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921.
Soy protein isolate (SPI) and glycerol were mixed under mild (L series) and severe (H series) mixing conditions, respectively, and then were compression-molded at 140 degrees C and 20 MPa to prepare the sheets (SL and SH series). The glass transition behaviors and microstructures of the soy protein plasticized with glycerol were investigated carefully by using differential scanning calorimetry and small-angle X-ray scattering. The results revealed that there were two glass transitions in the SPI/glycerol systems. When the glycerol contents ranged from 25 to 40 wt.-%, all of the SL- and SH-series sheets showed two glass transition temperatures (T(g1) and T(g2)) corresponding to glycerol-rich and protein-rich domains, respectively. The T(g1) values of the sheets decreased from -28.5 to -65.2 degrees C with an increase of glycerol content from 25 to 50 wt.-%, whereas the T(g2) values were almost invariable at about 44 degrees C. The results from wide-angle X-ray diffraction and small-angle X-ray scattering indicated that both protein-rich and glycerol-rich domains existed as amorphous morphologies, and the radii of gyration (R(g)) of the protein-rich domains were around 60 nm, a result suggesting the existence of stable protein domains. The results above suggest that protein-rich domains were composed of the compact chains of protein with relatively low compatibility to glycerol and glycerol-rich domains consisted of relative loose chains that possessed good compatibility with glycerol. The significant microphase separation occurred in the SPI sheets containing more than 25 wt.-% glycerol, with a rapid decrease of the tensile strength and Young's modulus. [illustration in text]. 相似文献
922.
An apparatus for heavy-current and high-tension electrophoresis on filter paper is described This apparatus enables one to avoid the difficulties that occur in electrophoresis in base electrolytes that are highly concentrated or show greater electric conductivity The zones migrate along the paper strips with constant speed and, consequently, it is possible to measure the mobility The effective length of the filter paper strips is 660 mm Correction of the apparent mobility in the porous adsorbent is treated thoroughly.Diagrams of the electrophoretic mobility of the chloro-complexes of Hg(II), Bi(III), Cd(II), Pb(II), and Cu(II) in hydrochloric acid, are given in the experimental part The concentration of the hydrochloric acid varied between 0.1N and 6N In 6N HCl all the metals investigated are present asani onic complexes. Hg, Bi.Cd, and Pb chloro-complexes show a pronounced maximum of mobility in the anionic range. The sequence of the zones in the direction anode to cathode is Hg, B1, Cd, Pb, Lu al 0.1–2.3N HCl and B1, Hg, Cd, Pb.Cu at2.3–6N HCl.Finally, the electrophoretic separation of a mixture of Hg, Bi, Cd, Pb, Cu in 1N, 2N and 4N HCl is illustrated Complete separation of the zones was achieved in each experiment 相似文献
923.
利用四极铁调制的方法可以改变工作点,测量工作点的改变,可以计算出四极铁位置的Beta函数值,这样测量得到的值是四极铁位置的平均Beta函数值。采用该方法在合肥光源(HLS)储存环进行了实验,四极铁电源电阻并联后,分流调制四极铁的电流,从而改变四极铁强度,对环上的30块四极铁进行Beta函数测量。以理论值为参考,对采用计算公式得到的结果进行了比较和分析,利用四极铁中心位置的理想Beta函数计算值和测量值作比较,结果表明:测量最大绝对差为2.741,平均绝对差为0.521;垂直方向的测量最大绝对差为1.711,平均绝对差为0.009,四极铁自身电流和分流电流的测量对Beta函数测量值误差的影响非常小。通过改进工作点测量系统,适当加大分流电流可以减小Beta函数测量误差。 相似文献
924.
925.
开发了一种由顺酐直接加氢高选择性及高转化率制备琥珀酸酐的新方法,研究结果表明:钯三苯基膦催化体系对顺酐加氢具有较高的反应活性.在所考察的反应条件下,此催化剂体系对琥珀酸酐的选择性为100%,无其他副产物生成.并考察了三苯基膦/钯摩尔比,反应温度,氢气压力,催化剂和顺酐浓度对顺酐催化加氢生成琥珀酸酐的影响.在反应条件为PdCl2=125×10-3mol/L,n(顺酐)/n(Pd)≤2000,n(三苯基膦)/n(Pd)=4,T=373~393K,25MPa的氢压下于乙二醇二甲醚溶剂中反应1h以上,可使顺酐的转化率大于90%. 相似文献
926.
We discuss the energy eigenstates, ground and spin mixing dynamics of a spin-1 spinor Bose–Einstein condensate for a dilute atomic vapor confined in an optical trap. Our results go beyond the mean field picture and are developed within a fully quantized framework. 相似文献
927.
928.
1‐Dodecene Hydroformylation Catalyzed by Water Soluble Rhodium Phosphine Complex in Two‐Phase System
1‐Dodecene hydroformylation catalyzed by water soluble rhodium complex [RhCl(CO) (TPPTS)2] was studied in the presence of TTPTS [P(m‐C2H4SO3Na)3] and CTAB (cetyltrimethyl ammonium). The influence of reaction parameters was discussed in detail based on micelle effect in biphasic system. The modification for the microcircumstance of micelle interface was conducted by the introduction of a catalyst promoter TPPDS [PhP(m‐C2H4SO3Na)2] into the reaction solution. A synergistic effect between TPPDS and TPPTS on the regioselectivity of 1‐dodecene hydroformylation was observed. The selectivity of linear aldehyde in the products was so high as 95.7% at the molar ratio of [TPPDS]/[TPPTS] = 0.5. 相似文献
929.
The crystal and molecular structure of [Pd(iPr2dtc)2] (dtc = dithiocarbamate) have been determined by X‐ray crystallography. The unit cell of the crystal structure consists of two discrete monomelic molecules of [Pd(iPr2dtc)2]. The Pd(II) ion has an square‐planar geometry. The electronic and IR spectral data are in agreement with the X‐ray structure. The TG data indicate slight degradation of a few percent. 相似文献
930.
Y. Tagaya S. Hashimoto K. Morita Y.H. Pu T. Ariga K. Ohta T. Minemura I. Hisanaga T. Motobayashi T. Nomura 《The European Physical Journal A - Hadrons and Nuclei》1999,5(2):123-125
The α-decay energy and halflife of 195mAt were determined to be 6960±20 keV and 385+69
−51 ms respectively, on the basis of genetic correlations in the 169Tm(36Ar, α6n)195At reaction, while those of 195gAt measured simultaneously were 7105±30 keV and 146+21
−17 ms respectively, reconfirming the previously reported values. A new isotope 199Fr was also produced and identified in the same way in the 169Tm(36Ar, 6n)199Fr reaction, yielding Eα= 7655±40 keV and T1/2= 12+10
−4 ms.
Received: 26 March 1999 相似文献