Observation of M3 isomeric transition from <Superscript>156m</Superscript>Pm through the βdecay of <Superscript>156</Superscript>Nd

An M3 transition in a doubly odd nucleus of ¹⁵⁶Pm was identified by internal conversion electron measurement through the β-decay of ¹⁵⁶Nd which was separated from the fission products of ²³⁵U using the on-line mass separator KUR-ISOL. The isomeric state at 150.3keV de-excites to the ground state with the M3 transition, and the spin-parity is considered to be 1^-. Nilsson configurations are also discussed on the basis of the systematics.     

Modifying estimators of ordered positive parameters under the Stein loss

This paper treats the problem of estimating positive parameters restricted to a polyhedral convex cone which includes typical order restrictions, such as simple order, tree order and umbrella order restrictions. In this paper, two methods are used to show the improvement of order-preserving estimators over crude non-order-preserving estimators without any assumption on underlying distributions. One is to use Fenchel’s duality theorem, and then the superiority of the isotonic regression estimator is established under the general restriction to polyhedral convex cones. The use of the Abel identity is the other method, and we can derive a class of improved estimators which includes order-statistics-based estimators in the typical order restrictions. When the underlying distributions are scale families, the unbiased estimators and their order-restricted estimators are shown to be minimax. The minimaxity of the restrictedly generalized Bayes estimator against the prior over the restricted space is also demonstrated in the two dimensional case. Finally, some examples and multivariate extensions are given.     

Photoexcited chemical wave in the ruthenium-catalyzed Belousov-Zhabotinsky reaction

The excitation of the photosensitive Belousov-Zhabotinsky (BZ) reaction induced by light stimulation was systematically investigated. A stepwise increase in the light intensity induced the excitation, whereas a stepwise decrease did not induce the excitation. The threshold values for the excitation were found to be a function of the initial and final light intensities, time variation in light intensity, and the concentration of NaBrO(3). The experimental results were qualitatively reproduced by a theoretical calculation based on a three-variable Oregonator model modified for the photosensitive BZ reaction. These results suggest that although the steady light irradiation is known to inhibit oscillation and chemical waves in the BZ system under almost all conditions, the stepwise increase in the light irradiation leads to the rapid production of an activator, resulting in the photoexcitation.     

An extension of the SM based on effective Peccei–Quinn Symmetry

Peccei–Quinn (PQ) mechanism based on a chiral global U(1) symmetry is considered to be a simple and elegant solution for strong CP problem. The fact that the mechanism could be experimentally examined through the axion search makes it much more interesting and recently it causes a lot of attention again. However, it is also known that the mechanism is annoyed by two serious problems, that is, a domain wall problem and goodness of global symmetry. Any global symmetry is considered not to be exact due to the quantum effect of gravity. In this paper, we consider a solution to these problems, in which quark mass hierarchy and mixing, neutrino mass generation and existence of dark matter are closely related. In our solution, PQ symmetry is assumed to be induced through symmetry breaking at an intermediate scale of a local U(1) symmetry, and a global U(1) symmetry which plays a role of Froggatt–Nielsen symmetry . In the lepton sector, a remnant of the PQ symmetry controls neutrino mass generation and dark matter existence.     

Variation in the Isospecific Active Sites of Internal Donor‐Free MgCl2‐Supported Ziegler Catalysts: Effect of External Electron Donors

The stopped‐flow polymerization of propylene was carried out using an internal donor‐free MgCl₂‐supported Ziegler catalyst in the absence or presence of external electron donors. The variation in the isospecific active sites was investigated based on the isotacticity distribution of the poly(propylene) analyzed by the TREF method. Highly isospecific active sites derived from the highest isotactic fraction (elution temperature by TREF: >112 °C) exist in the electron donor‐free catalyst system. The addition of external electron donors converted parts of the aspecific into isospecific active sites, but showed no effects on the highest isospecific active sites. The external electron donor sterically affects a coordination vacancy of each aspecific titanium species and, consequently, transfers it into an isospecific active site of high, but not highest isospecificity.     

Kinetic evaluation of various isospecific active sites on MgCl2-supported Ziegler catalysts

The formation, variation and conversion of isospecific active sites were investigated, based on the isotacticity distribution of the polypropenes analyzed by the temperature rising elution fractionation (TREF) method. Stopped-flow polymerization of propene was carried out with a MgCl₂-supported Ziegler catalyst in the absence or presence of an internal or external electron donor so that the effects and roles of the electron donors could be clarified. The results showed that various kinds of active sites with different isospecificities, including the highest isospecific active sites responsible for producing the highest isotactic fraction (elution temperature: > 112°C) existed, even in the electron donor-free catalyst system. The isospecificity of the active sites in the donor-free catalyst might have originated from a surface monolayer multinuclear titanium species, namely an “island” of titanium species. The addition of the external electron donor converted a part of the aspecific and/or low isospecific active sites into the second highest isospecific active sites, but showed no effect on the formation of the highest isospecific active sites, whereas the addition of an internal donor played an important role in creating the highest isospecific active sites as well as suppressing the formation of the aspecific active sites.