全文获取类型
收费全文 | 485篇 |
免费 | 20篇 |
专业分类
化学 | 465篇 |
力学 | 2篇 |
数学 | 9篇 |
物理学 | 29篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 10篇 |
2018年 | 5篇 |
2016年 | 10篇 |
2015年 | 10篇 |
2014年 | 8篇 |
2013年 | 14篇 |
2012年 | 32篇 |
2011年 | 42篇 |
2010年 | 13篇 |
2009年 | 15篇 |
2008年 | 29篇 |
2007年 | 38篇 |
2006年 | 34篇 |
2005年 | 29篇 |
2004年 | 35篇 |
2003年 | 21篇 |
2002年 | 29篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1983年 | 2篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1968年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有505条查询结果,搜索用时 15 毫秒
51.
Kamo T Kasahara R Abe S Hirota M Sugano M Yamaya H Hiradate S Fujii Y 《Natural product research》2010,24(17):1637-1642
The 13C labels of [13C]carbon dioxide and D-[13C?]glucose were incorporated into cyanamide (NH?CN) when they were administered to Vicia villosa subsp. varia shoots. In contrast, the administration of sodium [2,3-13C?]pyruvate did not affect the relative area of the [M + 1]+ ion of cyanamide in the gas chromatography-mass spectrometry analysis. [2,3-13C?]pyruvate was incorporated into organic acids that are part of the citric acid cycle, such as succinate and fumarate, confirming that the shoots absorbed and metabolised it. These observations demonstrated that the carbon atom of cyanamide is derived from any of the carbohydrates that are present upstream of pyruvate in the metabolic pathway. 相似文献
52.
Summary We consider the stationary Navier-Stokes equations in a certain type of semi-infinite channel under the general outflow condition. Assuming that the domain and the data are symmetric with respect to a straight line, the axis of symmetry, and that the axis intersects every component of the boundary, we show the existence of solutions and certain regularity properties of the solutions.
Sunto In questo lavoro consideriamo le equazioni di Navier-Stokes stazionarie in un certo tipo di canali semi-infiniti sotto la condizione generale di outflow. Assumendo che sia il dominio sia i dati siano simmetrici rispetto ad una retta, l’asse di simmetria, e che questa retta intersechi ogni componente del bordo, mostriamo esistenza di soluzioni ed alcune proprietà di regolarità delle stesse.相似文献
53.
54.
55.
A predual of B_σ-spaces is investigated. A predual of a predual of B_σ-spaces is also investigated,which can be used to investigate the boundedness property of the commutators. The relation between Herz spaces and local Morrey spaces is discussed. As an application of the duality results, one obtains the boundedness of the singular integral operators, the Hardy-Littlewood maximal operators and the fractional integral operators, as well as the commutators generated by the bounded mean oscillation(BMO) and the singular integral operators.What is new in this paper is that we do not have to depend on the specific structure of the operators. The results on the boundedness of operators are formulated in terms of B_σ-spaces and B_σ-spaces together with the detailed comparison of the ones in Herz spaces and local Morrey spaces. Another application is the nonsmooth atomic decomposition adapted to B_σ-spaces. 相似文献
56.
Nobutaka Takahashi Noboru Murofushi Saburo Tamura Nobuhide Wasada Hiroko Hoshino Toshikazu Tsuchiya Shin-Ichi Sasaki Tetsumi Aoyama Eiji Watanabe 《Journal of mass spectrometry : JMS》1969,2(7):711-722
Based on the element maps of twenty-two gibberellin methyl esters fragmentations are discussed, which are characteristic of the common structural features as well as structural modification in gibberellin homologues. 相似文献
57.
Morohashi N Noji S Nakayama H Kudo Y Tanaka S Kabuto C Hattori T 《Organic letters》2011,13(13):3292-3295
Powdery crystals of p-tert-butylthiacalix[4]arene (2) selectively include EtOH from 1:1 mixtures of MeOH-EtOH and EtOH-PrOH, and EtCO(2)H from HCO(2)H-EtCO(2)H. On the other hand, no acid is included from HCO(2)H-MeCO(2)H, even though MeCO(2)H is included from the neat acid. The origins of these phenomena are discussed based on X-ray analysis of inclusion crystals prepared separately by crystallization. 相似文献
58.
Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly Prussian blue analogs, which have unique properties. In this perspective, we describe a charge-transfer phase transition, reversible photomagnetism, second harmonic generation and magnetization-induced second harmonic generation, ferroelectric ferromagnetism, humidity-sensitive magnetism, high ionic conductivity, and a coupling effect (which we named spin-ionics) between ionic conduction and magnetic ordering with Prussian blue analogs. 相似文献
59.
Hiroko Nakagawa Kumiko Ohtsuka Katsuhito Sugahara Chika Kobayashi Yuichi Masuoka Koh-ichi Yamada Masami Kawase 《Tetrahedron: Asymmetry》2010,21(6):659-664
Helical [5]thiaheterohelicene 5HM, which rapidly interconverts between P and M enantiomers in solution, was connected to helical l-phenylalanine oligomers with an ester linkage to give peptidehelicenes (5Fn, where n: number of bonded phenylalanines). The characteristics of 5F4 and 5F5 with two types of helixes in a molecule were investigated, particularly in comparison with those of 5F1–5F3 with an incomplete coil of a peptide moiety. l-Phenylalanine peptide chains induced a shift in the equilibrium between the P and M helixes of 5HM toward the P side for all the 5Fns examined. The enantiomeric excess (ee) of the P form increased with a decrease in temperature, together with an elongation of the peptide chains. 5F4 and 5F5 in hot solutions of some solvents formed a gel at room temperature, whereas 5F1–5F3 showed no such behavior. In this gel, the stable helical form of the 5HM moiety in 5F4 and 5F5 was observed to be the M form in contrast to that in their solutions. 相似文献
60.
A diketone precursor of air-stable bis-2-thienyl-2,6-anthracene was prepared and quantitatively converted to the target acene by photoirradiation of the n-π∗ absorption both in solution and as a film, in air. 相似文献