Adsorption von Kohlensäure durch Ferrihydroxyd

Ohne Zusammenfassung     

T(h)-symmetrical hexakisadducts of C(60) with a densely packed pi-donor shell can act as energy- or electron-transducing systems

For the first time several T(h)-symmetrical hexakisadducts of C(60) bearing up to six electro- and photoactive o-phenylene diamine or 9,10-dialkoxyanthracene moieties were synthesized and subjected to photoinduced electron/energy-transfer studies. Both donors form a densely packed pi-donor shell surrounding the fullerene core. In these novel core-shell ensembles (7 and 19), either an efficient energy transfer from the dialkoxyanthracene periphery, or an electron transfer from the o-phenylene diamine periphery transduces the flow of excited-state energy or electrons, respectively, to the fullerene moiety, which resides in the central core. Due to the relatively high reduction potential of the fullerene core, which is anodically shifted by approximately equal to 0.7 V, compared with that of pristine C(60), the outcome of these intramolecular reactions depends mainly on the donor ability of the peripheral system. Interestingly, the charge-separated state in the o-phenylene diamine heptad (7; tau=2380 ns in benzonitrile) is stabilized by a factor of 20 relative to the corresponding o-phenylene diamine dyad (6; tau=120 ns in benzonitrile), an effect that points unequivocally to the optimized storage of charges in this highly functionalized fullerene ensemble.     

Macroreticular chelating ion-exchangers

Two macroreticular chelating ion-exchangers have been prepared and characterized. One contains the iminodiacetate group and the second contains the arsonate group as the ion-exchanging site. The macroreticular resins show selectivities among metal ions similar to those of the commercially available naicroreticular chelating resins. Chromatographie separations on the new resins are rapid and sharp.     

Numerical simulation of cavitating flow in 2D and 3D inducer geometries

A computational method is proposed to simulate 3D unsteady cavitating flows in spatial turbopump inducers. It is based on the code FineTurbo, adapted to take into account two‐phase flow phenomena. The initial model is a time‐marching algorithm devoted to compressible flow, associated with a low‐speed preconditioner to treat low Mach number flows. The presented work covers the 3D implementation of a physical model developed in LEGI for several years to simulate 2D unsteady cavitating flows. It is based on a barotropic state law that relates the fluid density to the pressure variations. A modification of the preconditioner is proposed to treat efficiently as well highly compressible two‐phase flow areas as weakly compressible single‐phase flow conditions. The numerical model is applied to time‐accurate simulations of cavitating flow in spatial turbopump inducers. The first geometry is a 2D Venturi type section designed to simulate an inducer blade suction side. Results obtained with this simple test case, including the study of its general cavitating behaviour, numerical tests, and precise comparisons with previous experimental measurements inside the cavity, lead to a satisfactory validation of the model. A complete three‐dimensional rotating inducer geometry is then considered, and its quasi‐static behaviour in cavitating conditions is investigated. Numerical results are compared to experimental measurements and visualizations, and a promising agreement is obtained. Copyright © 2004 John Wiley & Sons, Ltd.     

Flow equations for the relevant part of the pure Yang—Mills action

Wilson’s exact renormalization group equations are derived and integrated for the relevant part of the pure Yang-Mills action. We discuss in detail how modified Slavnov—Taylor identities control the breaking of BRST invariance in the presence of a finite infrared cutoff k through relations among different parameters in the effective action. In particular they imply a nonvanishing gluon mass term for nonvanishing k. The requirement of consistency between the renormalization group flow and the modified Slavnov—Taylor identities allows to control the self—consistency of truncations of the effective action.