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901.
Yasunari Ikezawa Hiroshi Saito Hisashi Fujisawa Shusuke Tsuji Genjiro Toda 《Journal of Electroanalytical Chemistry》1988,240(1-2)
Carbon monoxide adsorbed on a smooth platinum electrode in the double-layer region was investigated in 1 M HClO4 solution by using in situ polarization modulation IR reflection spectroscopy and an electrochemical oxidation. From the electrochemical oxidation, the adsorbed CO could be distinguished to be comprised of stable and unstable adsorbed CO's. The unstable adsorbed CO constituted about
of the adsorbed CO, and corresponded to linearly adsorbed CO, but the band intensity of the linearly adsorbed CO was not proportional to the amount of unstable adsorbed CO. The stable adsorbed CO constituted about
; it was one-site adsorbed, and was an IR-inactive species. It is presumed that the IR-inactive species is adsorbed on two Pt atoms with the C-O axis parallel to the electrode surface and one of the Pt atoms bound to two CO molecules. 相似文献
902.
Deconjugative protonation of ()-2-alkenoate with bulky alkoxy group using potassium disilazide as the base gives (Z)-3-alkenoate selectively. 相似文献
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907.
Kazuo Itoh Masahiko Chikuma Mieko Nishimura Tomoo Tanaka Motoko Tanaka Morio Nakayama Hisashi Tanaka 《Fresenius' Journal of Analytical Chemistry》1989,333(2):102-107
Summary A sulfonic acid derivative of bismuthiol-II (bisIIS) was synthesized from 4-hydrazinobenzene sulfonic acid and carbon disulfide. Selenium(IV) was adsorbed selectively and quantitatively on the anion-exchange resin loaded with bis-IIS. Selenium adsorbed on the resin was eluted by the use of penicillamine and determined by hydride generation atomic absorption spectrometry (hydride generation/AAS). Selenium(VI) and other forms of selenium, which were not adsorbed onto the resin, were collected on the resin after digestion with nitric acid followed by reduction with hydrochloric acid. Separative preconcentration of selenium(IV), selenium(VI) and other forms of selenium in 0.5 mol/l sodium chloride could be carried out successfully by the proposed procedures. However, in the case of estuarial sea water containing a large quantity of organic substances, selenium(IV) could not be separated, because organic substances interfered with the reduction of selenium(VI) to selenium(IV) by the use of hydrochloric acid. Selenium(IV) and total amount of selenium(VI) and other forms of selenium dissolved in polluted sea water samples were determined by the proposed procedures.
Bestimmung von Selen (IV) und anderen in Meereswasser gelösten Selenformen mit Hilfe eines mit dem Sulfonsäurederivat von Bismuthiol-II beladenen Anionenaustauschers und der Hydrid-AAS相似文献
908.
Hisashi Yamada Kenji Iso Makoto Saito Hirohiko Hirasawa Natalie Fellows Hisashi Masui Kenji Fujito James S. Speck Steven P. DenBaars Shuji Nakamura 《固体物理学:研究快报》2008,2(2):89-91
InGaN/GaN‐based light emitting diodes (LEDs) grown on m ‐plane, a ‐plane and off‐axis between m ‐ and a ‐plane GaN bulk substrates were investigated. A smooth surface was obtained when a ‐plane substrate was applied; however, large amounts of defects were observed. Photoluminescence measurements of the LEDs with a well thickness of 2.5 nm revealed that all the LEDs showed the peak emission wavelength at 389 nm. The PL intensity of the a ‐plane LED is one order of magnitude lower than that of the m ‐plane LED. The a ‐plane LEDs showed significant lower electroluminescence output powers than m ‐plane LEDs, suggesting that excitons are trapped by the defects, which act as non‐radiative recombination centers. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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