基于远场时间反演的亚波长天线阵列研究

基于远场时间反演, 从信号处理角度对亚波长阵列的超分辨率聚焦特性进行了理论分析. 提出了一种新型的微结构刻蚀亚波长阵列, 通过时间反演聚焦实验表明, 该阵列具有远场超分辨聚焦特性, 各单元间信道相互独立. 将这种亚波长阵列应用在时间反演镜天线上, 通过实验验证了可以获得更好的超分辨率聚焦效果. 所提出的亚波长天线阵列对多天线超宽带无线通信具有潜在的应用价值. 关键词： 时间反演 亚波长 天线阵列 超分辨率     

一维周期与准周期排列沟槽结构的流体减阻特性研究

本文设计了具有相同平均沟槽密度的三种排列类型的一维沟槽结构: 密排列、周期间隔排列和两种准周期间隔排列, 并采用数值模拟和实验验证相结合的方法研究了一维沟槽结构在不同排列下的流体减阻特性. 模拟计算分析流场特征和总阻力, 发现相对于密排列和周期间隔排列的沟槽结构, 准周期间隔排列具有更好的减阻特性, 并且这一结果得到减阻实验的验证. 通过流场分布特性进一步分析沟槽结构的减阻机理. 机理分析发现高速流在经一维准周期结构的扰动波调制后形成了准周期间隔排列的速度条纹相, 这有效地抑制了大涡在流向和展向上的形成, 从而实现较大幅度的减阻. 同时对比分析沟槽排列结构调制展向涡和流向涡各自对流动减阻的贡献, 结果表明, 调制流向涡对减阻的作用更大. 关键词： 流体减阻 沟槽结构 准周期     

气质联用法测定复合食品包装袋中的二氨基甲苯

建立复合食品包装袋中二氨基甲苯气相色谱一质谱测定方法.样品用4%乙酸提取,加三氟乙酸酐进行衍生化,用气相色谱-质谱联用仪测定.二氨基甲苯含量在0. 002～0. 05μg/mL范围内与离子蜂面积呈良好的线性关系,相关系数r=0. 9998,检出限低于0. 0004 mg/L.测定结果的相对标准偏差为2. 98%～5. 50%(n=6),加标回收率为82%～92%.该方法快速、灵敏、测定结果准确.     

Simultaneous determination of 103 pesticide residues in tea samples by LC‐MS/MS

A simple and sensitive method was developed and validated for the simultaneous determination of 103 pesticide residues in tea by LC‐MS/MS. For the analysis of the pesticide with polarity, thermal lability or low volatility, this LC‐MS/MS method has an advantage over GC. In this work, residual pesticides were extracted from the tea sample with ACN and then purified using Carb‐NH₂ SPE cartridges. Using the multiple reaction monitoring mode, the pesticides were quantified and identified by the most abundant and characteristic fragment ions. The recoveries obtained for each pesticide ranged between 65 and 114% at three spiked concentration levels. The intra‐day precisions were lower than 19.6%. Good linear relationships were observed with the correlation coefficients r² >0.996 for all analytes. The established method was successfully applied to the determination of pesticide residues in real tea samples.     

Excess of a class of g-frames

In this paper, we study the relationship between frames for the super Hilbert space H⊕H and g-frames for H with respect to C². We show that a g-frame associated with a frame for H⊕H remains a g-frame whenever any one of its elements is removed. Furthermore, we show that the excess of such a g-frame is at least dimH.     

Packing circuits in matroids

The purpose of this paper is to characterize all matroids M that satisfy the following minimax relation: for any nonnegative integral weight function w defined on E(M),

Syntheses and characterization of two oxoborates, (Pb3O)2(BO3)2MO4 (M=Cr, Mo)

Two oxoborates, (Pb₃O)₂(BO₃)₂MO₄ (M=Cr, Mo), have been prepared by solid-state reactions below 700 °C. Single-crystal XRD analyses showed that the Cr compound crystallizes in the orthorhombic group Pnma with a=6.4160(13) Å, b=11.635(2) Å, c=18.164(4) Å, Z=4 and the Mo analog in the group Cmcm with a=18.446(4) Å, b=6.3557(13) Å, c=11.657(2) Å, Z=4. Both compounds are characterized by one-dimensional chains formed by corner-sharing OPb₄ tetrahedra. BO₃ and CrO₄ (MoO₄) groups are located around the chains to hold them together via Pb–O bonds. The IR spectra further confirmed the presence of BO₃ groups in both structures and UV–vis diffuse reflectance spectra showed band gaps of about 1.8 and 2.9 eV for the Cr and Mo compounds, respectively. Band structure calculations indicated that (Pb₃O)₂(BO₃)₂MoO₄ is a direct semiconductor with the calculated energy gap of about 2.4 eV.     

A new phenylethanoid glycoside from Rabdosia lophanthoides （Buch.-Ham.ex D.Don） Hara.

A new phenylethanoid glycoside,3-hydroxy-4-methoxy-β-phenylethoxy-O-α-L-rhamnopyranosyl-(1→3)-2-O-acetyl-O-β-D-glucopyranoside, named lophanthoside A,was isolated from Rabdosia lophanthoides(Buch.-Ham.ex D.Don) Hara.Its structure was determined by spectroscopic evidences.     

Synthesis,crystal structure,and magnetic properties of ([Cu(oxbe)]Mn(H(2)O)[Cu(oxbe)(DMF)])(n).nDMF.nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer

Self-assembly of the building block [Cu(oxbe)](-) with Mn(II) led to a novel coordination polymer ([Cu(oxbe)]Mn(H(2)O)[Cu(oxbe)(DMF)])n).nDMF.nH(2)O, where H(3)oxbe is a new dissymmetrical ligand N-benzoato-N'-(2-aminoethyl)oxamido and DMF = dimethylformamide. The crystal forms in the triclinic system, space group Ponemacr;, with a = 9.260(4) A, b = 12.833(5) A, c = 15.274(6) A, alpha = 76.18(3) degrees, beta = 82.7(3) degrees, gamma = 82.31(3) degrees, and Z = 2. The crystal structure of the title complex reveals that the two-dimensional bimetallic layers are constructed of Cu(II)Mn(II)Cu(II) chains linked together by carboxylate bridge and hydrogen bonds help to produce a novel three-dimensional channel-like structure. The magnetic susceptibility measurements (5-300 K) were analyzed by means of the Hamiltonian H = -2JS(Mn)(S(Cu1) + S(Cu2)), leading to J = -17.4 cm(-1).     

果蔬中L—抗坏血酸的示波计时电位滴定

果蔬中的L—抗坏血酸(以下简称V_c)的直接测定方法较多,目前常见的有2,6—二氯酚靛酚滴定法、二甲苯提取后的2,6—二氯酚靛酚分光光度法、乙醚提取法、高压液相色谱法及电位滴定法等。本文提出的示波计时电位滴定法简便、快速、终点直观,不受食品颜色、浑浊的干扰,不污染空气。具有一定实用价值。实验部分一、主要仪器与试剂 1.仪器 LS—lA型示波极谱滴定仪(山东电讯七厂),SD50—Z型双位滴定仪,213型铂片电极,铂丝电极,pH522型数字式pH计(西德WTW),10ml微量滴定管。 2.试剂(所有试剂为分析纯)