全文获取类型
收费全文 | 1561篇 |
免费 | 37篇 |
国内免费 | 12篇 |
专业分类
化学 | 1180篇 |
晶体学 | 23篇 |
力学 | 24篇 |
数学 | 110篇 |
物理学 | 273篇 |
出版年
2022年 | 7篇 |
2021年 | 7篇 |
2020年 | 15篇 |
2019年 | 26篇 |
2018年 | 21篇 |
2017年 | 14篇 |
2016年 | 28篇 |
2015年 | 35篇 |
2014年 | 36篇 |
2013年 | 92篇 |
2012年 | 89篇 |
2011年 | 93篇 |
2010年 | 50篇 |
2009年 | 73篇 |
2008年 | 82篇 |
2007年 | 83篇 |
2006年 | 84篇 |
2005年 | 82篇 |
2004年 | 96篇 |
2003年 | 86篇 |
2002年 | 74篇 |
2001年 | 27篇 |
2000年 | 21篇 |
1999年 | 17篇 |
1998年 | 21篇 |
1997年 | 24篇 |
1996年 | 26篇 |
1995年 | 17篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 16篇 |
1990年 | 15篇 |
1989年 | 15篇 |
1988年 | 10篇 |
1987年 | 16篇 |
1986年 | 6篇 |
1985年 | 31篇 |
1984年 | 11篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 13篇 |
1980年 | 14篇 |
1979年 | 7篇 |
1978年 | 9篇 |
1977年 | 13篇 |
1976年 | 10篇 |
1975年 | 7篇 |
1974年 | 7篇 |
1973年 | 10篇 |
1969年 | 7篇 |
排序方式: 共有1610条查询结果,搜索用时 31 毫秒
11.
On a certain move generating link-homology 总被引:4,自引:0,他引:4
Dedicated to Professor Kunio Murasugi on his sixtieth birthday 相似文献
12.
Midori Kobayashi Hitoshi Awoki Yoshimi Nakazaki Gisaku Nakamura 《Graphs and Combinatorics》1989,5(1):243-244
In this paper, a perfect one-factorization ofK
36 is given, which is factor-1-rotational. 相似文献
13.
Hideyuki Yoshida Yuki Ohno Kenichiro Yoshikuni Kenichiro Todoroki Hitoshi Nohta Masatoshi Yamaguchi 《Analytical sciences》2003,19(2):317-319
A simple and sensitive fluorometric high-performance liquid chromatographic method was developed for the determination of midodrine in human plasma. After liquid-liquid extraction from plasma, the drug and 2-phenylglycinol (internal standard) were convened into the corresponding fluorescent derivatives by reaction with 3,4-dihydro-6,7-dimethoxy-4-methyl-3-oxoquinoxaline-2-carbonyl chloride, a fluorescence derivatization reagent for amines. The derivatives were separated within 30 min on a reversed-phase column using isocratic elution with acetonitrile-methanol-water (10:30:60, v/v) and were detected spectrofluorometrically at 485 nm with excitation at 400 nm. The detection limit for midodrine was 0.3 pmol (76 pg) per mL plasma at a signal-to-noise ratio of 3. 相似文献
14.
A novel measurement method of the binding force between a micrometer-sized particle and a solid surface in an electrolyte solution has been established by using the electromagnetophoretic buoyancy on the particle. By this method, we investigated the binding force between a yeast cell surface and an oligosaccharide-binding protein, concanavalin A (Con A), fixed on a silica capillary wall. The force measurement was carried out up to 60 pN. In a lower surface concentration of Con A, yeast cells could be desorbed by a force less than 60 pN. However, in a higher surface concentration after treated by 1 mg ml(-1) solution, yeast cells were adsorbed with a force stronger than 60 pN. In this case, the addition of 10 mg ml(-1) D-mannose solution to the medium reduced the binding force to less than 60 pN. The observed adsorption force of yeast cells ranged within 30 - 40 pN, regardless of the interfacial amount of Con A. This force was thought to be the single binding force between a mannose group of the cell surface and an active site of Con A. Moreover, the dissociation rate constant of the single binding of yeast cell and Con A complex was determined as 4.6 x 10(-3) s(-1) and the increment of the binding distance at the transition state as 0.33 nm from the desorption kinetic experiments of yeast cell under the constant pulling conditions of 10, 20 and 30 pN. Such satisfactory results demonstrate the novel advantages of the present method. 相似文献
15.
