The Simulation and Experiment of In 718 in Warm Laser Shock Processing Without Coating

Journal of Russian Laser Research - A modified constitutive model, combining laser shock processing and dynamic strain aging (DSA), is used to obtain the compressive residual stress field of In 718...     

以函数为参量的间歇发酵非线性动力系统及其辨识

建立以连续分段线性函数为参量的间歇发酵非线性动力系统,证明该动力系统的主要性质及解的存在性.以实验数据拟合得到的光滑曲线为依据,提出了连续分段线性函数为优化变量的辨识模型,论述可辨识性.依状态变量与辨识函数的相关性,构造求解辨识模型的优化算法,并给出优化算法的收敛性分析及数值结果.     

蒙特卡洛法评定橡胶门尼黏度测量的不确定度

根据高聚物流变学原理,建立了门尼黏度测量模型,分析了模型中各个变量的概率分布,利用Mathcad软件进行了测量模型的门尼黏度模拟,给出了模拟最佳值、不确定度及其包含区间,实现了门尼黏度测量不确定度的蒙特卡洛法评定。与GUM法相比,蒙特卡洛法评定门尼黏度测量不确定度具有编程模式化,过程简单等优点,适合多变量测量模型的不确定度评价。     

Synthesis,characterization, and functionalization of zirconium tungstate (ZrW2O8) nano‐rods for advanced polymer nanocomposites

Nanomaterials based on zirconium tungstate (ZrW₂O₈) exhibit numerous outstanding properties that make them ideal candidates for the development of high‐performance composites. Low coefficient of thermal expansion for advanced materials is a promising direction in the field of insulating nanocomposites. However, the agglomeration of zirconium tungstate (ZrW₂O₈)‐based nanomaterials in the polymer matrix is a limiting factor in their successful applications, and studies on surface functionalization ZrW₂O₈ for advanced nanocomposites are very limited. In this work, ZrW₂O₈ nano‐rods were synthesized using a hydrothermal method and subsequently functionalized in a solvent‐free aqueous medium using dopamine. Both pristine and functionalized nano‐rods were thoroughly characterized using Fourier transform infrared spectroscopy, Raman spectroscopy, thermogravimetric analysis, X‐ray diffraction, Scanning Electron Microscopy (SEM), and transmission electron microscopy techniques, which confirmed the successful functionalization of the nanomaterials. Polymer nanocomposites were also prepared using epoxy resin as a model matrix. Polymer nanocomposites with functionalized ZrW₂O₈ nano‐rods exhibited low coefficient of thermal expansion and enhanced tensile properties. The improved properties of the nanocomposites render them suitable for electronic applications. Copyright © 2017 John Wiley & Sons, Ltd.     

Palladium-Catalyzed Asymmetric [4+2] Cycloaddition of 2-Methylidenetrimethylene Carbonate with Alkenes: Access to Chiral Tetrahydropyran-Fused Spirocyclic Scaffolds

A palladium-catalyzed asymmetric [4+2] cycloaddition of 2-methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or barbiturate has been successfully developed, affording pharmacologically interesting chiral tetrahydropyran-fused spirocyclic scaffolds. The target compounds were generated in good to excellent yields and with high enantioselectivity (up to 99 % ee). Furthermore, this cycloaddition reaction could be efficiently scaled up, and several synthetic transformations were accomplished for the construction of other useful chiral spiropyrazolone and spiroindandione derivatives.     

Synthesis, rapid responsive thickening, and self-assembly of brush copolymer poly(ethylene oxide)-graft-poly(N,N-dimethylaminoethyl methacrylate) in aqueous solutions

Double hydrophilic brush copolymer poly(ethylene oxide)-graft-poly(N,N-dimethylaminoethyl methacrylate) (PEO-g-PDMAEMA) was successfully prepared via atom transfer radical polymerization (ATRP). We investigated the pH/thermoresponsive behaviors of PEO-g-PDMAEMA brush-shaped copolymer concentrated aqueous solutions by rheology. The observed LCST strongly decreased with increasing pH of the solutions, which was lower than that of linear block copolymer for different pH, indicating rapid thermoresponsiveness of the brush PDMAEMA chains. An unexpected shear thickening behavior was observed and could be tuned by the pH, resulting from the mobile nature and tractive force of the densely grafted hydrophobic chains of PDMAEMA at high pH. Self-assembly of the brush copolymer in a different pH and ionic strength environment was studied by transmission electron microscopy. A wormlike cylinder structure was formed at low pH. Fractals were observed for the brush copolymer aqueous solution in the presence of NaCl. The results showed that by adjusting the pH and NaCl concentration of the dispersions fractal aggregates with different topology were obtained. The observations reported here can supply a better understanding of the molecular self-assembling nature and be used to develop responsive materials with better performance.     

高功率激光器自动准直系统图像处理的可信度评估

自动准直系统是将采集的图像进行特定算法处理获取光束的位置信息,驱动电机调整光斑到指定的位置,其中图像质量对光束定位的精确性影响很大,为尽量避免受严重噪音和光束畸变影响的图像进入图像处理流程而产生准直结果的错误判断,保证自动准直系统图像处理结果的精确性,试图提供一种较为简单的判断依据,采用基于Monte-Carlo模拟方法,建立了远场准直过程中三种主要噪音的干扰评估模型,以测量不确定度作为定量判断处理图像与否的特征参数,将该结果做成统计图表作为判断依据。结果表明,在设定合理测量不确定度阈值的情况下,该特征参数能够较好地排除不良图像,从而提高准直结果的可信度。     

Investigation of 1.06 μm laser induced plasma in air using optical interferometry

The laser produced plasma in air by Q-switch Nd:YAG pulses with 50 mJ and 7 ns was analyzed using Mach-Zehnder interferometer. The interferograms were taken at various delay times after single pulses induced gas breakdown. The 3D electron density distribution at early times of the plasma is investigated. To determine the 3D electron density distribution of the plasma, the FFT analysis is applied to extract the phase of the reconstructed interferograms and the numerical inverse Abel transformation is used to calculate the refractive index. The results provide an understanding of the electron density temporal and spatial evolution of laser induced plasma in air from 18 ns and up to 100 ns of plasma lifetime.     

半线性热方程的反馈零能控性

考虑具有Lipschitz非线性项,半线性热方程的最优控制问题.我们将运用观测不等式,证明值函数ψ作为相应Hamilton-Jacobi方程的唯一粘性正解是局部Lipschitz连续的.最后,运用动态规划方法,得到系统最优的反馈控制.     

国际原油价格预测的双层随机整数规划模型、算法及应用

根据国际原油价格近期数据及原油价格变化量,给出了国际原油价格改变量的状态转移概率(或频率)矩阵.依此提出以国际原油价格预测误差的期望与方差最小为最优目标,建立国际原油价格预测的双层随机整数规划,并论述该优化问题最优解的存在性, 根据约束特性构造了优化算法.同时按照国内现行成品油定价机制, 提出的优化算法,对国内成品油调价进行了预测,实证分析表明提出的模型与优化算法具有一定的预测精度和较好的实用性.