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81.
[structure: see text] The feasibility of assembling 3JH,H profiles from NMR data collected on relevant, but not necessarily specific, NMR database compounds representing a given stereocluster was demonstrated. By this approach, the 3JH,H profile was created for the contiguous tetraol peracetate stereocluster. The reliability and applicability of the database thus assembled were demonstrated for known peracetates derived from two heptoses. 相似文献
82.
A new type of mesh generator is developed by using a self-organized pattern in a reaction–diffusion system. The system is the Gray–Scott model, which creates a spot pattern in a specific parameter region. The spots correspond to nodes of a mesh. The mesh generator has several advantages: the algorithm is simple and processes to improve the mesh, such as smoothing, (locally) addition, and removal of nodes, are automatically performed by the system. 相似文献
83.
Jun Hayashi Nozomu Hashimoto Noriaki Nakatsuka Hirofumi Tsuji Hiroaki Watanabe Hisao Makino Fumiteru Akamatsu 《Proceedings of the Combustion Institute》2013,34(2):2435-2443
Soot formation characteristics of a lab-scale pulverized coal flame were investigated by performing carefully controlled laser diagnostics. The spatial distributions of soot volume fraction and the pulverized coal particles were measured simultaneously by laser induced incandescence (LII) and Mie scattering imaging, respectively. In addition, the radial distributions of the soot volume fraction were compared with the OH radical fluorescence, gas temperature and oxygen concentration obtained in our previous studies [1], [2]. The results indicated that the laser pulse fluence used for LII measurement should be carefully controlled to measure the soot volume fraction in pulverized coal flames. To precisely measure the soot volume fraction in pulverized coal flames using LII, it is necessary to adjust the laser pulse fluence so that it is sufficiently high to heat up all the soot particles to the sublimation temperature but also sufficiently low to avoid including a too large of a change in the morphology of the soot particles and the superposition of the LII signal from the pulverized coal particles on that from the soot particles. It was also found that the radial position of the peak LII signal intensity was located between the positions of the peak Mie scattering signal intensity and peak OH radical signal intensity. The region, in which LII signal, OH radical fluorescence and Mie scattering coexisted, expanded with increasing height above the burner port. It was also found that the soot formation in pulverized coal flames was enhanced at locations where the conditions of high temperature, low oxygen concentration and the existence of pulverized coal particles were satisfied simultaneously. 相似文献
84.
Hirofumi Matsuhata Hirotaka Yamaguchi Tamotsu Yamashita Toshiaki Tanaka Bin Chen Takashi Sekiguchi 《哲学杂志》2013,93(15):1674-1685
Shockley partial dislocations in 4H-SiC were observed using monochromatic synchrotron X-ray topography with a grazing-incidence Bragg-case geometry, that is, Berg–Barrett topography. The contrast of partial dislocations at the edges of Shockley-type stacking faults is discussed in terms of whether they have C- or Si-core edge components, or screw components. The dissociated state of basal-plane dislocation is discussed on a basis of the stacking sequence for basal-planes in the 4H-SiC crystal structure. It is expected that the results obtained in this study will be useful for characterizing Shockley-type stacking faults in Berg–Barrett topography. 相似文献
85.
We perform a Wilsonian renormalization group analysis for the nucleon–nucleon scattering in the P waves in the nuclear effective field theory including pions, in a similar way to the one done for the S-waves in our previous paper. We emphasize that the one-pion exchange interaction with large momentum transfer is of the same order as the leading contact interaction, so that there is no mismatch of the power counting. It is explicitly shown by obtaining consistent sets of renormalization group equations, that the cutoff dependence generated by the loop diagrams containing pion exchanges can be compensated by the cutoff dependence of the coupling constants of the contact interactions. 相似文献
86.
We explain how the Wilsonian renormalization group (RG) can determine the power counting of the nuclear effective field theory (NEFT) including pions. We emphasize that the separation of pion exchange into the short-distance part and the long-distance part is essential since they behave differently in the RG analysis; we found that the latter is perturbative whereas the a part of the former is nonperturbative. As for the contact interactions power counting turns out to be the same as that for pionless NEFT: pion exchange does not affect the scaling property of contact operators. Our RG equations for NEFT including pions connect smoothly with those for the pionless NEFT: pions decouple at very low energies as we expect. 相似文献
87.
88.
Tatsuya Iioka Satoshi Takahashi Yuichiro Yoshida Yoshihiro Matsumura Shuichi Hiraoka Hirofumi Sato 《Journal of computational chemistry》2019,40(1):279-285
The kinetics on a basic ligand substitution reaction on dinuclear platinum complexes [Pt(PEt3)2PhPt(PEt3)2]2+ and [Pt(PEt3)2PhCOPhPt(PEt3)2]2+ , with the ligands pyridine and 3-chloropyridine, is studied. This is a fundamental step in a self-assembly, and the time evolution has been observed with a new experimental technique, QASAP (quantitative analysis of self-assembly process), which is recently developed by Hiraoka's group. As a result of numerical calculations based on master equation, we succeed in specifying the reaction rate constants with a simple reaction model. In addition, the time evolutions of all the intermediate components produced and consumed in chemical reaction are revealed, including those unobserved in the experiments. The convergence behavior of the existence ratios of specific chemical species calculated with the stochastic algorithm method is compared with those obtained from deterministic formalism based on rate equations, revealing a clear dependence on the number of constituent molecules. © 2018 Wiley Periodicals, Inc. 相似文献
89.
We demonstrate laser-field-free molecular orientation with the combination of a moderate electrostatic field and an intense nonresonant rapidly turned-off laser field, which can be shaped with the plasma shutter technique. We use OCS (carbonyl sulfide) molecules as a sample. Molecular orientation is adiabatically created in the rising part of the laser pulse, and it is found to revive at around the rotational period of an OCS molecule with the same degree of orientation as that at the peak of the laser pulse in the virtually laser-field-free condition. This accomplishment means that a new class of molecular sample has become available for various applications. 相似文献
90.
报道了n型掺杂ZnSe/BeTe/ZnSe Ⅱ型量子阱(type-Ⅱ QW)在极低温 (5—10 K)条件下的各种光学性质. 磁场中(Farada配置)ZnSe层的反射光谱展示了一个典型的负的带电激子(X-)的跃迁特征. 对于空间间接光致发光(spacially indirect PL)光谱,它的主发光峰显示了一个反玻尔兹曼分布的非对称性,并且在磁场中(Voigt配置)它的峰值能量随磁场的增加而降低. 这些实验结果显示了该掺杂样品的空间间接PL是来自Ⅱ型QW结构所特有的带电激子的跃迁.
关键词:
光致发光
二维电子气
带电激子
Ⅱ型量子阱 相似文献