Excitonic properties of nanostructure semimagnetic semiconductors

Magneto-optical properties of semimagnetic semiconductors with nanometer-scale structures (nanostructures) are described. Superlattices of the CdTe/Cd_{1 − x}Mn_xTe and Cd_{1 − x}Mn_xTe/ZnTe systems and microcrystals of Cd_{1 − x}Mn_xSe were grown by epitaxy and sputtering methods. These semimagnetic semiconductor nanostructures show remarkably enhanced magneto-optical responses in the optical absorption, the luminescence and the dynamics of the confined excitons. The results are interpreted by the quantum-confined excitonic states interacting with the magnetic ion spins involved in the nanostructures.     

Novelty Filtering Using Phase Conjugate Wave in Organic Dye-Doped Polymer Films

A real-time detection of a moving object was demonstrated by taking the subtraction between cross-polarized phase conjugate waves with fast and slow response times with two kinds of dye-doped phase conjugators. One consists of superposed films of an erythrosin-B-doped film and a methyl-orange-doped film, and the other is a film dispersed with both dyes. The relative phase between cross-polarized phase conjugate waves by the both dye-dispersed films was stable.     

Synthesis and antiulcer activity of the metabolites of 2-(4-ethyl-1-piperazinyl)-4-phenylquinoline dimaleate (AS-2646), a novel gastric antisecretory and antiulcer agent

The metabolites 3 and 4 of 2-(4-ethyl-1-piperazinyl)-4-phenylquinoline dimaleate (AS-2646, 1), a candidate as a gastric antisecretory and antiulcer drug, were synthesized to confirm the proposed structures. The effects of the metabolites 2-4 on ulcer induced by stress were determined.     

A finite element analysis of strain localization for soft rock using a constitutive equation with strain softening

Summary It is well known that deformation and/or strain of geological materials localize when they come close to the failure state. In the present: study, we try to analyze the deformation problem using a constitutive relation with strain hardening and strain softening. The constitutive model of a soft rock and overconsolidated clay using an elasto-plastic constitutive theory with memory was originally developed by Adachi and Oka. This type of formulation is shown to be easily applied to analyze the material behavior of strain softening because there is a similarity to that in viscoplasticity. Using the proposed model, the loss of uniqueness of the solution to the initial value problem can be avoided and a special or complicated numerical technique, e.g., an arc length method, does not need to be used. When we use constitutive equations with strain softening in a finite element analysis, there is a problem of strong mesh size dependency of numerical results. To remedy the mesh size dependency, we generalize the Adachi-Oka model based on the concept of non-localization by Bazant. We apply the proposed constitutive model to the behavior of a sedimentary soft rock in the drained triaxial compression test. It is found that mesh size dependency becomes smaller using the non-localization of the constitutive model.

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Eine Finite-Element-Analyse der lokalisierten Verformung von weichem Gestein bei einem Stoffgesetz mit Entfestigung

Übersicht Bekanntlich findet bei geologischen Stoffen in der Nähe des Versagenszustandes eine Lokalisierung der Verformung statt. Die Analyse dieses Problems wird in diesem Beitrag auf der Grundlage eines Stoffansatzes mit Ver- und Entfestigung unternommen. Entwickelt wurde das zugrunde gelegte elastischplastische Stoffmodell mit Gedächtnis von Adachi und Oka für weiches Gestein und übermäßig verdichteten Ton. Wegen der Ähnlichkeit zur Viskoplastizität läßt sich diese Formulierung des Stoffgesetzes leicht auf die Analyse des Verhaltens von entfestigendem Material anwenden, da der Eindeutigkeitsverlust der Lösung des Anfangswertproblems vermieden wird und besondere Rechenverfahren wie etwa die Bogenlängenmethode nicht benötigt werden. Bei der Benutzung von Stoffgesetzen in einer Finite-Element-Rechnung hängen die Ergebnisse stark von der Netzeinteilung ab. Um dies abzustellen, wird das Modell von Adachi und Oka auf der Grundlage von Bazant's Konzept der Nichtlokalisierung verallgemeinert. Anwendungsbeispiel ist das Verhalten von weichem Gestein im drainierten Triaxial-Test. Es zeigt sich, daß mit dem Konzept der Nichtlokalisierung im Stoffmodell der Einfluß der Netzeinteilung geringer wird.

