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161.
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163.
Hiromi Takiguchi Tamao Odake Tomonari Umemura Hiroki Hotta Kin-ichi Tsunoda 《Analytical sciences》2005,21(11):1269-1274
The formation conditions and characteristics of a liquid/liquid optical waveguide (LLW) were studied using a two-phase sheath flow, where the inner organic phase flow acted as the core and the outer aqueous flow acted as the clad. In immiscible solvent systems, i.e., toluene/water and diethyl ether/water systems, the LLWs were formed in the range of higher than ca. 600 of the Reynolds number (Re), where the linear velocity of the organic solvent was much higher than that of the aqueous solution. On the other hand, in a miscible solvent system, i.e., a tetrahydrofuran/water system, a stable LLW was formed in the range of a much lower Re than in immiscible systems. Moreover, the molecules at the toluene/water interface of the LLW were observed with both fluorescence and absorbance measurement systems. In particular, the change in the fluorescence spectrum of 1-anilino-8-naphthalenesulfonate (ANS) at the interface within 1 ms was observed by this method, indicating the usefulness of the LLW for a fast kinetic study of a liquid/liquid interface. 相似文献
164.
Keisuke Yoshiki Hiroki Azuma Kazuhiko Yoshioka Mamoru Hashimoto Tsutomu Araki 《Optical Review》2005,12(5):415-419
We have investigated the fluorescence lifetime properties of 8 calcium ion probes, calcium-green-1, calcium green-2, calcium
green-5N, calcium orange, oregon green 488 BAPTA-6F, fluo-3, fluo-4, and fluo-5N. We found that the decay time of calcium
green-5N varied more sensitively with calcium concentration than calcium green-1 which was known to be a highly sensitive
probe. We have also found that the center of observable range of calcium concentration by fluorescence lifetime measurement
is lower than that by fluorescence intensity measurement. 相似文献
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166.
A laser Doppler imaging system with a TV camera has been constructed and velocity distributions of fluid flow in cross sections of a rectangular channel have been measured. Consequently, it has been found that the system has some advantages in comparison with usual laser Doppler velocimeters, for example, the visualization of flow can be easily achieved. 相似文献
167.
A void network in a-Si films prepared by vacuum deposition was studied. A close relationship in annealing behavior has been observed between the changes in surface area of voids and in the ESR signal strength. 相似文献
168.
Hiroki Nakatsuka Makoto Tomita Masahiro Fujiwara Shuji Asaka 《Optics Communications》1984,52(2):150-152
Subpicosecond time resolutions have been obtained in photon echoes when a sample was excited by two nanosecond dye laser pulses with a smooth and broad spectrum. The dye laser was pumped by second harmonics of a Q-switched Nd:YAG laser, and the pulse width was 10 ns. The sample was 3% Nd3+-doped silicate glass, and the center frequency of the dye laser was tuned at 5910 Å on resonance with the 4I ? 2G, 4G transition of Nd3+. The homogeneous transverse relaxation time T2 was measured to be 91 ps at 10 K in agreement with the previous measurements by picosecond pulses. 相似文献
169.
Trimethylene carbonate was readily obtained in the reaction of oxetane and carbon dioxide in the presence of tetraphenylstibonium iodide. 相似文献
170.
Takao Yamazaki Masanori Nagata Katsuhide Matoba Hiroki Takahata Raymond N. Castle 《Journal of heterocyclic chemistry》1977,14(3):469-472
Homoveratrylamine (II) was condensed with 3-(2-carbomethoxyethyl)-1,3-dimethyl-2-pyrrol-idone (Ib) to furnish the corresponding amide (III), which was subjected to the Bischler-Napieralski reaction to afford the corresponding dihydroisoquinoline derivative (IV). Compound V was obtained by the reductive ring closure of Vila which was obtained by the hydrogena-tion of IV. The stereochemistry of V is proposed to have the anti-trans-trans quinolizidine conformation. 相似文献