Mode-selective internal conversion of perylene

We observed fluorescence excitation spectra and dispersed fluorescence spectra for single vibronic level excitation of jet-cooled perylene-h ₁₂ and perylene-d ₁₂, and carefully examined the vibrational structures of the S₀ ¹ A _g and S₁ ¹ B _2u states. We performed vibronic assignments on the basis of the results of ab initio calculation, and found that the vibrational energies in the S₁ state are very similar to those in the S₀ state, indicating that the potential energy curves are not changed much upon electronic excitation. We conclude that the small structural change is the main cause of its slow radiationless transition and high fluorescence quantum yield at the zero-vibrational level in the S₁ state. It has been already reported that the lifetime of perylene is remarkably short at specific vibrational levels in the S₁ state. Here, we show that the mode-selective nonradiative process is internal conversion (IC) to the S₀ state, and the ν₁₆(a _g ) in-plane ring deforming vibration is the promoting (doorway) mode in the S₁ state which enhances vibronic coupling with the high-vibrational level (b _2u ) of the S₀ state.     

Utilization and Modification of Perovskite-Type Layered Structures as Inorganic-Organic Hybrid Materials

Abstract

The aromatic ammonium-based layered halide compounds were obtained of bis(4-nitroanilinium)tetrachlorocadmate and bis(2-methyl-4-nitroanilinium) tetrachlorocadmate, aiming at a new type of inorganic-organic hybrid layered material. X-ray diffraction analyses of the single crystals revealed that both of the crystals take an alternate layered structure of the organic bilayer and the inorganic sheet. Cadmium ion and chloride anions form six-coordinated octahedra whose corner anions are shared with the neighboring octahedra for the crystal of bis(4-nitroanilinium)tetrachlorocadmate. In the case of bis(2-methyl-4-nitroanilinium) tetrachlorocadmate crystal the inorganic portion takes distorted four-coordinated tetrahedra. The structure of the inorganic portion for the latter crystal can be considered to be caused by the distortion of a perovskite-type octahedron due to the introduction of a bulky organic molecule.     

Compact Permanent Magnetic Circuit with Periodic Magnetic Field Designed for Studies of Liquid Crystals

Abstract

We have developed a high-performance compact magnetic circuit to investigate orientational phase behaviors of biological and synthetic macromolecular systems by using spectroscopic methods such as X-ray scattering and light scattering. This magnetic circuit can apply a periodic magnetic field and gradient to samples. The maximum values of the magnetic field strength and gradient are varied from 1.5 tesla to 0.55 tesla and from 2.4 × 10² tesla/m to 7.3 × 10¹ tesla/m. Owing to the high periodicity of the magnetic field strength and gradient macromolecules are subjected to both rotational and translational forces from the magnetic field. We show some prominent features of this magnetic circuit and its first application to the synchrotron radiation small-angle X-ray scattering (SR-SAXS) studies of supermacromolecular liquid crystals.     

Packing state in bilayer membranes of diacylphosphatidylcholines with varying acyl chain lengths under high pressures

The bilayer packing states of a series of diacylphosphatidylcholines (CnPC) containing linear saturated acyl chains were examined by a high-pressure fluorescence method. We revealed from the second derivatives of Prodan fluorescence spectra for all bilayer membranes that the Prodan molecules can be distributed into multiple sites in these bilayer membranes and move around the head-group region, depending on the phase state. The hydrophobicity of the PC molecules markedly affected the distribution quantities of the Prodan molecules between the gel and liquid crystalline phases. The distribution of the Prodan molecules into the gel phase decreased with the increasing acyl chain length while that into the liquid crystalline phase conversely increased. The present study suggests that Prodan can sensitively recognize the packing states and strengths in the bilayer membranes and becomes a good packing indicator.     

On Derived Equivalences for Selfinjective Algebras

We show that if A is a representation-finite selfinjective Artin algebra, then every P ^? ? K ^b(𝒫 _A ) with Hom _K(Mod?A)(P ^?,P ^?[i]) = 0 for i ≠ 0 and add(P ^?) = add(νP ^?) is a direct summand of a tilting complex, and that if A, B are derived equivalent representation-finite selfinjective Artin algebras, then there exists a sequence of selfinjective Artin algebras A = B ₀, B ₁,…, B _m  = B such that, for any 0 ≤ i < m, B _i+1 is the endomorphism algebra of a tilting complex for B _i of length ≤ 1.     

