固相萃取-高效液相法测定炒货食品及坚果制品中的多种抗氧化剂

运用固相萃取和高效液相色谱技术,建立炒货食品及坚果制品中丁基羟基茴香醚(BHA)、二丁基羟基甲苯(BHT)、叔丁基对苯二酚(TBHQ)、没食子酸丙酯(PG)等人工合成的抗氧化剂和茶多酚、甘草抗氧化物、迷迭香提取物等天然抗氧化剂的测定方法。样品经甲醇、异丙醇、乙腈等混合溶剂提取,冷冻离心后经C18柱固相萃取净化,用高效液相色谱检测。各抗氧化剂残留量在6~100 mg/L范围内呈良好线性关系,加标回收率为80%~106%。     

Efficient Z-scheme g-C3N4/MoO3 heterojunction photocatalysts decorated with carbon quantum dots: improved visible-light absorption and charge separation

Z-scheme heterojunction photocatalysts based on g-C₃N₄ generally need to recombine g-C₃N₄ and a wide bandgap semiconductor. This structure is limited by the large bandgap of the constituent material, which can effectively suppress carrier recombination while limiting the absorption of visible light. Due to the superior up-conversion photoluminescence properties of the carbon quantum dots (CQDs), this dilemma can be solved ingeniously by adding CQDs to the composite. Moreover, the charge reservoirs of CQDs are conducive to the charge carrier separation effect. In this work, a novel CQDs-modified Z-type photocatalyst is constructed and the successful implantation of CQDs is demonstrated. The composite catalyst exhibits broad-spectrum response to visible light and the overall performance is obviously superior to that of the binary MoO₃/g-C₃N₄ heterojunction. The high efficiency and versatility of the degradation imply that the newly prepared CQDs/g-C₃N₄/MoO₃ is a versatile photocatalyst for the removal of various target pollutants in the environment.

     

Bifurcation of limit cycles near equivariant compound cycles

In this paper we study some equivariant systems on the plane. We first give some criteria for the outer or inner stability of compound cycles of these systems. Then we investigate the number of limit cycles which appear near a compound cycle of a Hamiltonian equivariant system under equivariant perturbations. In the last part of the paper we present an application of our general theory to show that a Z3 equivariant system can have 13 limit cycles.     

A boundary element method and spectral analysis model for small‐amplitude viscous fluid sloshing in couple with structural vibrations

A boundary element method (BEM) is presented for the coupled motion analysis of structural vibrations with small‐amplitude fluid sloshing in two‐dimensional space. The linearized Navier–Stokes equations are considered in the frequency domain and transformed into a Laplace equation and a Helmholtz equation with pure imaginary constant. An appropriate fundamental solution for the Helmholtz equation is provided. The conditions of zero stress are imposed on the free surface, and non‐slip conditions of fluid particles are imposed on the walls of the container. For rigid motion models, the expressions for added mass and added damping to the structural motion equations are obtained. Numerical examples are presented. Copyright © 2000 John Wiley & Sons, Ltd.     

Study on Z-scan characteristics of multilayer nonlinear media using coordinate transformation method

We present a method that combines coordinate transformation and Crank-Nicholson finite difference scheme to simulate numerically Z-scan measurements of a multilayer nonlinear medium or a complicated multilayer structure. The method would be useful to design and optimize optical limiters and to determine the nonlinearities of cascading medium layers. The method has given a guideline for determining the characteristics of multilayer medium.     

机房空调在变环境温度下的数值模拟与实验研究

文中对变环境温度下的机房空调进行研究,利用实验研究与Matlab编程模拟相结合的方法,比较了不同工况下性能参数的模拟值与实测值,其偏差控制在10%左右。从研究结果中得出,随着冷凝器进风温度从35℃降低到5℃,压缩机的压比、输入功率降低,制冷量增加,整个机组的制冷系数迅速升高,从2.23迅速升高到4.24,提高47%。以及所选模型中存在的问题,分析了出现问题的原因,为机组进一步优化打下良好基础。     

Effect of duty cycles and repetition rates of QCW pumped LD on Nd:YVO<Subscript>4</Subscript> blue laser efficiency

High efficiency operation on 457 mm blue laser at room temperature in Nd:YVO₄ crystal pumped by a pulsed 808 nm diode-laser is reported in this letter. The influence of different pulse repetition rate and duty cycle on decrease of heat effect and increase of optical-to-optical efficiency has been deeply investigated. The maximum output power of 314 mW has been obtained at the pump power of 4 W. The corresponding optical-to-optical conversion efficiency 11.2% was obtained at the duty cycle of 70%.     

Conductively cooled 250-Hz single frequency Nd：YAG laser

A conductively cooled, laser diode （LD） end-pumped, injection-seeded single frequency Nd：YAG laser is designed and impleinented. The laser utilizes Nd：YAG rod as gain medium and compact dual-endpumping arrangement using two fiber-coupled LDs with a maximum output of 150 W. The optimized ramp-fire technique is applied to build reliable single longitudinal mode oscillating. The laser is capable of producing a 10-raJ Q-switched pulse with 13-ns pulse width at 1064 nm at a pulse repetition rate of 250 Hz. The output beam qualities M2 of approximately 1.19 and 1.22 in horizontal and vertical directions are detected, respectively.     

Study of particle transport in ac plasmas on HT-7 tokamak

The particle transport coefficients were investigated in ac plasmas by density modulation method on HT-7 tokamak. It is observed that the particle diffusion coefficient (D) is almost the same in various cases and varies with the electron density. The convection velocity (V) is equal to the value of inward pinch velocity (VE×B) for low and high density discharges. The particle confinement time becomes much higher when the directions of plasma current and toroidal field are uniform.