We study the metrical theory of fibred systems, in particular, in the case of continued fraction mixing systems. We get the
limit distribution of the largest value of a continued fraction mixing stationary stochastic process with infinite expectation
and some related results. These are analogous to J. Galambos, W. Philipp, and H. G. Diamond–J. D. Vaaler theorems for the
regular continued fractions. As an application, we see that these theorems hold for Jacobi-Perron algorithm.
Received September 30, 2001; in revised form January 8, 2002 相似文献
16.
17.
18.
Tetsuo Hiramoto Masanobu Nishii Vladimir Fiala Hitoshi Yamaoka 《Journal of polymer science. Part A, Polymer chemistry》1973,11(9):2257-2263
Radiation-induced solid-state polymerization of cyclohexene sulfide has been investigated. Differential thermal analysis shows that this compound has a phase transition point at ?74°C and behaves as a plastic crystal in the temperature range from ?74 to ?20°C (melting point). By rapid cooling, this plastic crystal was easily supercooled, and below ?166°C a glassy crystal, i.e., a supercooled nonequilibrium state of plastic crystal, was obtained. In-source polymerization proceeded in the plastic crystalline state. Postpolymerization of glassy crystalline monomer irradiated at ?196°C occurred above ?166°C (glass transition point) during subsequent heating. 相似文献
19.
We prepared novel zinc 8-ethyl-8-methyl-7-oxo- and 7-ethyl-7-methyl-8-oxo-bacteriochlorins 1 and 2 possessing substituents characteristic of chlorosomal chlorophylls, exclusively observed in extramembraneous light-harvesting antennas of photosynthetic green bacteria. The electronic absorption spectra of monomeric 1 and 2 in THF were obviously different: the Q(y) maximum of the former was 724 and that of the latter was 683 nm. This observed spectral difference was clearly explained by theoretical ZINDO/S calculation of their energetically minimized molecules. The optical properties of monomeric 1/2 were controlled by the electronic effect of the 7/8-oxo groups. Specific spectral changes in the electronic, CD, and FT-IR absorption spectra by dilution of the monomeric THF solutions of 1/2 with a 100/200-fold volume of cyclohexane showed the formation of chlorosomal self-aggregation species constructed by 13-C=O...H-O(3(1))...Zn and pi-pi stacking. Especially, the red-shift values in the Q(y) band of 1/2 by self-aggregation were 2450/1970 cm(-1), indicating that exciton interaction among the composite molecules in the self-aggregation of 1 was stronger than in those of 2. Molecular model calculations for dodecamers of 1/2 based on a parallel chain arrangement gave partially different supramolecular structures; the specific hydrogen-bonding distances in 2-dodecamer were larger than those of 1-dodecamer, while both coordinations gave the same Zn-O distance. These modeling results showed that 1 was more tightly packed in the self-aggregates to give a larger red-shift value in the Q(y) band by self-aggregation than 2. The difference in the supramolecular structures is mainly ascribable to the steric effect of 8/7-dialkyl groups in self-aggregates of 1/2. 相似文献
20.
Hiroshi Saito Hitoshi Kurabe Eiichi Suzuki Fumio Watari 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1995,51(14)
The IR spectra (4000-250 cm−1) of CH3SCl and CD3SCl in solid argon have been obtained. Fundamental vibrations, except the torsional vibrations, have been assigned. Normal coordinate analysis has been carried out omitting the torsional modes. 相似文献