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41.
Maity P Tsunoyama H Yamauchi M Xie S Tsukuda T 《Journal of the American Chemical Society》2011,133(50):20123-20125
A new class of monolayer-protected Au clusters with Au-C covalent bonds (organogold clusters) was synthesized by ligating phenylacetylene (PhC≡CH) to PVP-stabilized Au clusters. Matrix-assisted laser desorption ionization mass spectrometry revealed for the first time a series of stable compositions of the organogold (Au:C(2)Ph) clusters. 相似文献
42.
43.
Ariga K Ishihara S Izawa H Xia H Hill JP 《Physical chemistry chemical physics : PCCP》2011,13(11):4802-4811
A landmark accomplishment of nanotechnology would be successful fabrication of ultrasmall machines that can work like tweezers, motors, or even computing devices. Now we must consider how operation of micro- and molecular machines might be implemented for a wide range of applications. If these machines function only under limited conditions and/or require specialized apparatus then they are useless for practical applications. Therefore, it is important to carefully consider the access of functionality of the molecular or nanoscale systems by conventional stimuli at the macroscopic level. In this perspective, we will outline the position of micro- and molecular machines in current science and technology. Most of these machines are operated by light irradiation, application of electrical or magnetic fields, chemical reactions, and thermal fluctuations, which cannot always be applied in remote machine operation. We also propose strategies for molecular machine operation using the most conventional of stimuli, that of macroscopic mechanical force, achieved through mechanical operation of molecular machines located at an air-water interface. The crucial roles of the characteristics of an interfacial environment, i.e. connection between macroscopic dimension and nanoscopic function, and contact of media with different dielectric natures, are also described. 相似文献
44.
45.
Takemoto H Honda K Masaki S Shimada Y Fujimoto I 《The Journal of the Acoustical Society of America》2006,119(2):1037-1049
A 3D cine-MRI technique was developed based on a synchronized sampling method [Masaki et al., J. Acoust. Soc. Jpn. E 20, 375-379 (1999)] to measure the temporal changes in the vocal tract area function during a short utterance /aiueo/ in Japanese. A time series of head-neck volumes was obtained after 640 repetitions of the utterance produced by a male speaker, from which area functions were extracted frame-by-frame. A region-based analysis showed that the volumes of the front and back cavities tend to change reciprocally and that the areas near the larynx and posterior edge of the hard palate were almost constant throughout the utterance. The lower four formants were calculated from all the area functions and compared with those of natural speech sounds. The mean absolute percent error between calculated and measured formants among all the frames was 4.5%. The comparison of vocal tract shapes for the five vowels with those from the static MRI method suggested a problem of MRI observation of the vocal tract: data from static MRI tend to result in a deviation from natural vocal tract geometry because of the gravity effect. 相似文献
46.
Ki Hyeon Kim Masahiro Yamaguchi Hironori Orikasa Takashi Kyotani 《Solid State Communications》2006,140(11-12):491-494
The radio frequency characteristics of Permalloy nanorods’ array have been examined by coplanar waveguide (CPW) cell. The Permalloy nanorods’ array was grown in anodic aluminum oxide porous templates with a diameter of 20 nm. As the Permalloy nanorods’ array was placed on CPW, the characteristic impedances of the CPW were changed from 50 to at 1 GHz. The magnitude of inductance was decreased from 3 GHz and the capacitance was increased up to twice in comparison with that of CPW. The signal attenuations were abruptly increased over 1 GHz. The propagation wavelengths due to the insertion of Permalloy nanorods’ array were decreased about 30% at 1 GHz in comparison with that of CPW without magnetic materials. 相似文献
47.
Spectroscopic and thermodynamic investigations on complexation of naphthalene-appended amino-beta-cyclodextrins 1 and 2 with cyclic alcohols (cyclohexanol and cycloheptanol) and acyclic alcohols (1-pentanol, 2-pentanol, 1-hexanol, and 1-heptanol) have been carried out. Host 1 exhibits a drastic fluorescent enhanced-signal change in the presence of alcohol guests in aqueous solution. [structure: see text] 相似文献
48.
Kazuo Akutagawa Hironori Kumura 《Calculus of Variations and Partial Differential Equations》2013,48(1-2):67-88
The classical Hardy inequality for the Laplacian Δ on ${\mathbb{R}^n}$ shows the borderline-behavior of a potential V for the following question: whether the Schrödinger operator ?Δ + V has a finite or infinite number of the discrete spectrum. In this paper, we will give a sharp generalization of this inequality on ${\mathbb{R}^n}$ to a relative version of that on large classes of complete noncompact manifolds. Replacing ${\mathbb{R}^n}$ by some specific classes of complete noncompact manifolds, including hyperbolic spaces, we also establish some sharp criteria for the above-type question. 相似文献
49.
Background
The purpose of this study was to examine task-related changes in prefrontal cortex (PFC) activity during a dual-task in both healthy young and older adults and compare patterns of activation between the age groups. We also sought to determine whether brain activation during a dual-task relates to executive/attentional function and how measured factors associated with both of these functions vary between older and younger adults.Results
Thirty-five healthy volunteers (20 young and 15 elderly) participated in this study. Near-infrared spectroscopy (NIRS) was employed to measure PFC activation during a single-task (performing calculations or stepping) and dual-task (performing both single-tasks at once). Cognitive function was assessed in the older patients with the Trail-making test part B (TMT-B). Major outcomes were task performance, brain activation during task (oxygenated haemoglobin: Oxy-Hb) measured by NIRS, and TMT-B score. Mixed ANOVAs were used to compare task factors and age groups in task performance. Mixed ANOVAs also compared task factors, age group and time factors in task-induced changes in measured Oxy-Hb. Among the older participants, correlations between the TMT-B score and Oxy-Hb values measured in each single-task and in the dual-task were examined using a Pearson correlation coefficient. Oxy-Hb values were significantly increased in both the calculation task and the dual-task within patients in both age groups. However, the Oxy-Hb values associated with there were higher in the older group during the post-task period for the dual-task. Also, there were significant negative correlations between both task-performance accuracy and Oxy-Hb values during the dual-task and participant TMT-B scores.Conclusions
Older adults demonstrated age-specific PFC activation in response to dual-task challenge. There was also a significant negative correlation between PFC activation during dual-task and executive/attentional function. These findings suggest that the high cognitive load induced by dual-task activity generates increased PFC activity in older adults. However, this relationship appeared to be strongest in participants with better baseline attention and executive functions. 相似文献50.
Hironori Okamura Takanobu Fujioka Naoki Mori Tohru Taniguchi Kenji Monde Hidenori Watanabe Hirosato Takikawa 《Tetrahedron letters》2019,60(32):150917
Salinipostins are cyclic enol-phosphotriesters isolated from a marine-derived Salinispora sp. as antimalarial compounds. Herein, the first enantioselective synthesis of salinipostin A was achieved. Organocatalyst-mediated asymmetric cyclopropanation and regioselective cyclopropane ring opening were the key steps. 相似文献