and dynamic performance research of MR hydro-pneumatic spring based on multi-physics coupling model

Aiming at the problem that the damping coefficient of the traditional hydro-pneumatic spring cannot be adjusted in real-time, the magnetorheological (MR) damping technology was introduced into the traditional hydro-pneumatic spring with single gas chamber. A new shear-valve mode MR hydro-pneumatic spring was proposed. And its dynamic performance was analyzed based on multi-physical coupling simulation and mechanical property test. Firstly, a structural scheme of MR hydro-pneumatic suspension was proposed to ensure the original height adjustment function based on the working principle of traditional hydro-pneumatic suspension with single gas chamber. Secondly, based on the design requirements, the parameter of MR hydro-pneumatic spring damping structure was designed by using MR damper design method. Thirdly, the multi-physical coupling dynamic performance of the MR hydro-pneumatic spring damping structure was analyzed based on the electromagnetic field analysis theory, flow field analysis theory and thermal field analysis theory. The analysis results showed that the designed MR hydro-pneumatic spring has reasonable magnetic circuit structure and excellent working performance. Then, the mechanical properties of MR hydro-pneumatic spring were tested. The results showed that the maximum damping force can reach 20 kN, and the dynamic adjustable multiple can reach 6.4 times. It has good controllability and meets the design requirements. Finally, a nonlinear model of MR hydro-pneumatic spring was established based on the elastic force calculation model of the gas and the Bouc–Wen model. The simulation results of the established model agree well with the experimental results, which can accurately describe the dynamic properties of the hydro-pneumatic spring. The proposed design and modeling method of the MR hydro-pneumatic spring can provide a theoretical basis for the related vibration damping devices.

     

磁耦合谐振式超导无线电能传输线圈错动对传输效率的影响仿真

超导以其低阻抗的特性,受到了广泛关注和应用.将超导线圈引入无线电能传输系统中,能够提升其传输性能.本文通过有限元仿真软件COMSOL Multiphysics对超导线圈错动对无线电能传输系统传输性能的影响进行了仿真,得出超导无线电能传输性能较之传统的在线圈错动时性能更好,在大功率的使用场合中能更好的适应实际情况,减少损耗,提升传输质量,为超导无线电能传输技术的应用提供了一定的参考依据.     

Optimization of Diode-Pumped Continuous-Wave Tape-Casting YAG/Nd:YAG/YAG-Ceramic Lasers

We demonstrate a diode-laser-pumped solid-state 1.06 μm laser using a novel YAG/Nd:YAG/YAG composite ceramics with a sandwich structure. We optimize the laser performance using different output couplers, pumping beam waists, and cavity lengths. A maximum CW output power of 11 W for the YAG/Nd:YAG/YAG-ceramic laser is obtained at an absorbed pump power of 25 W resulting in a slope efficiency of 49.4%. The excellent output performance shows that the novel YAG/Nd:YAG/YAGceramic material has a great potential in applications with diode-laser pumping.