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41.
Koji Nonaka Hidehiko Takara Atsushi Takada Kentaro Uchiyama Yoshiaki Yamabayashi 《Optical Review》1998,5(6):331-333
An optical mono-stable multivibrator laser diode (MM-LD) is realized by using a multi-electrode distributed feedback laser diode. All-optical pulse-width conversion of ultra-short pulses to non-return-to-zero (NRZ) is achieved using an MM-LD. The MM-LD is adopted for a wide range of bit-rates between 2-10 Gbit/s by tuning the DC bias. Data format transformation from 10-Gbit/s return-to-zero optical signals to NRZ optical-signals is achieved with error free operation. Converted optical signals, which have a narrower spectral bandwidth and lower peak power than when input, are transmitted using a 1.3-μm zero dispersion fiber (1.3Aλ0-SMF). 相似文献
42.
New 4-aminoquinolines having a -CF2CH-(heteroaryl)-OH moiety are obtained in moderate yields from the electrochemical catalyzed reaction of the corresponding 4-amino-3-chlorodifluoroacetyl-2-methoxyquinoline in the presence of heteroaryl aldehydes. A one-pot intramolecular zinc mediated aromatic nucleophilic substitution also gave access to novel difluorinated 5-aminodihydropyrano[2,3-b]quinolin-4-ones. 相似文献
43.
Time-resolved FTIR spectroscopy with microsecond resolution was applied to the switching process of FLCs using an IR polarizer attached to a microscope whose axis was set along the aligning direction (direction of SiO flux). A tilted bookshelf geometry with a layer tilt angle of approximately 34° was obtained by alignment using obliquely evaporated SiO layers in a CaF2 cell with about 1.7 μm gap. Six kinds of FLC mixtures were prepared by mixing 5 wt % of a chiral molecule with host mixtures of phenylpyrimidines. By monitoring an absorption band at 1432 cm-1, assigned to vibrational modes of the pyrimidine skeleton, it was found that the molecular long axis either rotates along the upper side or along the lower side of the cone during switching. Moreover, we investigated the relationship between the rotational direction of the directors and the stability of the dark level transmission during multiplexing. The dark level transmission during rotation along the upper side of the cone may fluctuate less than that during rotation along the lower side of the cone. We found that the bias stability of the dark level transmission is closely related to the direction of the rotation along the cone. The direction of the rotation of FLCs along the cone was therefore found to play an important role in realizing high contrast ratios during multiplexing. 相似文献
44.
Sujoy Bandyopadhyay Rmi Mtivier Pragyan Pallavi Eduard Preis Keitaro Nakatani Katharina Landfester Abhijit Patra Ullrich Scherf 《Macromolecular rapid communications》2016,37(3):271-277
Conjugated polymer nanoparticles based on poly[9,9‐bis(2‐ethylhexyl)fluorene] and poly[N‐(2,4,6‐trimethylphenyl)‐N,N‐diphenylamine)‐4,4′‐diyl] are fabricated using anionic surfactant sodium dodecylsulphate in water by miniemulsion technique. Average diameters of polyfluorene and polytriarylamine nanoparticles range from 70 to 100 and 100 to 140 nm, respectively. The surface of the nanoparticles is decorated with triplet emitting dye, tris(2,2′‐bipyridyl)ruthenium(II) chloride. Intriguing photophysics of aqueous dispersions of these hybrid nanoparticles is investigated. Nearly 50% quenching of fluorescence is observed in the case of dye‐coated polyfluorene nanoparticles; excitation energy transfer is found to be the dominant quenching mechanism. On the other hand, nearly complete quenching of emission is noticed in polytriarylamine nanoparticle‐dye hybrids. It is proposed that the excited state electron transfer from the electron‐rich polytriarylamine donor polymer to Ru complex leads to the complete quenching of emission of polytriarylamine nanoparticles. The current study offers promising avenues for developing aqueous solution processed‐electroluminescent devices involving a conjugated polymer nanoparticle host and Ru or Ir‐based triplet emitting dye as the guest.
45.
46.
