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41.
Hiroyoshi Kamogawa Shuuji Minoura Shingo Miyama 《Journal of polymer science. Part A, Polymer chemistry》1990,28(6):1435-1444
Photoredox catalytic functions of water-soluble vinyl copolymers with pendant porphyrin or metalloporphyrin dimers were investigated. With FRA-L-ascorbic acid in aqueous solution, a vinyl copolymer bearing Mg-porphyrin dimer linked with the shortest N,N′-methylenebisamide bridge was found to have a remarkable accelerating effect under illumination of visible light as compared with that bearing Mg-porphyrin monomer and other copolymers with longer dimer bridges as well as vinyl copolymers bearing porphyrin dimers and monomer. A copolymer bearing Zn-porphyrin dimer was much inferior to that bearing monomer. Copolymers with other metals such as Co(II), Ni(II), and Cu(II) were almost inert. 相似文献
42.
T. Shizuma M. Kidera E. Ideguchi A. Odahara H. Tomura S. Suematsu T. Kuroyanagi Y. Gono S. Mitarai J. Mukai T. Komatsubara K. Furuno K. Heiguchi 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(1):25-29
Theβ + decay of86Mo has been firstly investigated by means ofβγ spectroscopy. The86Mo nuclei were produced by fusion-evaporation reactions of54 Fe (35Cl, 1 p2n) and58Ni (32S,2p 2n) at beam energies of 103 and 120 MeV, respectively. Threeγ rays of 47.3, 49.8 and 187.0 keV were unambiguously identified to follow theβ + decay of86Mo by results ofXγ andβγ coincidence and cross-bombardment. A half life and a maximumβ +-ray energy of86Mo were determined to be 19.6±1.1 s and 3.9±0.4 MeV, respectively. A decay scheme of86Mo is proposed in this article. Furthermore, a decay of86Nb has been studied using the same combinations of projectiles and targets, and a newβ-decaying isomer86m Nb was observed with a half life of 56.3±8.3 s. 相似文献
43.
Terai T Maki E Sugiyama S Takahashi Y Matsumura H Mori Y Nagano T 《Chemistry & biology》2011,18(10):1261-1272
Biotin-(strept)avidin complex is widely used in biotechnology because of its extremely high binding constant, but there is no report describing spatiotemporally controlled formation of the complex in live cells. Here, based on X-ray crystal structure analysis and calorimetric data, we designed and synthesized photoreleasable biotins, which show greatly reduced affinity for (strept)avidin, but recover native affinity after UV irradiation. For application at the cell surface, we introduced an amine-reactive moiety into these "caged" biotin molecules. Specific fluorescence imaging of live cells that had been labeled with these agents and then UV-irradiated, was accomplished by addition of streptavidin conjugated with a fluorophore. We also demonstrated the applicability of these compounds for UV-irradiated-cell-specific drug delivery by using caged-biotin-labeled cells, a prodrug, and streptavidin conjugated with a prodrug-activating enzyme. 相似文献
44.
The HIJKLM ring system of ciguatoxin CTX3C was synthesized in a convergent manner. The key steps were a conjugate addition/alkylation sequence, spiroacetalization, intramolecular allylation, ring-closing metathesis, and hydrogenation to form the 36-α-methyl substituent. 相似文献
45.
Enantioenriched synthesis of cyclopropenes with a quaternary stereocenter, versatile building blocks
Uehara M Suematsu H Yasutomi Y Katsuki T 《Journal of the American Chemical Society》2011,133(2):170-171
Ir(salen) complexes were found to catalyze enantioselective cyclopropenation efficiently. Cyclopropenation can be carried out using either a donor/acceptor- or an acceptor/acceptor-substituted diazo compound such as α-aryl-α-diazoacetates, α-phenyl-α-diazophosphonate, 2,2,2-trifluoro-1-phenyl-1-diazoethane, and α-cyano-α-diazoacetamide as carbenoid precursors. The reactions provide highly enantioenriched cyclopropenes (84-98% ee) with a functionalized quaternary carbon as versatile building blocks. 相似文献
46.
Kitamura C Takenaka A Kawase T Kobayashi T Naito H 《Chemical communications (Cambridge, England)》2011,47(23):6653-6655
Tetracene octaesters, which were prepared by twofold [2+2+2] cocyclization, were isolated as red, orange, and orange-yellow solids for the methyl, ethyl, and propyl ester derivatives, respectively. X-Ray crystallographic analysis reveals that the difference in solid-state color arises owing to differences in molecular packing. 相似文献
47.
Ultrafine MgAl2O4 powder has been synthesized by a polymerized complex method. Heating of a precursor solution containing citric acid (CA), ethylene glycol (EG) and Mg and Al salts with a molar ratio of Mg/Al/CA/EG=1/2/8/32 at 180°C produced a transparent polymeric gel, which have been characterized by FT-IR spectroscopy and TG/DTA. The organic fraction was removed by controlled thermal treatments (350–1200°C) whereby the bimetallic oxide was formed. XRD analysis showed the presence of MgAl2O4 at 600°C. TEM observation showed that the spherical nanosized powders with good uniformity was obtained. Furthermore, these powders showed excellent sinterability, relative density up to 99.8% was achieved when sintered at 1550°C for 3 h in air without any sintering additive. 相似文献
48.
Closed form approximate expressions are derived for the mode-coupling, radiation loss and losses of each guided mode in multimode clad-type dielectric slab waveguides due to the index inhomogeneities of the core material. The analysis considers the inhomogeneities of the core-index in the axial and transverse directions and includes correlation lengths of any magnitude. It allows us to conclude that there will be considerable mode-dependency for the mode-coupling and radiation loss if the axial and/or transverse correlation lengths are of the order of or greater than the wavelength. It is also found that the mode-coupling and radiation loss peak at some value of the axial correlation length, and the radiation loss can be reduced by increasing the refractive-index difference of the core and cladding materials. Finally, it is shown that if the correlation lengths are shorter than, or of the order of the wavelength, the losses of each guided mode will mainly be due to the radiation process. But, in the case where the axial correlation length is much greater than the wavelength, the scattering into other guided modes is the dominant mechanism. 相似文献
49.
Ei-ichi Nishizawa Leenawaty Limantara Noriyuki Nanjou Hiroyoshi Nagae Tomisaburo Kakuno Yasushi Koyama 《Photochemistry and photobiology》1994,59(2):229-236
The frequency of BChl that was bound to the light-harvesting complex (LHC) of Rhodobacter sphaeroides R26 was found to be 1598 cm-1 , a result which suggests that a pair of BChl molecules form a dimer in the LHC in the T1 state. 相似文献
50.
Hiroyoshi Kamogawa Kunimichi Kitahora Hidehito Hanawa Masato Nanasawa 《Journal of polymer science. Part A, Polymer chemistry》1976,14(5):1235-1240
Several polymerizable hydroquinone derivatives were prepared by the Williamson synthesis. Thus, hydroquinone mono(p-vinylbenzyl) ether (III-1), hydroquinone methyl p-vinylbenzyl ether (III-4), and hydroquinone benzyl p-vinylbenzyl ether (III-5), tert-butylhydroquinone mono(p-vinylbenzyl) ether (III-2), and 2,5-di-tert-butylhydroquinone mono(p-vinylbenzyl) ether (III-3) were synthesized by the reactions of p-chloromethylstyrene with the corresponding hydroquinone derivatives in alcoholic potassium hydroxide or with their potassium salts in dipolar aprotic solvents. All monomers were found to polymerize by free-radical initiation except III-3, which required a cationic initiator. 相似文献