The Leading Ideal of a Complete Intersection of Height Two,Part III

Let (S, 𝔫) be an s-dimensional regular local ring with s > 2, and let I = (f, g) be an ideal in S generated by a regular sequence f, g of length two. As in [2 Goto , S. , Heinzer , W. , Kim , M.-K. ( 2006 ). The leading ideal of a complete intersection of height two . J. Algebra 298 : 238 – 247 . [Google Scholar], 3 Goto , S. , Heinzer , W. , Kim , M.-K. ( 2007 ). The leading ideal of a complete intersection of height two, II . J. Algebra 312 : 709 – 732 . [Google Scholar]], we examine the leading form ideal I* of I in the associated graded ring G: = gr_𝔫(S). Let μ _G (I*) = n ≥ 3, and let {ξ₁, ξ₂,…, ξ _n } be a minimal homogeneous system of generators of I* such that ξ₁ = f* and ξ₂ = g*, and c _i : = deg ξ _i  ≤ deg ξ _i+1: = c _i+1 for each i ≤ n ? 1. For m ≤ n, we say that K _m : = (ξ₁,…, ξ _m )G is an ideal generated by part of a minimal homogeneous generating set of I*. Let D _i : = GCD(ξ₁,…, ξ _i ) and d _i  = deg D _i for i with 1 ≤ i ≤ m. Let K _m be perfect with ht _G K _m  = 2. We prove that the following are equivalent: 1. deg ξ _i+1 = deg ξ _i  + (d _i?1 ? d _i ) +1, for all i with 3 ≤ i ≤ m ? 1;

2. deg ξ _i+1 ≤ deg ξ _i  + (d _i?1 ? d _i ) +1, for all i with 3 ≤ i ≤ m ? 1.

Furthermore, if these equivalent conditions hold, then K _m  = I*. Moreover, if e(G/K _m ) = e(G/I*), we prove that K _m  = I*. We illustrate with several examples in the cases where K _m is or is not perfect.     

DEA environmental assessment: Measurement of damages to scale with unified efficiency under managerial disposability or environmental efficiency

This study proposes a use of Data Envelopment Analysis (DEA) for environmental assessment. Firms usually produce not only desirable but also undesirable outputs as a result of their economic activities. The concept of disposability on undesirable outputs is separated into natural and managerial disposability. Natural disposability is an environmental strategy in which firms decrease their inputs to reduce a vector of undesirable outputs. Given the reduced input vector, they attempt to increase desirable outputs as much as possible. Managerial disposability involves the opposite strategy of increasing an input vector. The concept of disposability expresses an environmental strategy that considers a regulation change on undesirable outputs as a new business opportunity. Firms attempt to improve their unified (operational and environmental) performance by utilizing new technology and/or new management. Considering the two disposability concepts, this study discusses how to measure unified efficiency under managerial disposability and then discusses how to measure environmental efficiency. The proposed uses of DEA can serve as an empirical basis for measuring new economic concepts such as “Scale Damages (SD)”, corresponding to scale economies for undesirable outputs, and “Damages to Scale (DTS)”, corresponding to returns to scale for undesirable outputs.     

Post-merger cultural integration from a social network perspective: a computational modeling approach

Although cultural integration, or sharing a common corporate culture, is crucial for the success of mergers, previous studies have been limited to firm-level analyses. From a social network perspective, this study explores how cultural integration emerges from the patterns of social interactions among individuals. Using an agent-based model, we investigate the impact of network structures within and between two merging firms on post-merger cultural integration and organizational dysfunctions—individual turnover, interpersonal conflict and organizational communication ineffectiveness—that arise from insufficient cultural integration. The simulation results demonstrate that the highest level of cultural integration is achieved when social ties are more centralized within each merging firm and the social ties between the merging firms are less concentrated on central individuals. Additionally, the results show that within-firm and between-firm network structures significantly affect individual turnover, interpersonal conflict and organizational communication ineffectiveness, and that these three outcome measurements do not vary in tandem.