Novel applications of 2-cyanoethylanilines in the synthesis of conjugated primary and secondary anilines

2-Cyanoethyl anilines were controllably cleaved by 1 equiv of potassium t-butoxide in dry THF with a reaction that can be used in situ with the Wittig reaction to synthesize conjugated primary and secondary anilines.     

A co‐ordinate system independent streamwise upwind method for fluid flow computation

A new co‐ordinate invariant streamwise upwind formulation for convection dominated flows is developed. The eddy diffusivity/viscosity is added directly to the equations in order to remove the oscillations in the solution. The equations then can be solved by any high‐order scheme and the solution retains the accuracy of the high‐order scheme. The accuracy and reduced lateral thickness growth rate are demonstrated with several numerical examples, including pure convective flows and lid‐driven cavity flow. The lateral spreading due to the numerical diffusion is controlled by the anisotropic tensor. Copyright © 2004 John Wiley & Sons, Ltd.     

Inviscid,laminar and turbulent opposed flows

This paper attempts to reproduce numerically previous experimental findings with opposed flows and extends their range to quantify the effects of upstream pipes and nozzles with inviscid, laminar and turbulent flows. The choice of conservation equations, boundary conditions, algorithms for their solution, the degree of grid dependence, numerical diffusion and the validity of numerical approximations are justified with supporting calculations where necessary. The results of all calculations on the stagnation plane show maximum strain rates close to the annular exit from the nozzles and pipes for lower separations and it can be expected that corresponding reacting flows will tend to extinguish in this region with the extinction moving towards the axis. With laminar flows, the maximum strain rate increased with Reynolds number and the maximum values were generally greater than with inviscid flows and smaller than with turbulent flows. With large separations, the strain rates varied less and this explains some results with reacting flows where the extinction appeared to begin on the axis. The turbulent‐flow calculations allowed comparison of three common variants of a two‐equation first‐moment closure. They provided reasonable and useful indications of strain rates but none correctly represented the rms of velocity fluctuations on the axis and close to the stagnation plane. As expected, those designed to deal with this problem produced results in better agreement with experiment but were still imperfect. Copyright © 2004 John Wiley & Sons, Ltd.     

Time resolved spectroscopic NMR imaging using hyperpolarized Xe

We have visualized the melting and dissolution processes of xenon (Xe) ice into different solvents using the methods of nuclear magnetic resonance (NMR) spectroscopy, imaging, and time resolved spectroscopic imaging by means of hyperpolarized ¹²⁹Xe. Starting from the initial condition of a hyperpolarized solid Xe layer frozen on top of an ethanol (ethanol/water) ice block we measured the Xe phase transitions as a function of time and temperature. In the pure ethanol sample, pieces of Xe ice first fall through the viscous ethanol to the bottom of the sample tube and then form a thin layer of liquid Xe/ethanol. The xenon atoms are trapped in this liquid layer up to room temperature and keep their magnetization over a time period of 11 min. In the ethanol/water mixture (80 vol%/20%), most of the polarized Xe liquid first stays on top of the ethanol/water ice block and then starts to penetrate into the pores and cracks of the ethanol/water ice block. In the final stage, nearly all the Xe polarization is in the gas phase above the liquid and trapped inside the pores. NMR spectra of homogeneous samples of pure ethanol containing thermally polarized Xe and the spectroscopic images of the melting process show that very high concentrations of hyperpolarized Xe (about half of the density of liquid Xe) can be stored or delivered in pure ethanol.     

The 7th Asian Symposium on Visualization

The 7th Asian Symposium on Visualization (7ASV) was successfully held in Singapore from 3^rd to 7^th November 2003. This event was originally scheduled from 26^th to 30^th May 2003, but had to be postponed because of the outbreak of SARS (Severe Acute Respiratory Syndrome) in some parts of the world. A total number of 122 participants attended the Symposium of which, 107 were foreign participants from 16 countries (excluding Singapore) worldwide. There were 104 papers covering broad range of topics presented at the Symposium which were delivered in 2×7 long sessions, and 9 keynote papers.     

X-ray damage characterization in BaLiF3,KMgF3 and LiCaAlF6 complex fluorides

Two-inch sized KMgF₃,BaLiF₃ and LiCaAlF₆ (LiCAF) single crystals were grown by the Czochralski method under a CF₄ atmosphere. X-ray irradiation was used to carry out a comparative study of induced optical absorption phenomena and colour centre creation in the ultra-violet and visible spectral regions. The integral of the induced absorption spectra is significantly lower in LiCAF with respect to the other studied materials. It is found that the amplitude of the F-absorption band is suppressed more than a factor of 3 by Mg-doping. For Mg-doped crystals, the optimum doping concentration is about 0.2 mol% of Mg²⁺.     

New data on the ternary fission of 252Cf from the Gammasphere facility

Ternary fission of ²⁵²Cf was studied at Gammasphere using eight ΔE×E particle telescopes. Helium, beryllium, boron, and carbon light charged particles (LCPs) emitted with kinetic energy more than 9, 21, 26, and 32 MeV, respectively, were identified. The 3368-keV γ transition from the first 2⁺ excited state in ¹⁰Be was found and the population probability ratio N(2⁺)/N(0⁺) = 0.160 ± 0.025 was estimated. No evidence was found for 3368-keV γ rays emitted from a triple molecular state. For the first time, charge distributions are obtained for ternary fission fragments emitted with helium, beryllium, and carbon LCPs.     

Nontrivial manifestation of clustering in fission of heavy nuclei at low and middle excitations

An analysis of the preferable fission path manifesting itself as a fine structure of the total kinetic energy-mass distribution of the fission fragments compelled us to put forward an absolutely new shape of the fissioning system on the descent from the fission barrier. It is a multicomponent nuclear molecule constituted by two magic clusters and a torus-like neck between.     

Cyclotron production and quality control of “high specific activity' radionuclides in “no-carrier-added” form for radioanalytical applications in the life sciences

Radionuclides of very high specific activity A _S(t) have great relevance for applications in the life sciences. Updated definitions of A _S are given. The real A _S(t) must be measured by analytical and radioanalytical techniques. No-carrier-added (NCA) radionuclides have A _S(NCA) sometimes close to the carrier-free (CF) value A _S(CF). The accurate knowledge of excitation functions of nuclear reactions vs. ion beam energy is mandatory to maximize A _S(NCA); the minimization of isotopic dilution factor IDF(t) has been achieved too. A range of accelerator production and radioanalytical QC methods for A _S(NCA) optimization and determination is presented. This revised version was published online in August 2006 with corrections to the Cover Date.     

1,1‐Organoboration of bis(trimethylstannyl)ethyne with trimethylsilyl‐ and dimethylsilyl‐dialkylboryl‐substituted alkenes: organometallic‐substituted allenes

The reactions of bis(trimethylstannyl)ethyne, Me₃Sn–C?C–SnMe₃ ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by ²⁹Si and ¹¹⁹Sn NMR, and the products were characterized by an extensive NMR data set (¹H, ¹¹B, ¹³C, ²⁹Si, ¹¹⁹Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd.