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81.
Guan-Yeow Yeap Michi Nakata Yoichi Takanishi Ken Ishikawa Hideo Takezoe 《Liquid crystals》2013,40(11):1437-1443
In order to study the difference in microscopic orientation of ferro- and antiferroelectric liquid crystalline molecules, we synthesized the partially deuteriated chiral compounds, (S)-(-)-2-methylbutyl 4-(4-(d13)-hexyloxy- and (S)-(-)-2-methylbutyl 4-(4-(d17)-octyloxy-phenyl)benzoates. Fundamental physical properties such as phase transition temperatures, spontaneous polarization and tilt angle were determined. Polarized FTIR measurements were also made to provide information on molecular structure and orientation. 相似文献
82.
Yuki Goto Masahiro Shiosaki Takeshi Hanamoto Masato Yoshida Hideo Sawada 《Colloid and polymer science》2013,291(5):1211-1217
Fluoro(silyl)acetylenes, which were prepared by reaction of 1,1-difluoroethylene with silyl chlorides, reacted with triethylamine to give dark-brown colored polyfluoro(silyl)acetylene powders in excellent to moderate isolated yields. In contrast, the corresponding nonfluorinated acetylene was unable to react with triethylamine at all to afford poly(silyl)acetylene under similar conditions. Polyfluoro(silyl)acetylenes thus obtained were nanometer size-controlled cubic fine particles with a good dispersibility and stability in a variety of solvents. These polyfluoro(silyl)acetylene nanoparticles exhibited clear absorption and emission spectra related to the conjugated units in polymer main chain. Furthermore, these polyfluoro(silyl)acetylene nanoparticles were applied to the surface modification of poly(methyl methacrylate) [PMMA] film to exhibit a higher oleophobicity imparted by fluorine on their surface, compared to that on the reverse side. Figure
New polyfluoro(silyl)acetylenes were prepared by reaction of the creesponding fluoro(silyl)acetylenes with triethylamine in excellent to moderate isolated yields. In contrast, the corresponding nonfluorinated silylacetylene was unable to give poly(silyl)acetylene under similar conditions. These polyfluoro(silyl)acetylenes thus obtained can form the nanometer size-controlled cubic fine particles (within 100 nm) in a variety of solvents. 相似文献
83.
Mari Iizuka Shoju Fukushima Yuki Goto Masaaki Okazaki Hideo Sawada Masato Yoshida 《Colloid and polymer science》2013,291(3):595-601
Head-to-head-type styrene and substituted styrene dimers bearing two fluoroalkyl end-groups have been efficiently synthesized by a simple reaction of perfluoroalkyl iodide with styrene under radical conditions as a mixture of meso and racemic forms. The meso form obtained from the mixture by recrystallization gave a crystal suitable for X-ray diffraction study and the crystal structure was found to be based on π-stacking of benzene rings and aggregation of fluoroalkyl chains. Dynamic light scattering measurements showed that meso-styrene dimers bearing two fluoroalkyl end-groups can form the nanometer size-controlled self-assemblies through the intermolecular π-stacking of benzene rings and aggregation of end-capped fluoroalkyl groups in methanol. Figure
Self-assembled meso-perfluorohexylated styrene dimer [C6F13–CH2CHPh–CHPh–CH2–C6F13] based on π-stacking of benzene rings and aggregation of fluoroalkyl chains: Fluorous domains are constructed by self-assembly of fluoroalkyl chains. 相似文献
84.
Keisuke Kinomura Masahiro Tamura Tetsuo Oga Hideo Okai 《Journal of carbohydrate chemistry》2013,32(2):229-241
Abstract To confirm the potential usefulness of amino acid residues as protecting groups for sugar hydroxyls, methyl 2,3-di-O-glycyl-α-D-glucopyranoside (5) and methyl 4,6-di-O-glycyl-2,3-di-O-methyl-α-D-gluco-pyranoside (7) were synthesized as reference compounds. Conditions were then established for the removal of these aminoacyl groups from the sugar molecules. The reference compounds were easily prepared by condensation of methyl α-D-glucopyranoside derivatives with N-protected glycine in the presence of dicyclohexyl-carbodiimide (DCC). The aminoacyl groups were removed by alkaline treatment, as were conventional acyl groups and also with ease by enzymatic hydrolysis using Pronase E. Conventional ester and ether protecting groups are not removed by such enzymatic treatment. Removal of aminoacyl group from sugar moieties on a practical scale is also described. 相似文献
85.
86.