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Presented at the workshop on Numerical Methods for Localization and Bifurcation of Granular bodies, held at the Technical University of Gdask (Poland), September 25–30, 1989.     

Preparation of highly dispersible and tumor-accumulative, iron oxide nanoparticles Multi-point anchoring of PEG-b-poly(4-vinylbenzylphosphonate) improves performance significantly

This paper describes the preparation of iron oxide nanoparticles, surface of which was coated with extremely high immobilization stability and relatively higher density of poly(ethylene glycol) (PEG), which are referred to as PEG protected iron oxide nanoparticles (PEG-PIONs). The PEG-PIONs were obtained through alkali coprecipitation of iron salts in the presence of the PEG-poly(4-vinylbenzylphosphonate) block copolymer (PEG-b-PVBP). In this system, PEG-b-PVBP served as a surface coating that was bound to the iron oxide surface via multipoint anchoring of the phosphonate groups in the PVBP segment of PEG-b-PVBP. The binding of PEG-b-PVBP onto the iron oxide nanoparticle surface and the subsequent formation of a PEG brush layer were proved by FT-IR, zeta potential, and thermogravimetric measurements. The surface PEG-chain density of the PEG-PIONs varied depending on the [PEG-b-PVBP]/[iron salts] feed-weight ratio in the coprecipitation reaction. PEG-PIONs prepared at an optimal feed-weight ratio in this study showed a high surface PEG-chain surface density (≈0.8 chainsnm(-2)) and small hydrodynamic diameter (<50 nm). Furthermore, these PEG-PIONs could be dispersed in phosphate-buffered saline (PBS) that contains 10% serum without any change in their hydrodynamic diameters over a period of one week, indicating that PEG-PIONs would provide high dispersion stability under in vivo physiological conditions as well as excellent anti-biofouling properties. In fact we have confirmed the prolong blood circulation time and facilitate tumor accumulation (more than 15% IDg(-1) tumor) of PEG-PIONs without the aid of any target ligand in mouse tumor models. The majority of the PEG-PIONs accumulated in the tumor by 96 h after administration, whereas those in normal tissues were smoothly eliminated by 96 h, proving the enhancement of tumor selectivity in the PEG-PION localization. The results obtained here strongly suggest that originally synthesized PEG-b-PVBP, having multipoint anchoring character by the phosphonate groups, is rational design for improvement in nanoparticle as in vivo application. Two major points, viz., extremely stable anchoring character and dense PEG chains tethered on the nanoparticle surface, worked simultaneously to become PEG-PIONs as an ideal biomedical devices intact for prolonged periods in harsh biological environments.     

Confinement in carbon nanospace-induced production of KI nanocrystals of high-pressure phase

An outstanding compression function for materials preparation exhibited by nanospaces of single-walled carbon nanohorns (SWCNHs) was studied using the B1-to-B2 solid phase transition of KI crystals at 1.9 GPa. High-resolution transmission electron microscopy and synchrotron X-ray diffraction examinations provided evidence that KI nanocrystals doped in the nanotube spaces of SWCNHs at pressures below 0.1 MPa had the super-high-pressure B2 phase structure, which is induced at pressures above 1.9 GPa in bulk KI crystals. This finding of the supercompression function of the carbon nanotubular spaces can lead to the development of a new compression-free route to precious materials whose syntheses require the application of high pressure.     

Control of vibronic excitation using quantum-correlated photons

We theoretically investigate the two-step excitation of a molecular vibronic state using quantum-correlated photons with time delay in order to control the population of the vibronic excited state. A Morse oscillator having three sets of vibronic states, namely, the ground state, intermediate states, and excited states, is used to evaluate the efficiency of the two-step excitation process. We show that we can efficiently and selectively excite only a target state by using correlated photons and can control the excitation population of the target state by adjusting the delay time of the correlated photons. The potential of controlling a chemical reaction using correlated photons is also discussed.