Wang C Pu F Lin Y Ren J Dohn C Nakatani K Qu X 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(29):8189-8194
A robust and photoresponsive DNA network has been designed and constructed from branched DNA and molecular glue. The molecular glue is photoswitchable and can specifically bind to G-G mismatched double-stranded DNA. The assembly process can be reversibly controlled by manipulating the wavelength of light. The approach is flexible, allowing tuning of the size, morphology as well as the cavity of the network by variation of the molar ratio and the isotropic/anisotropic character of the branched building blocks. The assembled architectures are versatile and heat tolerant. These properties should allow the use of the network in further applications. 相似文献
47.
Horinouchi T Nakagawa H Suzuki T Fukuhara K Miyata N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(17):4809-4813
We report a novel NO donor (RpNO), containing a 2,6-dimethylnitrobenzene moiety for photocontrollable NO release and a rhodamine moiety for targeting to mitochondria. Photorelease of NO from RpNO in aqueous solution was confirmed by means of ESR analysis. Cellular release of NO from RpNO was confirmed with the aid of DAF-FM DA, an NO-specific fluorescence probe. RpNO was colocalized with MitoTracker Green FM, a mitochondrial stain, in HCT116 colon cancer cells and exhibited photodependent cytotoxicity. Our results indicate that RpNO is an effective NO donor for time-controlled, mitochondria-specific NO treatment. 相似文献
48.
Hidehiko Mishou 《Journal of Number Theory》2011,131(12):2352-2367
In this paper we investigate the joint functional distribution for a pair of Hurwitz zeta functions ζ(s,αj) (j=1,2) in the case that real transcendental numbers α1 and α2 satisfy α2∈Q(α1). Especially we establish the joint universality theorem for these zeta functions. 相似文献
49.
A redox species was extracted from water (50 x 10(-6) dm3) into a single micro-oil-droplet (30 x 10(-12) dm3) in contact with a microelectrode using microcapillary injection and manipulation techniques. Further, an in situ microanalysis of the solute in a single oil droplet was demonstrated by differential pulse voltammetry. The redox species of 10(-16) mol concentrated in the droplet could be quantitatively analyzed independently of the distribution coefficient of the solute between the oil and water phases. The potential of this technique was considered in terms of the preconcentration and separation as well as a microanalysis and an ultratrace analysis. 相似文献
50.
Lydie Viau Itamar Malkowsky Karine Costuas Stéphanie Boulin Lo?c Toupet Eléna Ishow Keitaro Nakatani Olivier Maury Hubert Le Bozec 《Chemphyschem》2006,7(3):644-657
Two 2,2'-bipyridines, substituted at the 4,4'-positions by p-dialkylaminophenylazostyryl moieties p-R2N-C6H4-N=N-C6H4-CH=CH-[6 a, R2N=nBu2N; 6 b, R2N=(nBu)(C4H8OTHP)N; 6 c, R2N=(nBu)(C4H8OH)N], were successfully synthesized by using Wadworth-Emmons reactions. The X-ray structure of 6 a has been determined. Esterification of 6 c with 2-bromoisobutyroylbromide afforded 6 d. This ligand was used as an initiator for the living radical polymerization of methylmethacrylate (MMA) and gave rise to macroligand 6 e. Thin films of good optical quality were obtained by the spin-coating technique. Photoisomerization experiments were carried out on 6 a in solution and on 6 e in both solution and film, and the kinetics of photochemical (E/Z) and thermal (Z/E) isomerization were investigated. They were found to show Z-E back isomerization typical of aminoazobenzene-type rather than of push-pull-type molecules. Density functional theoretical (TD-DFT) calculations were performed on model compound 6 a' (R2N=Me2N) to understand the structural and electronic transitions of the corresponding E-E, E-Z and Z-Z isomers. It was found that the E-E isomer is almost planar as observed experimentally by X-ray diffraction, whereas the Z-Z isomer, which is 35.4 kcal mol(-1) less stable than the E-E isomer, is nonplanar. The theoretical studies also reveal that several transitions of pi-pi*, n-pi* and charge-transfer (CT) types, are involved in the long-wavelength transition of 6 a (E-E). The same observations can be made for the (Z-Z) isomer, and the TD-DFT simulated spectrum fits quite nicely to the experimental, reproducing and explaining the apparition of a blue-shifted charge-transfer band at 390 nm. 相似文献