Atsutoshi Yamada Yuki Watanabe Kyoko Noda Sumitaka Itoh Koji Ishihara Masahiko Inamo Refat Moustafa Hassan Hideo D. Takagi 《Journal of solution chemistry》2014,43(9-10):1479-1486
The reduction reaction of the Cu(II)–pitn complex (pitn = 1,3-di(pyridine-2-carboxaldimino)propane) by decamethylferrocene [Fe(Cp*)2] was examined in acetonitrile. The observed pseudo-first-order rate constants exhibited saturation kinetics with increasing excess amount of [Fe(Cp*)2]. Detailed analyses revealed that the reaction is controlled by a structural change prior to the electron transfer step, rather than a conventional bimolecular electron transfer process preceded by ion pair (encounter complex) formation. The rate constant for the structural change was estimated to be 275 ± 13 s?1 at 298 K (?H* = 33.3 ± 1.0 kJ·mol?1, ?S* = 86 ± 5 J·mol?1·K?1), which is the fastest among gated reactions involving CuN4 complexes. It was confirmed by EPR measurement and Conflex calculations that the dihedral angle between the two N–N planes is significantly large (40°) in solution whereas it is merely 17.14° in the crystal. 相似文献
87.
Well‐Defined Iron Complexes as Efficient Catalysts for “Green” Atom‐Transfer Radical Polymerization of Styrene,Methyl Methacrylate,and Butyl Acrylate with Low Catalyst Loadings and Catalyst Recycling
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So‐ichiro Nakanishi Dr. Mitsunobu Kawamura Hidetomo Kai Prof. Dr. Ren‐Hua Jin Dr. Yusuke Sunada Prof. Dr. Hideo Nagashima 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(19):5802-5814
Environmentally friendly iron(II) catalysts for atom‐transfer radical polymerization (ATRP) were synthesized by careful selection of the nitrogen substituents of N,N,N‐trialkylated‐1,4,9‐triazacyclononane (R3TACN) ligands. Two types of structures were confirmed by crystallography: “[(R3TACN)FeX2]” complexes with relatively small R groups have ionic and dinuclear structures including a [(R3TACN)Fe(μ‐X)3Fe(R3TACN)]+ moiety, whereas those with more bulky R groups are neutral and mononuclear. The twelve [(R3TACN)FeX2]n complexes that were synthesized were subjected to bulk ATRP of styrene, methyl methacrylate (MMA), and butyl acrylate (BA). Among the iron complexes examined, [{(cyclopentyl)3TACN}FeBr2] ( 4 b ) was the best catalyst for the well‐controlled ATRP of all three monomers. This species allowed easy catalyst separation and recycling, a lowering of the catalyst concentration needed for the reaction, and the absence of additional reducing reagents. The lowest catalyst loading was accomplished in the ATRP of MMA with 4 b (59 ppm of Fe based on the charged monomer). Catalyst recycling in ATRP with low catalyst loadings was also successful. The ATRP of styrene with 4 b (117 ppm Fe atom) was followed by precipitation from methanol to give polystyrene that contained residual iron below the calculated detection limit (0.28 ppm). Mechanisms that involve equilibria between the multinuclear and mononuclear species were also examined. 相似文献
88.
Molecularly Designed Nanoparticles by Dispersion of Self‐Assembled Organosiloxane‐Based Mesophases
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Shigeru Sakamoto Yasuhiro Tamura Dr. Hideo Hata Dr. Yasuhiro Sakamoto Prof. Atsushi Shimojima Prof. Kazuyuki Kuroda 《Angewandte Chemie (International ed. in English)》2014,53(35):9173-9177
The design of siloxane‐based nanoparticles is important for many applications. Here we show a novel approach to form core–shell silica nanoparticles of a few nanometers in size through the principle of “dispersion of ordered mesostructures into single nanocomponents”. Self‐assembled siloxane–organic hybrids derived from amphiphilic alkyl‐oligosiloxanes were postsynthetically dispersed in organic solvent to yield uniform nanoparticles consisting of dense lipophilic shells and hydrophilic siloxane cores. In situ encapsulation of fluorescent dyes into the nanoparticles demonstrated their ability to function as nanocarriers. 相似文献
89.
Dr. Roman S. Erdmann Dr. Hideo Takakura Alexander D. Thompson Felix Rivera‐Molina Dr. Edward S. Allgeyer Prof. Dr. Joerg Bewersdorf Prof. Dr. Derek Toomre Prof. Dr. Alanna Schepartz 《Angewandte Chemie (International ed. in English)》2014,53(38):10242-10246
We report a lipid‐based strategy to visualize Golgi structure and dynamics at super‐resolution in live cells. The method is based on two novel reagents: a trans‐cyclooctene‐containing ceramide lipid (Cer‐TCO) and a highly reactive, tetrazine‐tagged near‐IR dye (SiR‐Tz). These reagents assemble via an extremely rapid “tetrazine‐click” reaction into Cer‐SiR, a highly photostable “vital dye” that enables prolonged live‐cell imaging of the Golgi apparatus by 3D confocal and STED microscopy. Cer‐SiR is nontoxic at concentrations as high as 2 μM and does not perturb the mobility of Golgi‐resident enzymes or the traffic of cargo from the endoplasmic reticulum through the Golgi and to the plasma membrane. 相似文献