Polarographische Bestimmung von Molybd?n neben anderen Metallen

Zusammenfassung Es wird eine polarographische Bestimmungsmethode für Molybdän in Gegenwart anderer Metalle beschrieben. Molybdän(VI) gibt in Anwesenheit einer 0,25 M Ammoniumtartratlösung eine gut reproduzierbare Reduktionsstufe bei E _1/2= – 1,27 V (GKE). Die Methode wurde mit guten Ergebnissen bei der Molybdänbestimmung in Legierungen (Fehler ±1%) und mineralischem Gestein (Fehler –2%) angewandt. Der störende Einfluß von größeren Mengen Chrom(VI) wird durch ein beschriebenes säulen-chromatographisches Trennverfahren mit Hilfe des Anionenaustauschers Wofatit SBW beseitigt. Ein zehnfacher Überschuß an W(VI), Mn(II), Ni(II), Cu(II) und Tl(I) sowie gleiche Mengen an Fe(II), Fe(III), Cd(II), Co(II), V(V) und Bi(III) stören nicht.

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Summary A polarographic method for the determination of molybdenum in presence of other metals is described. Molybdenum (VI) yields a well-defined cathodic wave in ammonium tartrate medium (0.25 M) at E _1/2= –1.27 V vs. S.C.E. The results obtained have been applied to the determination of molybdenum in ores (error ±1%) and alloys (error –2%). The interfering influence of greater amounts of chromium(VI) is eliminated by ion-exchange with the strongly basic anion-exchanger Wofatit SBW. A ten-fold excess of W(VI), Mn(II), Ni(II), Cu(II) and Tl(I) as well as equal amounts of Fe(II), Fe(III), Cd(II), Co(II), V(V) and Bi(III) do not interfere.

     

Effect of pressure on the M?ssbauer isomer shift and quadrupole splitting in Au(I)-cyanides

The effect of pressure on the Mössbauer isomer shift and quadrupole splitting was studied with the 77 keV resonance of¹⁹⁷Au in the Au(I)-cyanides AuCN and KAu(CN)₂ at 4.2 K under pressures up to 80 kbar. We observe an increase of the electron density and a decrease of the absolute value of the electric field gradient at the Au nuclei in both compounds with pressure. This variation is different from the correlation that has been established for these parameters within the chemical series of Au(I) compounds at ambient pressure. It indicates that the-bonding increases strongly under pressure. X-ray diffraction studies on AuCN under pressures up to 115 kbar together with investigations of the Goldanskii-Karyagin-effect on AuCN at ambient pressure support the previous assumption that the sign of the electric field gradient at the Au(I) sites is negative.     

Magnetic structure of the spin-1/2 layer compound NaNiO2

We have carried out high resolution neutron powder diffraction experiments aiming at a determination of the magnetic structure of the S=1/2 layer compound NaNiO2. The magnetic moments are ferromagnetically aligned in the NiO2 layers and antiparallel between layers. The direction of the magnetic moment has a small component along the a-direction.     

The effect of high pressure on the electric field gradients at two inequivalent lattice sites of tantalum in ω-zirconium

The pressure variation of the electric field gradients at substitutional tantalum atoms on the two lattice sites (A and B) of ω-zirconium have been determined to be (? lnq ^A/?P)_T = ?1.05(26)10^?3 kbar^?1 and (? lnq ^B/?P)_T = +6.03(40)10^?3 kbar^?1. In addition the thermal expansion coefficients of the unit cell of ω-Zr were found to be α_‖ = +3.5(3)10^?6 K^?6 and α_⊥ = +7.9(4)10^?6 K^?1. A combined analysis of the pressure dependence and the previously determined temperature dependence of the electric field gradients supports the assumption of two different bonding types at the A and B sites.     

A biphasic transverse isotropic FEM model for cartilage

Articular cartilage is a viscoelastic, two-phase and fiber-strengthen tissue; it consists of a solid and a fluid phase. We describe this tissue using the Theory of Porous Media (TPM). Some simulation results are shown. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)